Search results for "Bulk polymerization"

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A supported titanium postmetallocene catalyst: Effect of selected conditions on ethylene polymerization

2011

Ethylene polymerization with a titanium complex [N,N-ethylenebis(3-methoxysalicylideneiminato)titanium dichloride] immobilized on the magnesium support with the formula MgCl2(THF)0.32(Et2AlCl)0.36 was studied. In particular, the effects of polymerization temperature, monomer pressure, and polymerization time on the activity of the catalyst and on the polyethylene properties (molecular weight and its distribution, melting point, crystallinity, and bulk density) were evaluated. The findings of investigations prove that the studied supported titanium catalyst is highly active in ethylene polymerization, and its activity increases with increasing temperature and monomer pressure. Moreover, stab…

polyethyleneMaterials sciencePolymers and PlasticsBulk polymerizationsupportsmelting pointtechnology industry and agriculturechemistry.chemical_elementSolution polymerizationGeneral Chemistrymolecular weight distributionPolyethylenecatalystsSurfaces Coatings and Filmschemistry.chemical_compoundChain-growth polymerizationchemistryPolymerizationPolymer chemistryMaterials ChemistryPrecipitation polymerizationCoordination polymerizationTitaniumJournal of Applied Polymer Science
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