Search results for "CERAMICS"
showing 10 items of 1599 documents
Crystal chemical characterization of mullite-type aluminum borate compounds
2017
Abstract Al-rich aluminum borates were prepared by different synthesis routes using various Al/B ratios, characterized by diffraction methods, spectroscopy and prompt gamma activation analysis. The 11B NMR data show a small amount of BO4 species in all samples. The chemical analysis indicates a trend in the Al/B ratio instead of a fixed composition. Both methods indicate a solid solution Al5−xB1+xO9 where Al is substituted by B in the range of 1–3%. The structure of B-rich Al4B2O9 (C2/m, a=1488 pm, b=553 pm, c=1502 pm, s=90.6°), was re-investigated by electron diffraction methods, showing that structural details vary within a crystallite. In most of the domains the atoms are orderly distrib…
A comparative study of photocatalytically active nanocrystalline tetragonal T zyrcon- type and monoclinic scheelite-type bismuth vanadate
2018
The authors from Vinča Institute of Nuclear Sciences acknowledge the financial support of the Ministry of Education, Science and Technological Development of the Republic of Serbia (Project no: 172056 ). The work of K. Smits was supported by Latvian National Research Program IMIS2 (Grant no. 302/2012 ).
Influence of Glass Additions on Illitic Clay Ceramics
2020
A mixture of an illitic clay and waste glass was prepared and studied during the sintering process. The illitic clay, from the Liepa deposit (Latvia), and green glass waste (GW) were disintegrated to obtain a homogeneous mixture. The addition of disintegrated GW (5&ndash
Advanced Strategies and Materials for Reinforcing Normal and Disturbed Regions in Brick Masonry Columns
2016
This work presents the results of an experimental investigation on the behavior of 42 solid clay brick masonry columns internally strengthened by fiber-reinforced polymer (FRP) fabrics or stainless steel grids placed in horizontal mortar joints. In some cases, every course, and in other cases, alternate courses were reinforced with steel grids, carbon, and basalt FRP fabrics. Monotonic compressive loading tests were carried out under concentric and eccentric loads. Eccentric tests were carried out by loading the specimens on a reduced area with respect to the entire cross section, producing a disturbed region (D-region). A detailed characterization of the constituent materials was made expe…
Experimental investigation on the effect of mortar grade on the compressive behaviour of FRCM confined masonry columns
2018
Abstract The use of Fiber Reinforced Cementitious Mortar (FRCM) systems for structural retrofitting of masonry structures has become increasingly popular in the last years, due to the capability of this technique in overcoming some of the drawbacks related to the adoption of resin-based composites. Recent studies investigated on the effect of FRCM wraps on the compressive behaviour of concrete members and demonstrated as the application of mortar-based composites allows increasing the strength and, above all, the ductility of the column. The main difference with FRP confined columns is related to the different post-peak behaviour, characterized by a softening branch. Differently, few studie…
Comparative experimental analysis on the compressive behaviour of masonry columns strengthened by FRP, BFRCM or steel wires
2017
Abstract In the last decade, several studies have investigated the application of Fibre Reinforced Polymer (FRP) wraps to masonry piers in order to provide a confinement effect and enhance compressive strength and ductility. Although this technique has proved to be quite effective, various drawbacks arise when organic resins are used to bind fibres. To solve these problems, different techniques have been developed to be used as alternative methods for enhancing the structural performances of weak masonry columns. Among these, the use of Basalt Fibre Reinforced Cementitious Matrix (BFRCM) wrapping, or the application of steel wires at mortar joints. This paper presents the results of an expe…
Influence of different parameters on drug release from hydrogel systems to a biomembrane model. Evaluation by differential scanning calorimetry techn…
2000
A comparative study on the drug release capacity of four water swellable polymeric systems was carried out by differential scanning calorimetry (DSC). The polymeric systems chosen were alpha,beta-polyaspartahydrazide (PAHy) crosslinked by glutaraldehyde (GLU) (PAHy-GLU) or by ethyleneglycoldiglycidylether (EGDGE), (PAHy-EGDGE), polyvinylalcohol (PVA) crosslinked by glutaraldehyde (PVA-GLU) and alpha,beta-poly(N-hydroxyethyl)-DL-aspartamide (PHEA) by gamma irradiation (PHEA-gamma matrices). The degree of crosslinking for PAHy-GLU, PAHy-EGDGE and PVA-GLU samples was about 0.4 and 0.8. These hydrogels were characterized as free of drugs and were loaded with diflunisal (DFN) (approximately 2.5%…
Micromechanisms of load transfer in a unidirectional carbon fibre–reinforced epoxy composite due to fibre failures. Part 1: Micromechanisms and 3D an…
2006
This study gives a detailed analysis of load distributions around fibre breaks in a composite and the mechanisms involved in load transfer. In contrast to other studies reported in the literature the analysis considers different configurations of composite damage from the failure of a few fibres to the failure of many. The model considers the elastic case with and without debonding at the broken fibre/matrix interface. In this way, the usual limitations of the finite element approach are overcome so as to take into account the numbers and interactions of broken fibres whilst maintaining an evaluation of the various fields involved, in particular the stress fields associated with fibre failu…
Local structure of ball-milled LaNi5 hydrogen storage material by Ni K-edge EXAFS
2010
Abstract Local structure of the nanostructured LaNi5 hydrogen storage alloys, prepared by ball-milling, has been studied using Ni K-edge extended X-ray absorption fine structure spectroscopy. Results indicate that the ball-milling up to 100 h results in the production of nanoparticles characterized by large atomic disorder and slightly reduced unit-cell volume, compared to the bulk LaNi5. High temperature annealing appears to help in partial recovery of atomic order in the ball-milled samples; however, long-time ball-milled samples retain large disorder even after the high temperature annealing. The results suggest that the large disorder and the reduced unit-cell volume might be causing a …
CO2 laser-induced structure changes in lead zirconate titanate Pb(Zr0.58Ti0.42)O3 sol–gel films
2003
Based on absorption spectra of lanthanum modified lead zirconate titanate Pb0.9La0.1(Zr0.65Ti0.35)O3 (PLZT10/65/35) ferroelectric ceramics an idea of local and selective treatment of lead zirconite titanate Pb(ZrXTi1−X)O3 (PZT) sol–gel film in the multi-layer structure by CO2 laser radiation was formulated. The possibility to obtain PZT perovskite film on the SiO2/Si substrate by irradiation with CO2 laser was shown experimentally. X-ray studies revealed the PZT perovskite structure ratio growth at the expenses of pirochlore structure with an increased power density of laser radiation.