Search results for "CAE"
showing 10 items of 601 documents
Efficient Vacuum-Deposited Perovskite Solar Cells with Stable Cubic FA 1– x MA x PbI 3
2020
Preparation of black formamidinium lead iodide (FAPbI3) requires high temperature annealing and the incorporation of smaller A-site cations, such as methylammonium (MA+), cesium or rubidium. A major advantage of vacuum processing is the possibility to deposit perovskite films at room temperature (RT), without any annealing step. Here we demonstrate stabilization of the cubic perovskite phase at RT, in a three-sources co-sublimation method. We found that the MA+ incorporation is a self-limiting process, where the amount of MA+ which is incorporated in the perovskite is essentially unvaried with increasing MAI deposition rate. In this way a phase-pure, cubic perovskite with a bandgap of 1.53 …
Collinear Laser Spectroscopy on Fast Atomic Beams
1978
In collinear geometry we have observed laser-excited, narrow resonances in fast beams of Na and Cs atoms obtained from ion beams by charge transfer collisions. Being very sensitive, the method is suited for measuring isotope shifts and hyperfine structure of isotopes far from stability provided by on-line mass separators. It may be used furthermore to study inelastic charge transfer from the energy-loss spectrum of the Doppler-shifted lines.
Ultrathin lead bromide perovskite platelets spotted with europium(ii) bromide dots
2019
We describe here the preparation of a novel nanohybrid comprising a two-layer cesium lead bromide nanoplatelet, [CsPbBr3]PbBr4 NPL, containing europium(II) bromide (EuBr2) nanodots, by ultrasound/heating treatment of toluene dispersions of the CsPbBr3 nanomaterial in the presence of EuBr2 nanodots. The hybrid nanoplatelets exhibit strong excitonic and narrow emission peaks characteristic of ultrathin NPLs at 430 and 436 nm, respectively.
Solvent-Free Synthesis and Thin-Film Deposition of Cesium Copper Halides with Bright Blue Photoluminescence
2019
Non-toxic alternatives to lead halide perovskites are highly sought after for applications in optoelectronics. Blue-luminescent materials are especially demanded as they could be used to prepare white light-emitting diodes, with important potential applications in lighting systems. However, wide bandgap blue emitters with high photoluminescence quantum yields (PLQY) are typically more difficult to obtain as compared to green- or red-emitting ones. Here, we prepared two series of inorganic cesium copper halides, with the general formulas Cs3Cu2X5 and CsCu2X3 (X = Cl, Br, I, and mixtures thereof) by dry mechanochemical synthesis at room temperature. X-ray diffraction demonstrates quantitative…
Room temperature vacuum-deposition of CsPbI2Br perovskite films from multiple-sources and mixed halide precursors
2020
Fully inorganic cesium lead halide perovskites, such as CsPbI2Br, show enhanced thermal stability compared to hybrid ones and are being widely investigated as wide bandgap absorbers for tandem applications. Despite their simple stoichiometry, the preparation of highly crystalline and stable cesium lead halide thin films is not trivial. In general, high-efficiency solar cells based on solution-processed CsPbI2Br thin films are prepared by hightemperature annealing or the use of chemical additives. In this work, we use solvent-free synthesis to investigate the formation of CsPbI2Br in bulk or in thin films via mechanochemical synthesis and multiple-source vacuum deposition, respectively. We d…
Electromagnetically Induced Transparency and optical pumping processes formed in Cs sub-micron thin cell
2012
Abstract The Electromagnetically Induced Transparency (EIT) effect in a Λ -system formed by Cs atoms (6 S 1/2 − 6 P 3/2 − 6 S 1/2 ) confined in an extremely thin cell (ETC) (atomic column thickness L varies in the range of 800 nm –3 µm is studied both experimentally and theoretically. It is demonstrated that when the coupling laser frequency is in exact resonance with the corresponding atomic transition, the EIT resonance parameters weakly depend on L , which allows us to detect the effect at L = λ = 852 nm. EIT process reveals a striking peculiarity in case of the coupling laser detuned by Δ from the atomic transition, namely the width of the EIT resonance rapidly increases upon an in…
Magnetic Field Gradiometer with Sub-Micron Spatial Resolution Based on Caesium Vapour in an Extremely Thin Cell
2015
Abstract In this paper we present a device for measuring the magnetic field and its gradient with a spatial resolution of several hundred nanometres. This device is based on caesium metal vapour confined to an extremely thin cell (ETC). To measure magnetic signals, we use absorption and very low laser powers, which might be appealing for modern fabrication techniques. A portable, fully automated device was constructed.
Photo-assisted O− and Al− production with a cesium sputter ion source
2021
It has been recently proposed that the production of negative ions with cesium sputter ion sources could be enhanced by laser-assisted resonant ion pair production. We have tested this hypothesis by measuring the effect of pulsed diode lasers at various wavelengths on the O− and Al− beam current produced from Al2O3 cathode of a cesium sputter ion source. The experimental results provide evidence for the existence of a wavelength-dependent photo-assisted enhancement of negative ion currents but cast doubt on its alleged resonant nature as the effect is observed for both O− and Al− ions at laser energies above a certain threshold. The beam current transients observed during the laser pulses s…
Recensione ad Albertino MUSSATO, Epistole metriche. Ediz. critica, trad. e commento a cura di L. LOMBARDO, Venezia 2020
2022
Recensione ad Albertino MUSSATO, Epistole metriche. Ediz. critica, trad. e commento a cura di L. LOMBARDO, Venezia 2020 Review of Albertino MUSSATO, Epistole metriche. Ediz. critica, trad. e commento a cura di L. LOMBARDO, Venezia 2020
Oxygen isotopes from limpet shells: Implications for palaeothermometry and seasonal shellfish foraging studies in the Mediterranean
2017
Limpet shells are common components of many archaeological sites in the Mediterranean. To test whether δ18O values from archaeological Patella caerulea shells can serve as a reliable palaeothermometer for the Mediterranean and a reliable archive of season of collection information, we collected live P. caerulea from eight Mediterranean locations in Croatia, Israel, Libya, Malta, Tunisia, and Turkey. Shell growth patterns were studied in section, and samples for oxygen isotope analysis were milled from the shells and used to calculate sea surface temperature (SST). As with other species of limpet, SST reconstructed from P. caerulea δ18O values were lower than expected from observational reco…