Search results for "COMPOSITE"

Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer.

2018

We report a new chiral coordination polymer, prepared from the cytidine 5′-monophosphate (CMP) nucleotide, capable of separating efficiently (enantiomeric excess of ca. 100%) racemic mixtures of L- and D-Asp in a temperature-dependent manner. The crystal structure of the host–guest adsorbate, with the D-Asp guest molecules loaded within its channels, could be solved allowing a direct visualization of the chiral recognition process.

Phase and structural transformations in annealed copper coatings in relation to oxide whisker growth

2015

Abstract We describe structural and phase transformation in copper coatings made of microparticles during heating and annealing in air in the temperature range up to 400 °C. Such thermal treatment is accompanied by intensive CuO nanowhisker growth on the coating surface and the formation of the layered oxide phases (Cu 2 O and CuO) in the coating interior. X-ray diffraction and focused ion beam (FIB) are employed to characterize the multilayer structure of annealed copper coatings. Formation of volumetric defects such as voids and cracks in the coating is demonstrated.

Core-Shell Cylindrical Polymer Brushes with New Properties: A Mini-Review

2015

Effects of confinement level, cross-section shape and corner radius on the cyclic behavior of CFRCM confined concrete columns

2014

Abstract The main results of an experimental research aiming to investigate the behavior of medium-size low-strength concrete columns wrapped with Carbon Fiber Reinforced Cementitious Matrix (CFRCM) under monotonic and cyclic compressive axial loads are presented. Thirty columns with circular, square and rectangular cross-sections were tested under monotonic and cyclic axial loads to investigate the effect of the confinement level, the cross-section shape and the corner radius on the stiffness, strength, and ductility of CFRCM confined concrete columns under cyclic loads. The results prove that CFRCM confining jackets provide substantial gain in compressive strength, deformability and absor…

Unsupervised change detection with kernels

2012

In this paper an unsupervised approach to change detection relying on kernels is introduced. Kernel based clustering is used to partition a selected subset of pixels representing both changed and unchanged areas. Once the optimal clustering is obtained the estimated representatives (centroids) of each group are used to assign the class membership to all others pixels composing the multitemporal scenes. Different approaches of considering the multitemporal information are considered with accent on the computation of the difference image directly in the feature spaces. For this purpose a difference kernel approach is successfully adopted. Finally an effective way to cope with the estimation o…

Refined equivalent single layer formulations and finite elements for smart laminates free vibrations

2014

A family of 2D refined equivalent single layer models for multilayered and functionally graded smart magneto-electro-elastic plates is presented. They are based on variable kinematics and quasi-static behavior for the electromagnetic fields. First, the electromagnetic state of the plate is determined by solving the strong form of the electromagnetic governing equations coupled with the corresponding interface continuity conditions and external boundary conditions. The electromagnetic state is then condensed into the plate kinematics, whose governing equations can be written using the generalized principle of virtual displacements. The procedure identifies an effective elastic plate kinemati…

Variable kinematics models and finite elements for nonlinear analysis of multilayered smart plates

2015

Abstract A variable kinematics approach for moderately large deflection analysis of smart magneto-electro-elastic multilayered plates is presented. The approach is based on the condensation of the electro-magnetic state into the plate kinematics, whose nonlinear strain–displacement relationships are expressed in the von Karman sense. This leads to models resulting in an effective mechanical plate, which takes the multifield coupling effects into account by the plate stiffness, inertia and loading characteristics, consistently defined as combinations of the layers material properties. By a unified approach, both equivalent single layer and layerwise models are developed formulating the assoc…

Influence of spatial delay on the modulational instability in a composite system with a controllable nonlinearity.

2017

A theoretical investigation of the modulational instability (MI) in a composite system with a nonlocal response function is presented. A composite system of silver nanoparticles in acetone is chosen, whose nonlinearity can be delicately varied by controlling the volume fraction of the constituents, thus enabling the possibility of nonlinearity management. A pump-probe counterpropagation configuration has been assumed, and the interplay between the competing nonlinearities and the nonlocalities in the MI dynamics is systematically explored. A different class of nonlocalities have been considered, and the study reveals that the nonlocality critically depends on the kind of nonlocal function. …

Functionalization of Graphene with Molecules and/or Nanoparticles for Advanced Applications

2019

Graphene is considered the material of the third millennium, due to its extraordinary electronic and mechanical properties, and due to the possibility to modulate its conductivity, flexibility, elasticity, transparency, and biocompatibility by bottom-up approach. The possibility to gather the proper- ties of graphene and graphene oxide with those of functional moieties or nanoparticles is herein reviewed. The synthetic approaches proposed, either covalent or noncovalent, are aimed to tune appropriately graphene’s properties for the realization of materials for advanced uses, such as bio- medical applications, sensors, catalysis, and energy devices. In particular, methods based on covalent l…

Fatigue Crack Growth for Different Ratios of Bending to Torsion in AlCu4Mg1

2008

The paper contains the fatigue crack growth test results obtained under proportional bending with torsion in AlCu4Mg1 aluminium alloy [1]. Specimens with rectangular cross sections and dimensions: length l = 90 mm, height w = 10 mm and thickness g = 8 mm were tested [2]. Each specimen had an external unilateral notch with depth 2 mm and radius ρ = 0.2 mm. The tests were performed under the stress ratio R = −1. The notches in the specimens were cut with a milling cutter and their surfaces were polished after grinding. The tests were realized on a fatigue test stand MZGS-100 where the ratio of torsion moment to bending moment was \( M_T (t)/M_B (t) = tg\alpha = \sqrt 3 /3,1{\text{ }}and\sqrt …