Search results for "CONDENSATION"
showing 10 items of 468 documents
Water-soluble polyesters from long chain alkylesters of citric acid and poly(ethylene glycol)
2007
Abstract Long chain aliphatic alcohols have been used as model compounds to develop a preparative method for a water-soluble material, which could be a carrier for triacontanol, a highly hydrophobic plant growth regulator. New polyesters from long chain aliphatic (C = 12, 18 and 22) mono-1-alkyl citrates and poly(ethylene glycol) were synthesized and characterized by NMR spectroscopy. The polyester containing the triacontyl moiety was obtained from mono-1-triacontyl citrate, which was synthesized from the corresponding alcohol extracted from the Agave fourcroydes . The molecular weight M ¯ n of the polyesters depends on experimental conditions during synthesis such as reaction time, atmosph…
Properties of trialkylamines as catalysts of resoles synthesis
2000
A series of the syntheses of phenol–formaldehyde resoles was carried out in the presence of trimethyl-, triethyl-, tripropyl-, and tributylamines and sodium hydroxide as catalysts for this process. The rate constants were calculated for the partial reactions identified in the synthesis. Also, the performance properties of the resins obtained and the hardened resin samples were estimated in simple tests. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 898–902, 2000
Synthesis of large-pore ordered mesoporous silicas containing aminopropyl groups
2005
Ordered mesoporous silicas with large-pore diameters incorporating aminopropyl groups in variable quantity have been synthesized via the co-condensation of tetraethyl orthosilicate (TEOS) and 3-tert-butyloxycarbonylaminopropyltriethoxysilane templated with nonionic surfactant P123 under acidic conditions. The deprotection of amino groups was then quantitatively achieved either by thermal treatment or acid hydrolysis followed by Et3N treatment, both routes leading to exactly the same materials. We showed that the free amino centers are fully accessible, by using the condensation of the amine function with benzaldehyde.
Observations of high concentrations of I2and IO in coastal air supporting iodine-oxide driven coastal new particle formation
2010
[1] Theoretical studies have predicted that concentrations of gaseous I2 and IO of the order of 80–100 ppt and 40–50 ppt, respectively, are required in coastal air to account for photochemically-driven coastal new-particle formation events to occur. However, measurements reported to date (i.e., ∼20 ppt I2, ≤ 10 ppt IO) have not supported the required model predictions. Here, we present measurements of high concentrations of I2 and IO in N.E. Atlantic marine air on the west coast of Ireland. The maximum mixing ratios of daytime I2 and IO over the seaweed beds during low tide were 302 ppt and 35 ppt, respectively. The I2 distribution was rather inhomogeneous, even at the inter-tidal zone, but…
Exploring quantum matter with ultracold atoms in optical lattices
2005
Seventy years after Einstein's prediction, the seminal achievement of Bose–Einstein condensation in dilute atomic gases in 1995 has provided us with a new form of quantum matter. Such quantum matter can be described as a single giant matter wave. By loading it into an artificial periodic potential formed by laser light—a so-called optical lattice—it has become possible to probe matter far beyond the wave-like description. In a review of a series of experiments with ultracold quantum gases in optical lattices, we show that the granularity of the matter wave field, caused by the discreteness of atoms, gives rise to effects going beyond the simple single matter wave description. Bose–Einstein …
Quasiparticles and quantum phase transition in universal low-temperature properties of heavy-fermion metals
2006
We demonstrate, that the main universal features of the low temperature experimental $H-T$ phase diagram of CeCoIn5 and other heavy-fermion metals can be well explained using Landau paradigm of quasiparticles. The main point of our theory is that above quasiparticles form so-called fermion-condensate state, achieved by a fermion condensation quantum phase transition (FCQPT). When a heavy fermion liquid undergoes FCQPT, the fluctuations accompanying above quantum critical point are strongly suppressed and cannot destroy the quasiparticles. The comparison of our theoretical results with experimental data on CeCoIn5 have shown that the electronic system of above substance provides a unique opp…
Condensation of classical optical waves
2010
We demonstrate the nonlinear condensation of classical optical waves. The condensation is observed directly, as a function of nonlinearity and wave kinetic energy, in a self-defocusing photorefractive crystal.
Ultracold atomic Bose and Fermi spinor gases in optical lattices
2006
We investigate magnetic properties of Mott-insulating phases of ultracold Bose and Fermi spinor gases in optical lattices. We consider in particular the F=2 Bose gas, and the F=3/2 and F=5/2 Fermi gases. We derive effective spin Hamiltonians for one and two atoms per site and discuss the possibilities of manipulating the magnetic properties of the system using optical Feshbach resonances. We discuss low temperature quantum phases of a 87Rb gas in the F=2 hyperfine state, as well as possible realizations of high spin Fermi gases with either 6Li or 132Cs atoms in the F=3/2 state, and with 173Yb atoms in the F=5/2 state.
Beyond the dilute Bose gas
2006
Abstract We discuss problems of three dimensional Bose gases in interaction but non-dilute. We then use the theory of a “weakly interacting” Bose gas recently analyzed as an attempt to obtain further insights into non-dilute systems. In particular, we develop the theory with additional remarks, discussions and a slight modification. The article concludes with a much more detailed analysis of the Bose condensate depletion, as well as a study of the two-fluid model of Tisza and Landau: the coexistence of normal and superfluid liquids at sufficiently low temperatures. In fact, even if it is based on one debatable hypothesis, this non-dilute gas qualitatively leads, up to Landau's “ T 4 law”, t…
Colloid-polymer mixtures between asymmetric walls: Evidence for an interface localization transition
2007
We demonstrate via computer simulation that mixtures of colloids and polymers confined to thin films have the ability to undergo an interface localization transition. While one wall of the film is assumed to be hard for both particles, at the other wall, an additional repulsive potential acts, but on the colloids only. By varying the strength of this repulsion, a crossover from capillary condensation to interface localization is found. The latter occurs under conditions where in the bulk almost complete phase separation has occurred.