Search results for "C coupling"
showing 10 items of 149 documents
Changes of energy fluxes in marine animal forests of the anthropocene: Factors shaping the future seascape
2019
12 pages, 3 figures
Seasonal cycle of benthic denitrification and DNRA in the aphotic coastal zone, northern Baltic Sea
2020
Current knowledge on the seasonality of benthic nitrate reduction pathways in the aphotic, density stratified coastal zone of the Baltic Sea is largely based on data from muddy sediments, neglecting the potential contribution of sandy sediments. To gain a more comprehensive understanding of seasonality in this part of the Baltic Sea coast, we measured rates of benthic denitrification, anammox and dissimilatory nitrate reduction to ammonium (DNRA) monthly in the ice-free period of 2016 in both sandy and muddy aphotic sediments, northwestern Gulf of Finland. No anammox was observed. The seasonal cycle of denitrification in both sediment types was related to the hydrography-driven development …
Hydrography and food distribution during a tidal cycle above a cold-water coral mound
2022
Cold-water corals (CWCs) are important ecosystem engineers in the deep sea that provide habitat for numerous species and can form large coral mounds. These mounds influence surrounding currents and induce distinct hy- drodynamic features, such as internal waves and episodic downwelling events that accelerate transport of organic matter towards the mounds, supplying the corals with food. To date, research on organic matter distribution at coral mounds has focussed either on seasonal timescales or has provided single point snapshots. Data on food distribution at the timescale of a diurnal tidal cycle is currently limited. Here, we integrate physical, biogeochemical, and biological data throug…
[Mnii2(bpym)(H2O)8]4+ and [Miv(CN)8]4– (M = Mo and W) as building blocks in designing bpym- and cyanide-bridged bimetallic three-dimensional networks…
2002
One-pot reaction between the dinuclear [MnII2(bpym)(H2O)8]4+ complex and the mononuclear [MIV(CN)8]4− unit (M = Mo and W; bpym = 2,2′-bipyrimidine) in aqueous solution yields the novel heterobimetallic complexes of formula {(μ-bpym)[Mn(H2O)]2-(μ-NC)6M(CN)2} with M = Mo (1) and W (2). 1 and 2 are isostructural three-dimensional compounds where the manganese atoms are bridged by bisbidentate bpym and hexakismonodentate octacyanometalate units. Variable-temperature magnetic susceptibility data of 1 and 2 show the occurrence of a significant antiferromagnetic coupling between the high spin manganese(II) ions through bridging bpym (Jca. −1.1 cm−1, the exchange Hamiltonian being defined as H = −J…
Intersystem crossing in Fe(II) coordination compounds
1994
Fe(II) spin-crossover systems can be quantitatively converted from the low-spin (LS) to the high-spin (HS) state well below the thermal transition temperature by irradiating either into the metal-ligand charge transfer or d-d absorption bands, and even in low-spin systems a transient population of the HS state can be achieved. This fact can be made use of to determine HS → LS relaxation rate constants for a wide variety of Fe(II) spin-crossover and low-spin systems. The HS → LS relaxation shows strong deviations from an Arrhenius behaviour, with nearly temperature-independent tunnelling below ∼70 K and a thermally activated process above ∼100 K. The range of more than 12 orders of magnitude…
FT Raman and DFT Study on a Series of All-antiOligothienoacenes End-Capped with Triisopropylsilyl Groups
2009
minal a positions. These substituents aid in purification and solution processability, and can be removed under mild chemical conditions. For the first time, we have the opportunity to analyze a series of oligothienoacenes to gain insight into the fundamental structure–property relationships with respect to the addition of each ring. Furthermore, this series of compounds can be directly compared to other well-studied series of closely related oligomers, such as nonfused oligothiophenes and fully fused all-syn oligothienoacenes. [7] To gain precise insight into relationships between the structure and properties of a wide range of p-conjugated molecular Herein, we study the p-conjugational pr…
Control subsystem design for wireless power transfer
2014
Recently, the wireless power transfer has been increasingly employed. Particularly for the electric vehicles, the wireless solution is attractive for contactless battery charging, based on the Inductive Power Transfer (IPT). In this paper, a 150W prototype for IPT-based battery charging is presented and design criteria are reported. In addition to the power stage analysis, a proper control strategy is proposed. Simulation and experimental results are shown. The proposed control method aims at regulating the load current against variations in the magnetic coupling, so that the required amount of power can be supplied despite of unexpected decreases in the coupling efficiency.
Clusters and Industrial Districts: Where is the Literature Going? Identifying Emerging Sub-Fields of Research
2015
[EN] The industrial district and cluster literature has generated an extraordinary quantity of articles, debates and topics for discussion, and encompasses one of the most vibrant lines of research in the field of economics, geography, management and related disciplines. The literature, however, is fairly fragmented. In this paper, “bibliometric” methods are used to analyse the cluster literature published between 1957 and 2014 in order to explore “prospective” research priorities through the method of “bibliographic coupling”. Beyond focusing on foundational works in the past, this approach shifts the focus away from the practice of analysing co-citations and seminal contributions to one o…
Experimental study of electrical FitzHugh-Nagumo neurons with modified excitability
2006
International audience; We present an electronical circuit modelling a FitzHugh-Nagumo neuron with a modified excitability. To characterize this basic cell, the bifurcation curves between stability with excitation threshold, bistability and oscillations are investigated. An electrical circuit is then proposed to realize a unidirectional coupling between two cells, mimicking an inter-neuron synaptic coupling. In such a master-slave configuration, we show experimentally how the coupling strength controls the dynamics of the slave neuron, leading to frequency locking, chaotic behavior and synchronization. These phenomena are then studied by phase map analysis. The architecture of a possible ne…
Coherent Manipulation of Polarization in Mixed-Valence Compounds by Electric Pulse via Landau–Zener Transitions
2012
In this contribution, we predict and theoretically investigate the effects of the electric field pulse in mixed valence (MV) dimers. These systems exhibit bistability with a large internal dipole moment mediated by the itinerant electron trapped by the vibronic coupling. In this sense, they are similar to single molecular magnets (SMMs) that are bistable systems possessing large long-living magnetization and exhibiting Landau−Zener (LZ) transitions. We propose a scheme for a controllable LZ tunnelling in MV systems that provides also a possibility to control the dipole moment of a dimeric MV unit. It is supposed that the static electric field initially polarizes the system, and then the uni…