Search results for "CHIMIE"
showing 10 items of 170 documents
Dynamic tuning of the director field in liquid crystal shells using block copolymers
2020
When an orientationally ordered system, like a nematic liquid crystal (LC), is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director (the average molecule orientation) is tangential to the interface, but upon approaching the temperature TNI of the nematic– isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial …
Les phénols de la lignine et le 13C, traceurs de l'origine des matières organiques du sol
2001
Abstract In spodosols of Gascony (France), conversion of maritime pine stands into maize cropping leads to an incorporation of maize organic matter, which changed the isotopic (δ13C) and phenolic signature in A and L horizons of soil. Hydrolysis of phenol lignin in forests and cultivated soils showed the predominance of vanillic units under forest and the early but moderate incorporation of cinnamic acids. Incorporation of syringic units appeared higher, related to a large maize production of stable syringic phenols. Syringic units represented a long-term marker of maize inputs in soils, whereas vanillic units revealed the degradation of forest organic matter.
Biochemical and physiological studies of the small heat shock protein Lo18 from the lactic acid bacterium Oenococcus oeni
2001
47 ref.; International audience
Model Based Targeting of IL-6-Induced Inflammatory Responses in Cultured Primary Hepatocytes to Improve Application of the JAK Inhibitor Ruxolitinib
2017
IL-6 is a central mediator of the immediate induction of hepatic acute phase proteins (APP) in the liver during infection and after injury, but increased IL-6 activity has been associated with multiple pathological conditions. In hepatocytes, IL-6 activates JAK1-STAT3 signaling that induces the negative feedback regulator SOCS3 and expression of APPs. While different inhibitors of IL-6-induced JAK1-STAT3-signaling have been developed, understanding their precise impact on signaling dynamics requires a systems biology approach. Here we present a mathematical model of IL-6-induced JAK1-STAT3 signaling that quantitatively links physiological IL-6 concentrations to the dynamics of IL-6-induced …
Computing absolute free energies of disordered structures by molecular simulation
2009
We present a Monte Carlo simulation technique by which the free energy of disordered systems can be computed directly. It is based on thermodynamic integration. The central idea is to construct an analytically solvable reference system from a configuration which is representative for the state of interest. The method can be applied to lattice models (e.g., the Ising model) as well as off-lattice molecular models. We focus mainly on the more challenging off-lattice case. We propose a Monte Carlo algorithm, by which the thermodynamic integration path can be sampled efficiently. At the examples of the hard sphere liquid and a hard disk solid with a defect, we discuss several properties of the …
Comprehension and food analysis of a fermented mixture of animal proteins and vegetable proteins : influence on the physico-chemistry and the accepta…
2017
Many problems have been identified following the attempts to incorporate vegetal proteins in our food. In particular, off-flavor, taste or texture have been highlighted as real barriers to the acceptability of plant products by consumers. The consumer himself is also an important determinant regarding the term "acceptability." So, in order to develop a new fermented product based on pea, two issues were studied: the product and the consumer. To understand the physico-chemical properties and the acceptability of pea protein-based fermented products, several factors have been investigated in successive stages such as culture, positive health and environmental claims, lactic acid bacteria stra…
Sedimentological and diagenetic influences on low permeability properties of the Middle Jurassic limestones (Paris Basin, France)
2009
A detailed sedimentological, geochemical and mineralogical study is carried out on the Early Bajocian to Early Callovian (Middle Jurassic) limestones of the Paris Basin. Deposits include 18 lithofacies which are stacked into 10 third-order depositional sequences. Our geochemical study including a compilation of bibliographic data allows us to refine the existing sea surface palaeotemperature pattern. A cooling from the latest Early Bajocian to the Late Bajocian and a subsequent warming from the earliest Callovian to the Early/Middle Callovian transition are described using a proxy of sea surface temperatures. Together with δ13C and mineralogical data, our new δ18O values suggest a palaeo-cl…
La réception des Noces chimiques d'Andreae chez Novalis [in] Jean-Pierre Brach, Aurélie Choné: Un roman alchimique à Strasbourg 1616-2016. Ein al…
2018
International audience
Chemistry for wine and wine for health: a propaganda film in benefit of french wines at the beginning of the XXth century
2022
La Cinématographie est une merveilleuse méthode d'éducation générale et de formation technique » 1. Pour compléter cette sentence avancée par le Ministère de l'Agriculture en 1928 en introduction d'un ouvrage sur le cinéma agricole, ajoutons qu'en ce début de XX e siècle, le cinéma s'impose aussi comme un nouvel et formidable outil de propagande pour les productions, les méthodes et les institutions agricoles françaises. En effet, dès le début des années 1920, le Ministère de l'Agriculture, en lien avec des scientifiques ou des sociétés privées, se lance dans l'édition cinématographique afin de montrer, sous la forme de documentaires principalement, les multiples facettes qui forment l'agri…
Tuning the defect configurations in nematic and smectic liquid crystalline shells
2013
Thin liquid crystalline shells surrounding and surrounded by aqueous phases can be conveniently produced using a nested capillary microfluidic system, as was first demonstrated by Fernandez-Nieves et al. in 2007. By choosing particular combinations of stabilizers in the internal and external phases, different types of alignment, uniform or hybrid, can be ensured within the shell. Here, we investigate shells in the nematic and smectic phases under varying boundary conditions, focusing in particular on textural transformations during phase transitions, on the interaction between topological defects in the director field and inclusions in the liquid crystal (LC), and on the possibility to rel…