Search results for "CAPI"
showing 10 items of 2622 documents
Analysis of thiabendazole and procymidone in fruits and vegetables by capillary electrophoresis–electrospray mass spectrometry
2002
Abstract A capillary electrophoresis–mass spectrometry method for determining procymidone and thiabendazole in apples, grapes, oranges, pears, strawberries and tomatoes is described. Separation is achieved using a buffer of formic acid–ammonium formate at pH 3.5 with 2% of methanol. Fungicide residues present in the sample are preconcentrated by both solid-phase extraction and injection of large sample volumes into the capillary by a stacking technique, to obtain lower detection limits. Ionization is performed at atmospheric pressure in an electrospray type source and detection is carried out using positive ionization and selected ion monitoring modes. The quantitation limits are 0.005 and …
Determination of glyphosate and aminomethylphosphonic acid in natural water using the capillary electrophoresis combined with enrichment step
2005
A previously elaborated capillary electrophoresis (CE) method used for the determination of glyphosate and aminomethylphosphonic acid (AMPA) was slightly modified in order to improve the sensitivity. However, detection limits attained (5 μg mL−1 for glyphosate and 4 μg mL−1 for AMPA) were still not satisfactory for analytical purposes, thus the addition of a preconcentration step before the CE analysis was proposed. AMBERLITE®IRA-900, a strong anion-exchange resin, was used to preconcentrate both analytes in environmental aqueous samples. The experimental conditions optimised in a previous work were readapted, by decreasing the eluent concentration due to CE limitations. Satisfactory result…
Resolution of overlapped non-absorbing and absorbing solutes using either an absorption null-balance detection window or multivariate deconvolution a…
2004
Abstract Non-absorbing alkyl ether sulfates (AES) can be separated using anthraquinone-2-carboxylic acid (AQCA) as a probe; however, absorbing alkyl benzene sulfonates (ABS), if present, interfere indirect detection of most AES oligomers. Overcoming of this interference, as well as the simultaneous characterisation and evaluation of AES, fatty acids and ABS, was accomplished by using a diode-array detector and the procedures here discussed. First, it was shown that ABS can be made undetectable by using a 9 nm wide and 227 nm centred charge-absorptivity null-balance detection window (NBDW), where its contribution to the absorbance cancels the dilution effects that its presence induces on the…
Separation and determination of homologues of linear alkylbenzenesulfonates by nonaqueous capillary zone electrophoresis using alkylammonium salts in…
2001
The separation of linear alkylbenzene sulfonates (LAS) by nonaqueous capillary electrophoresis (NACE) using negative polarity, and a buffer containing acetic acid and an alkylamine in nonaqueous ethanol, has been investigated. Several primary, secondary, and tertiary alkylamines with alkyl chains of different length were compared. The solutes travelled against the electroosmotic flow (EOF), and at the same time were braked by association with the alkylamine molecules or with the alkylammonium ions. The best resolution between adjacent LAS homologues (R approximately 2.1), partial isomer resolution in two peaks, and at the same time an excellent repeatability, was obtained with a small dipen…
Development cooperation projects - on the road towards social organisational capital : case study: Latvia
2010
DEVELOPMENT COOPERATION PROJECTS – ON THE ROAD TOWARDS SOCIAL ORGANISATIONAL CAPITAL CASE STUDY: LATVIA Sintija Dutka Master’s Thesis Social and Public Policy / Master’s programme in Development and International Cooperation Department of Social Sciences and Philosophy University of Jyväskylä Instructor: Marja Järvelä English proof reader: Mark Dennis Time period: Autumn 2009 / Spring 2010 Pages: 97 pages + annex 4 pages The purpose of the thesis is to examine ways in which implementation of a development cooperation project influences the capacity of project implementing organisations in Latvia. Furthermore, the study aims to discover whether social capital generated during the project cyc…
Evaluation of 2,3-epoxypropyl groups and functionalization yield in glycidyl methacrylate monoliths using gas chromatography
2014
Abstract Poly(glycidyl methacrylate- co -ethylene dimethacrylate) (poly(GMA- co -EDMA)) is most frequently used as parent monolith to obtain stationary phases with a variety of surface chemistries for liquid chromatography and capillary electrochromatography. Functionalization is performed by opening the accessible 2,3-epoxypropyl groups of the monolith with a suitable reagent. The number of 2,3-epoxypropyl groups which are accessible before and after the functionalization reaction, and the grafting yield, are important parameters, required both to optimize functionalization and to interpret the chromatographic performance of functionalized monoliths. In this work, a method capable of provi…
Water Sorption on Mesoporous Aluminosilicate MCM-41
1995
Characterization of the interaction of water with the highly ordered mesoporous solid MCM-41 (pore diameter ∼2.5 nm) is undertaken with the aid of several techniques (adsorption gravimetry, X-ray diffraction, Fourier transform infrared spectroscopy, and controlled rate-evolved gas analysis). The relatively complex water-MCM-41 interactions are characterized by a type V isotherm indicating an initial repulsive character followed by a capillary condensation step of the adsorbate. This highlights both hydrophobic and hydrophilic properties of this potential model mesoporous adsorbent.
A dynamic panel study on digitalization and firm's agility: What drives agility in advanced economies 2009–2018
2021
Abstract Firm agility today is not a factor of competitiveness or success but a survival instrument on the market. Disruptive innovations and technological advancement, together with digitalization, change the role of firm agility. We show that the link between the national/industry level of digitalization and firm agility is statistically robust and essential. We study the link on data from 2009 to 2018 in fifteen EU advanced economies using dynamic panel data modeling. The digitalization impact level differs across firms by ownership type (family to non-family firms). Agility in family firms is strongly influenced by the national/industry level of digitization and investments in intangibl…
La formation continue contre le chômage, une vision économique réévaluée de l'investissement éducatif ?
1995
Article repris dans problèmes économiques, n° 2472, du 15 mai 1996, pp. 7-15, sous le titre "Les études supérieures assurent-elles une protection contre le chômage ? Une comparaison internationale"; International audience; Dans un contexte de croissance des études supérieures, différenciée selon les pays et les sexes, quelle protection celles-ci assurent-elles contre le chômage ? L'auteur présente une analyse détaillée de cette protection selon le sexe, l'âge ou l'étape dans la carrière, pour les pays de l'OCDE. Les résultats en sont parfois surprenants. Puis il propose des explications à ces variations. Il montre enfin comment la théorie du capital humain a dû être aménagée pour pouvoir re…
Le società: le società di capitali - Vol. II
2017
The text offers a systematic reconstruction of Italian company law.