Search results for "CERAMICS"
showing 10 items of 1599 documents
Introducing an amine functionality at the block junction of amphiphilic block copolymers by anionic polymerization strategies
2011
A series of block copolymers bearing a single amino in-chain functionality was synthesized via anionic polymerization of styrene and ethylene oxide. By means of both a conventional and a continuous setup, living polystyrene was quantitatively end functionalized with an oxirane (DBAG) prior to the polymerization of the poly(ethylene oxide) segment. The in-chain amine was conjugated with a fluorescent dye.
Crucial dependence of excimer laser toughness of “wet” silica on excess oxygen
2011
Creation of point defects by ArF (6.4 eV) and F2 laser (7.9 eV) irradiation in synthetic “wet” silica glass thermally loaded with interstitial O2 molecules was studied by optical absorption, electron paramagnetic resonance and infrared absorption. The presence of excess oxygen caused a significant increase of laser-induced ultraviolet (UV) absorption, which was 4 times (7.9 eV-irradiation) and > 20 times stronger (ArF irradiation) as compared to O2-free samples. The spectral shape of photoinduced absorption nearly completely coincided with the spectral shape of oxygen dangling bonds (NBOHC) in 3 to 6.5 eV regions. The contribution of Si dangling bonds (E' centers) was less than few % and wa…
On the effectiveness of Finite Element simulation of orthogonal cutting with particular reference to temperature prediction
2007
Abstract Finite Element simulation of orthogonal cutting is nowadays assuming a large relevance; in fact a very large number of papers may be found out in technical literature on this topic. In recent years, numerical simulation was performed to investigate various phenomena such as chip segmentation, force prediction and tool wear. On the other hand, some drawbacks have to be highlighted; due to the geometrical and computational complexity of the updated-Lagrangian formulation mostly used in FE codes, a cutting time of only a few milliseconds can be effectively simulated. Therefore, steady-state thermal conditions are not reached and the simulation of the thermal phenomenon may be ineffect…
Micro and macro mechanical characterization of friction stir welded Ti–6Al–4V lap joints through experiments and numerical simulation
2013
Abstract Lap joints of Ti–6Al–4V were produced and the effect of the main process parameters was studied through macro and micro investigations highlighting mechanical resistance, microhardness profiles, grain size and phase distributions. A dedicated numerical model was used to link the input process parameters to temperature and strain distributions and to the final microstructure in the welded joint. It is found that the strain produced in the stir zone by proper combination of process parameters plays a fundamental role in the final microstructure and mechanical properties of the joints.
CDRX modelling in friction stir welding of AA7075-T6 aluminum alloy: analytical approaches
2007
Abstract Friction stir welding (FSW) is an energy efficient and environmentally “friendly” (no fumes, noise, or sparks) welding process, during which the workpiece are welded together in a solid-state joining process at a temperature below the melting point of the workpiece material under a combination of extruding and forging. Significant microstructural evolution takes place during FSW: in particular continuous dynamic recrystallization (CDRX) phenomena result in a highly refined grain structure in the weld nugget and strongly affect the final joint resistance. In the paper two different analytical models aimed to the determination of the average grain size due to continuous dynamic recry…
Weighting non-covalent forces in the molecular recognition of C60. Relevance of concave–convex complementarity
2008
The relative contributions of several weak intermolecular forces to the overall stability of the complexes formed between structurally related receptors and [60]fullerene are compared, revealing a discernible contribution from concave–convex complementarity. Viruela Martin, Pedro Manuel, Pedro.M.Viruela@uv.es ; Viruela Martin, Rafael, Rafael.Viruela@uv.es ; Orti Guillen, Enrique, Enrique.Orti@uv.es
A water-soluble hexa-peri-hexabenzocoronene: synthesis, self-assembly and role as template for porous silica with aligned nanochannels
2005
A water-soluble hexa-peri-hexabenzocoronene was prepared and shown to undergo ordered columnar self-assembly either in water solution or bulk and therefore served as template for the fabrication of porous silica with aligned nanochannels.
Surfactant-assisted synthesis of titanium nanoMOFs for thin film fabrication
2021
We use dodecanoic acid as a modulator to yield titanium MOF nanoparticles with good control of size and colloid stability and minimum impact to the properties of the framework to enable direct fabrication of crystalline, porous thin films. ispartof: CHEMICAL COMMUNICATIONS vol:57 issue:72 pages:9040-9043 ispartof: location:England status: published
Multiphoton process investigation in silica by UV femtosecond laser
2022
We investigated the interaction processes between high intensity femtosecond ultraviolet laser pulses and amorphous silica, leading to permanent refractive-index changes that are at the basis of advanced manufacturing for photonics devices. The experiment, carried out as a function of the laser power, improves our understanding on the strong-field ionization process by the monitoring of the 1.9 eV and 2.65 eV emissions, related to nonbridging oxygen hole centers and self-trapped exciton, respectively, induced in the exposed glass region. Our results clearly proved that the UV laser light band-to-band absorption is allowed in the multiphoton ionization limit, whose consecutive relaxation lea…
Local structural investigation of hafnia-zirconia polymorphs in powders and thin films by X-ray absorption spectroscopy
2019
Björn Matthey (Fraunhofer IKTS, Dresden) is acknowledged for providing HfO2 and ZrO2 powders on short notice after DESY’s renowned customs office punished us. Parts of this research were carried out at Petra III at DESY, a member of the Helmholtz Association (HGF). The experiments on single Si:HfO2 thin film samples were performed at the CLAESS beamline at ALBA Synchrotron with the collaboration of ALBA staff. We would like to thank Edmund Welter for assistance (in using beamline P65) and DESY for enabling this research for proposal no. 20160591 and for travel support. T.S. acknowledges the German Research Foundation (DFG) for funding this work in the frame of the project “Inferox” (project…