Search results for "CID"
showing 10 items of 19479 documents
Modelling the dependence on medium, ionic strength and temperature of N-acetyl-L-cysteine acid-base properties, and its interactions with Na+, Mg2+, …
2017
N-acetyl-L-cysteine (NAC) is the acetylated precursor of L-cysteine, and it is strictly related to glutathione activity. NAC is used in medicine since more than 30 years, primarily as a mucolytic, though its properties are exploited in the treatment of many diseases, such as acute poisoning by acetaminophen (restoring protective levels of glutathione), HIV, contrast-induced nephropathy, type-2 DM (diabetes mellitus), and it also looks promising in the treatment of several psychiatric disorders [1]. This resulted in a huge number of scientific contributions published during the years on NAC (searching in some scientific databases, more than 10000 papers appear). As expected, most of them are…
Adaptation to stressful environments : invasion success of the Colorado potato beetle (Leptinotarsa decemlineata)
2018
Biological invasions, specifically human-induced dispersals, are one of the major threats to our biodiversity and are predicted to increase. Invasive pests provide an opportunity to study whether adaptation to human-induced environments could promote invasions to other human-induced environments. One major anthropogenic selection pressure is created by pesticides, and pests can be exposed to various pesticides in their native, as well as introduced, ranges. I investigated whether exposure to anthropogenic selection (i.e. insecticides and herbicides) and exposure to multiple anthropogenic stressors selects for higher stress tolerance. I also tested whether parental prolonged diapause or inse…
A Theoretical and Experimental Investigation of the Spectroscopic Properties of a DNA-Intercalator Salphen-Type ZnIIComplex
2014
The photophysical and DNA-binding properties of the cationic zinc(II) complex of 5-triethylammonium methyl salicylidene ortho-phenylenediiminato (ZnL 2 + ) were investi- gated by a combination of experimental and theoretical methods. DFT calculations were performed on both the ground and the first excited states of ZnL 2 + and on its possi- ble mono- and dioxidation products, both in vacuo and in selected solvents mimicked by the polarizable continuum model. Comparison of the calculated absorption and fluores- cence transitions with the corresponding experimental data led to the conclusion that visible light induces a two-elec- tron photooxidation process located on the phenylenediimi- nato…
Acetic acid leaching of neodymium magnets and iron separation by simple oxidative precipitation
2022
Neodymium-iron-boron (NdFeB) has become the most prominent permanent magnet alloy, with a wide variety of applications and an ever-increasing demand. Their recycling is important for securing the supply of critical raw materials used in their manufacturing. The use of organic acids such as acetic acid has been of recent interest for the recycling of waste NdFeB magnets. Despite achieving good leaching efficiencies, the published literature has not properly investigated the effects of key factors influencing the acetic acid leaching process and their respective interactions, which has lead to conflicting findings as to what conditions are optimal. The present work goes to show that no such o…
Recurrent lumbar disc herniation: Is there a correlation with the surgical technique? A multivariate analysis
2019
Purpose: The recurrence of a lumbar disc herniation (LDH) is a common cause of poor outcome following lumbar discectomy. The aim of this study was to assess a potential relationship between the incidence of recurrent LDH and the surgical technique used. Furthermore, we tried to define the best surgical technique for the treatment of recurrent LDH to limit subsequent recurrences. Materials and Methods: A retrospective study was conducted on 979 consecutive patients treated for LDH. A multivariate analysis tried to identify a possible correlation between (1) the surgical technique used to treat the primary LDH and its recurrence; (2) technique used to treat the recurrence of LDH and the secon…
Social psychological aspects of ACL injury prevention and rehabilitation: An integrated model for behavioral adherence
2017
Managing rehabilitation for ACL injury is dependent on uptake of, and compliance with, medical and safety recommendations. In this paper, we propose a multi-theory model that integrates self-determination theory and the theory of planned behavior to identify the motivational determinants ACL injury prevention and management behaviors and the processes involved. nonPeerReviewed
La relació entre història de la llengua i història literària
2021
La relació entre la disciplina història de la llengua i la disciplina història de la literatura ha estat una relació de subordinació, tant des del punt vista conceptual com metodològic. La primera ha estat subordinada a la segona. En aquest article tractem en primer lloc de les circumstàncies i els esdeveniments històrics que han determinat aquesta situació de subordinació: la identificació cultural entre llengua i literatura (però amb la supeditació de la primera a la segona), el naixement de la lingüística romànica (que, paradoxalment, no va afavorir l’autonomia de la història de la llengua) i la desclosa de les cultures nacionals, que també van donar prioritat a la literatura nacional. E…
Efficient regio- and stereoselective access to novel fluorinated ?-aminocyclohexanecarboxylates
2013
A regio- and stereoselective method has been developed for the synthesis of novel fluorinated 2-aminocyclohexanecarboxylic acid derivatives with the fluorine attached to position 4 of the ring. The synthesis starts from either cis- or trans-β-aminocyclohex-4-enecarboxylic acids and involves regio- and stereoselective transformation of the ring C–C double bond through iodooxazine formation and hydroxylation, followed by hydroxy–fluorine or oxo–fluorine exchange.
Acaricidal Activity of Bufadienolides Isolated from Drimia pancration against Tetranychus urticae, and Structural Elucidation of Arenobufagin-3-O-α-L…
2022
Chemical characterization of the bulbs of Drimia pancration was conducted to isolate four steroidal saponins (1–4). Earlier, we focused on the structural elucidation of compounds 1–3. Herein, by means of 1H-NMR, 13C-NMR, Nuclear Overhauser Effects (NOE), and 2D-NMR spectra, the full stereochemical structure of 4 is reported, and all the 1H and 13C signals are assigned. Compounds 1–4 were tested for their acaricidal properties against the two-spotted spider mite Tetranychus urticae. Our results showed excellent activity of compound 1, with an LD50 (µg/cm2) of 0.29 and a LD90 (µg/cm2) of 0.96, whereas compounds 2, 3, and 4 showed moderate activity. Furthermore, t…
Nuove dipendenze del terzo millennio: l'utilizzo di steroidi anabolizzanti come sostanza d'abuso
2005
Obiettivo. L'abuso di sostanze anabolizzanti si sta configurando come un problema di rilevanza psicosociale. L'uso di steroidi anabolizzanti in questi ultimi anni si è spostato dalla pratica sportiva professionale allo sport amatoriale e ad ambiti occupazionali particolari (buttafuori, modelli, ect.). La letteratura indica l'assuntore di steroidi come un poliassuntore che mette in atto condotte pericolose e aggressive per sé e per gli altri. L'obiettivo di questo studio è indagare le abitudini, le condotte di vita e il profilo psicologico di un gruppo di soggetti che frequentano centri sportivi nella città di Palermo (Italia), per verificare come l'utilizzo sconsiderato di sostanze anaboliz…