Search results for "COLUMN"
showing 10 items of 1301 documents
Practical Syntheses of Terrylene Chromophores from Naphthalene and Perylene Building Blocks
2017
A facile and efficient method to synthesize terrylene imides, a unique class of chromophores, and their derivatives from commercially available naphthalene and perylene building blocks is reported. We developed an extremely efficient Suzuki/C-H-arylation coupling cascade with Pd2(dba)3/PCy3 (dba = dibenzylidenacetone, Cy = cyclohexyl) as the catalyst and highly soluble naphthalene derivatives as starting materials. This efficiency allows purification via precipitation and crystallization, avoiding time-consuming column chromatography. For the first time, the highly soluble 3,4,11,12-terrylene tetraester was prepared in gram scale with yields up to 75 % which thus becomes a versatile startin…
Hydrochemical mercury distribution and air-sea exchange over the submarine hydrothermal vents off-shore Panarea Island (Aeolian arc, Tyrrhenian Sea)
2017
Abstract There is a growing concern about the mercury (Hg) vented from submarine hydrothermal fluids to the marine surrounding and exchange of dissolved gaseous mercury (DGM) between the sea surface and the atmosphere. A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out in 2015 (15–17th June and 17–18th November), in order to investigate the concentration of Hg species in hydrothermal fluids and the vertical distribution in the overlying water column close to the submarine exhalative area. Specific sampling methods were employed by Scuba divers at five submarine vents located along the main regional tecton…
The giant inoceramid Platyceramus platinus as a high-resolution paleoclimate archive for the Late Cretaceous of the Western Interior Seaway
2018
Abstract Platyceramus platinus was a giant inoceramid bivalve that inhabited the outer shelf environments of the Western Interior Seaway (WIS) in North America. With axial heights typically exceeding 1 m, the shells of this species potentially serve as a unique high-resolution geochemical proxy archive for Late Cretaceous paleoclimate. Here we present the first sclerochronological investigation of P. platinus shells to evaluate the usefulness of this species as an archive of short-term (e.g., seasonal to inter-annual) paleoenvironmental variability. We analyzed the growth patterns, the stable oxygen (δ18O) and carbon (δ13C) isotope values of well-preserved P. platinus shell fragments from t…
Black shale deposition during Toarcian super-greenhouse driven by sea level
2013
Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a…
Trace element behaviour in seawater during Etna's pyroclastic activity in 2001: Concurrent effects of nutrients and formation of alteration minerals
2010
volcanic ash ; trace element leaching ; kinetic experiments ; chlorophyll-alpha; International audience; The eruption of Etna in Sicily on 13 July 2001 marked the most intense activity of the volcano in the last 300 years. The eruption occurred while the oceanographic cruise ANSIC 01 was being conducted to the east of Sicily, presenting a unique opportunity for the investigation of the chemical effects on the marine system during a period of significant (similar to 1 g m(-2)) ash deposition. Comparison of trace element data with measured concentrations from the oceanographic cruise JUVENILE 99, carried out two years before, indicates large enrichments of V. Cr, Mn, Fe, Co, Cu and Pb. We att…
Productivity modes in the Mediterranean Sea during Dansgaard–Oeschger (20,000–70,000 yr ago) oscillations
2013
The study of planktonic organisms during abrupt climatic variations of the last glacial period (Dansgaard-Oeschger oscillations, D-O) may reveal important insights on climatic, oceanographic and biological interactions. Here we present planktic foraminifera and coccolithophore data collected at the Ocean Drilling Program Site 963 (Sicily Channel), with a mean sampling resolution of respectively 43.5 and 98.9. yr, over the interval between 70,000 and 20,000. yr ago. The paleoenvironmental reconstruction suggests that three different scenarios can be seen across each D-O cycle: 1. oligotrophic surface water and a deep thermocline for the early Interstadials; 2. a Deep Chlorophyll Maximum and …
Response of the aquatic plants and mollusc communities in Lake Kojle (central Europe) to climatic changes between 250 BCE and 1550 CE
2018
Abstract Sediments of Lake Kojle, located in the transition zone between the nemoral and boreal biogeographic zones in NE Poland, were analysed to verify the response of the aquatic ecosystem to major environmental changes. High-resolution plant macrofossil, mollusc and pollen data were derived from two replicate parallel cores and revealed several shifts in the biota composition within the littoral zone between 250 BCE and 1550 CE. The reaction of the aquatic ecosystem to temperature changes was found to be minor, which is ascribed to the mitigating influence of water and the wide ecological tolerance of most of the taxa. Najas marina, considered as an indicator of warmer conditions, was t…
Modern sedimentary analogues and integrated monitoring to understand varve formation in the Mediterranean Lake Montcortès (Central Pyrenees, Spain)
2018
Este artículo contiene 13 páginas, 6 figuras, 1 tabla.
Water mass exchange and variations in seawater temperature in the NW Tethys during the Early Jurassic: evidence from neodymium and oxygen isotopes of…
2009
10 pages; International audience; Oxygen and neodymium isotope analyses performed on biostratigraphically well-dated fish remains recovered from the Hettangian to Toarcian of the Paris Basin were used to reconstruct variations of Early Jurassic seawater temperature and to track oceanographic changes in the NW Tethys. Our results indicate a strong correlation between δ18O trends recorded by fish remains and belemnites, confirming the paleoenvironmental origin of oxygen isotope variations. Interestingly, temperatures recorded by pelagic fishes and nektobenthic belemnites and bottom dwelling fishes are comparable during the Late Pliensbachian sea-level lowstand but gradually differ during the …
Applicability and consequences of the integration of alternative models for CO<sub>2</sub> transfer velocity into a process-based lake mo…
2019
Abstract. Freshwater lakes are important in carbon cycling, especially in the boreal zone where many lakes are supersaturated with the greenhouse gas carbon dioxide (CO2) and emit it to the atmosphere, thus ventilating carbon originally fixed by the terrestrial system. The exchange of CO2 between water and the atmosphere is commonly estimated using simple wind-based parameterizations or models of gas transfer velocity (k). More complex surface renewal models, however, have been shown to yield more correct estimates of k in comparison with direct CO2 flux measurements. We incorporated four gas exchange models with different complexity into a vertical process-based physico-biochemical lake mo…