Search results for "CAPI"
showing 10 items of 2622 documents
Le développement du capital humain en lien avec les compétences psychosociales
2018
International audience
L'intérêt de la prise en compte des compétences non académiques dans la redéfinition du capital humain développé par les élèves. Une application sur …
2017
International audience
Study of drilling and welding laser : dynamics of keyhole
2011
The aim of the present work is to study experimentally the formation of the capillary during the drilling and welding by laser beam and to develop the numerical simulation which allows following the dynamics and the evolution of the keyhole. The zinc was chosen as a test material because its thermodynamical properties are well known. To simplify the problem, in the first place the drilling mechanism was studied. Two experimental methods were used to characterize the evolution of the keyhole: the Direct Observation of Drilled Hole method, which allows the visualization of the keyhole after the application of laser pulses of different durations, and Zn-Quartz method, which allows the direct o…
Macroscopic equations of motion for two-phase flow in porous media
1998
The established macroscopic equations of motion for two phase immiscible displacement in porous media are known to be physically incomplete because they do not contain the surface tension and surface areas governing capillary phenomena. Therefore a more general system of macroscopic equations is derived here which incorporates the spatiotemporal variation of interfacial energies. These equations are based on the theory of mixtures in macroscopic continuum mechanics. They include wetting phenomena through surface tensions instead of the traditional use of capillary pressure functions. Relative permeabilities can be identified in this approach which exhibit a complex dependence on the state v…
Fluctuating Interfaces in Liquid Crystals
2008
We review and compare recent work on the properties of fluctuating interfaces between nematic and isotropic liquid-crystalline phases. Molecular dynamics and Monte Carlo simulations have been carried out for systems of ellipsoids and hard rods with aspect ratio 15:1, and the fluctuation spectrum of interface positions (the capillary wave spectrum) has been analyzed. In addition, the capillary wave spectrum has been calculated analytically within the Landau-de Gennes theory. The theory predicts that the interfacial fluctuations can be described in terms of a wave vector dependent interfacial tension, which is anisotropic at small wavelengths (stiff director regime) and becomes isotropic at l…
Theoretical and Experimental Studies of Capillary Hysteresis in MCM-41
1996
Mesoporous materials of MCM-41 type are considered to be reference model adsorbents due to their regular pore structure. Nitrogen adsorption isotherms on MCM-41 are modeled using the Non-Local Density Functional Theory (NLDFT). The thermal dependence of the thermodynamic hysteresis predicted by the NLDFT is confirmed by experimental measurements. The nitrogen hysteresis on MCM-41 at temperatures below 77.4 K or in pores greater than 4 nm is associated with the metastability of the adsorption branch of the isotherm. In the hysteresis regime, the desorption branch is likely to be thermodynamically stable and is recommended for calculating pore size distributions.
Colloid-polymer mixtures between asymmetric walls: Evidence for an interface localization transition
2007
We demonstrate via computer simulation that mixtures of colloids and polymers confined to thin films have the ability to undergo an interface localization transition. While one wall of the film is assumed to be hard for both particles, at the other wall, an additional repulsive potential acts, but on the colloids only. By varying the strength of this repulsion, a crossover from capillary condensation to interface localization is found. The latter occurs under conditions where in the bulk almost complete phase separation has occurred.
Direct measurement of forces between particles and bubbles
1999
One of the elementary stages of the flotation process is the formation of an aggregate between the particle and a bubble. This aggregate formation is governed by hydrodynamic, capillary and interparticle forces. During the last four years, techniques have been developed to measure directly the force between a colloidal particle and a bubble. These techniques are closely related to the development of atomic force microscopy. Advantages and possibilities, as well as limits and drawbacks are described.
Symmetric diblock copolymers confined into thin films: A Monte Carlo investigation on the CRAY T3E
2000
We present the results of large scale computer simulations targeted at investigating the phase stability and the structure of symmetric AB diblock copolymers in thin films. The connectivity of the two different monomer species A and B in the diblock copolymer prevents macrophage separation and the molecules assemble into A-rich and B-rich domains on the scale of the molecule’s extension. This large length scale of the ordering phenomena makes these polymeric systems a promising candidate for revealing the universal features of self-assembling in amphiphilic molecules. However, the widely spread length and time scales impart protracted long relaxation times to the systems and pose a challeng…
ChemInform Abstract: Tuning the Defect Configurations in Nematic and Smectic Liquid Crystalline Shells
2013
Thin liquid crystalline shells surrounding and surrounded by aqueous phases can be conveniently produced using a nested capillary microfluidic system, as was first demonstrated by Fernandez-Nieves et al. in 2007. By choosing particular combinations of stabilizers in the internal and external phases, different types of alignment, uniform or hybrid, can be ensured within the shell. Here, we investigate shells in the nematic and smectic phases under varying boundary conditions, focusing in particular on textural transformations during phase transitions, on the interaction between topological defects in the director field and inclusions in the liquid crystal (LC), and on the possibility to relo…