Search results for "CID"
showing 10 items of 19479 documents
Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane
2017
Abstract Image A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations. peerReviewed
Herbicidal activity of essential oils extracted from different Eucalyptus and Citrus species against Avena fatua
2018
Weeds are a serious threat for crop yield and quality since they compete for water, light, soil nutrients and space. Avena fatua L. is one of the ten worst annual weeds of temperate agricultural regions of the world. It could reduce annual crop yields by as much as 70%. The main traits of this species include high fecundity, self-pollination, and variable degrees of primary seed dormancy. A. fatua is in the 4th position of herbicide resistant weeds in the word. It has developed resistance to eight different modes of action. .. The European legislation also supports weed control by means of Integrated Pest Management. It is important to manage A. fatua interference preventing environmental p…
Ginger and Turmeric Essential Oils for Weed Control and Food Crop Protection
2019
Ginger and turmeric are two food ingredients that are in high demand due to their flavor and positive effects on health. The biological properties of these spices are closely related to the aromatic compounds they contain. The chemical compositions of their essential oils and their in vitro phytotoxic activity against weeds (Portulaca oleracea, Lolium multiflorum, Echinochloa crus-galli, Cortaderia selloana, and Nicotiana glauca) and food crops (tomato, cucumber, and rice) were studied. Forty-one compounds, accounting for a relative peak area of 87.7% and 94.6% of turmeric and ginger essential oils, respectively, were identified by Gas Chromatography&ndash
Evaluation of biocidal potential of some plant species from the Mediterranean wild flora
Plant essential oils in controlling fungal colonization on wooden substrate
2021
In order to control fungal colonization and the related deterioration process of cultural objects, several chemical compounds are actually utilised. These products generally are toxic, not biodegradable and persisting for long time in the environment, also acting on not-targeted biological systems. In this study, specifically to wooden cultural object, Origanum vulgare L. and Thymus vulgaris L. essential oils are proposed as green biocides to contrast the development of Penicillium chrysogenum, Aspergillus flavus and Aspergillus niger fungal species. The aim is replacing toxic products with natural molecules, proposing alternative methodologies supporting the using of non-toxic novel compou…
Infortunio sul lavoro e Covid: molto strepito per nulla?
2020
The classification of coronavirus infection as a work accident has raised some concerns about the possibility of an enlargement of the employer’s civil and criminal liability. Instead the norm confirms the jurisprudence’s interpretation of the concept of work accident, and can be used to read correctly, in harmony with the following interventions of the legislator, the article 2087 of the italian civil code.
The mitogen-activated protein kinase p38 pathway is conserved in metazoans: Cloning and activation of p38 of the SAPK2 subfamily from the sponge Sube…
2000
Our recent data suggest that during auto- and allograft recognition in sponges (Porifera), cytokines are differentially expressed. Since the mitogen-activated protein kinase (MAPK) signal transduction modulates the synthesis and release of cytokines, we intended to identify one key molecule of this pathway. Therefore, a cDNA from the marine sponge Suberites domuncula encoding the MAPK was isolated and analyzed. Its encoded protein is 366 amino acids long (calculated Mr 42 209), has a TGY dual phosphorylation motif in protein kinase subdomain VIII and displays highest overall similarity to the mammalian p38 stress activated protein kinase (SAPK2), one subfamily of MAPKs. The sponge protein w…
Conservation of the positions of metazoan introns from sponges to humans
2002
Abstract Sponges (phylum Porifera) are the phylogenetic oldest Metazoa still extant. They can be considered as reference animals (Urmetazoa) for the understanding of the evolutionary processes resulting in the creation of Metazoa in general and also for the metazoan gene organization in particular. In the marine sponge Suberites domuncula , genes encoding p38 and JNK kinases contain nine and twelve introns, respectively. Eight introns in both genes share the same positions and the identical phases. One p38 intron slipped for six bases and the JNK gene has three more introns. However, the sequences of the introns are not conserved and the introns in JNK gene are generally much longer. Intron…
Regulation of motility of cells from marine sponges by calcium ions
1996
Sponges are known not to contain muscle and nerve cells. Since sponge cells are characterized by high motility we determined the effect of intracellular calcium ion concentration ([Ca2+]i) on their motility. Addition of the Ca2+ ionophore ionomycin to dissociated cells from the marine sponge Suberites domuncula caused in Ca(2+)-containing artificial seawater (ASW) an increase in motility from 0.2 micron/min (absence of the ionophore) to 3.7 microns/min (presence of ionomycin). When the experiments were performed in Ca(2+)-free medium, no effect of ionomycin could be observed. In parallel experiments the changes of [Ca2+]i using the dye Fura-2 were measured. The experiments revealed that ion…