Search results for "CONDUCTIVITY"

INVESTIGATIONS ON INFILTRATION METHODS FOR AN IMPROVED SOIL HYDRAULIC CHARACTERIZATION

2020

Determining hydraulic properties of a loam soil by alternative infiltrometer techniques

2015

Testing infiltrometer techniques to determine soil hydraulic properties is necessary for specific soils. For a loam soil, the water retention and hydraulic conductivity predicted by the BEST (Beerkan Estimation of Soil Transfer parameters) procedure of soil hydraulic characterization was compared with data collected by more standard laboratory and field techniques. Six infiltrometer techniques were also compared in terms of saturated soil hydraulic conductivity, Ks. BEST yielded water retention values statistically similar to those obtained in the laboratory and Ks values practically coinciding with those determined in the field with the pressure infiltrometer (PI). The unsaturated soil hyd…

DETERMINING THE SATURATED HYDRAULIC CONDUCTVITY OF A LOAM SOIL WITH DIFFERENT INFILTROMETER TECHNIQUES

2015

The saturated soil hydraulic conductivity, Ks, is one of the most important soil hydraulic properties since it controls many hydrological processes. This hydrodynamic parameter depends on soil texture and structure and it is very difficult to measure. Infiltrometer techniques are becoming very popular to determine Ks in the field but testing alternative approaches is necessary for specific soil types. For a loam soil, the estimated Ks values with six infiltrometer techniques were compared. The so-called BEST procedure of soil hydraulic characterization, the pressure infiltrometer (PI), single head experiments with both the tension infiltrometer (TI) and the mini disk infiltrometer (MDI), th…

Constitution and conductivity of metalloporphyrin tapes

2020

Front Cover: Constitution and Conductivity of Metalloporphyrin Tapes (Eur. J. Inorg. Chem. 20/2020)

2020

Investigation of the Thermoelectric Properties of the Series TiCo1-xNixSnxSb1-x

2010

The effect of the simultaneous substitution of cobalt by nickel and antimony by tin in the solid solution TiCo1–xNixSnxSb1–x was systematically investigated. The number of valence electrons does not change by this substitution and therefore the resistivity stays semimetallic or semiconducting. The series were synthesized by arcmelting and the thermoelectric properties were determined. It was found out that the substitution of cobalt and antimony by nickel and tin reduces the thermal conductivity to 2 W·m–1·K–1 at 400 K. The reduction is caused by titanium rich prolate micro structures that were found by energy dispersive X-ray spectroscopy investigations. The Seebeck coefficient and the res…

Lattice dynamics of the ionic superconductor Li4C60. Inelastic neutron scattering and powder averaged lattice dynamics (PALD) investigations

2016

Hybrid magnetic superconductors formed by TaS2 layers and spin crossover complexes.

2013

The restacking of charged TaS2 nanosheets with molecular counterparts has so far allowed for the combination of superconductivity with a manifold of other molecule-intrinsic properties. Yet, a hybrid compound that blends superconductivity with spin crossover switching has still not been reported. Here we continue to exploit the solid-state/molecule-based hybrid approach for the synthesis of a layered TaS2-based material that hosts Fe(2+) complexes with a spin switching behavior. The chemical design and synthetic aspects of the exfoliation/restacking approach are discussed, highlighting how the material can be conveniently obtained in the form of highly oriented easy-to-handle flakes. Finall…

Structure and Properties of One-Dimensional Heterobimetallic Polymers Containing Dicyanoaurate and Dirhodium(II) Fragments

2012

The synthesis and characterization of compound [Rh(2)(O(2)CEt)(4)(H(2)O)(2)] (1) and one-dimensional heterobimetallic polymers K(n){Rh(2)(O(2)CEt)(4)[Au(CN)(2)]}(n) (2) and K(n){Rh(2)(O(2)CMe)(4)[Au(CN)(2)]}(n)·4nH(2)O (3), constructed from dirhodiumtetracarboxylato units, [Rh(2)(O(2)CR)(4)](+), and dicyanoaurate, [Au(CN)(2)](-), fragments are described. In both compounds 2 and 3 the resulting polymeric chains are nonlinear and have in common similar structural parameters, although the solid state supramolecular arrangement is very different. These structural differences explain the fact that complex 2 displays aurophilic interactions while this type of interactions are absent in complex 3.…

Pressure-dependent modifications in the optical and electronic properties of Fe(IO3)3: the role of Fe 3d and I 5p lone–pair electrons

2021

We have determined by means of optical-absorption experiments that Fe(IO3)3 is an indirect band-gap material with a band-gap energy of 2.1 eV. This makes this compound the iodate with the smallest band gap. We also found that under compression the band-gap energy has an unusual non-linear pressure dependence, which is followed by an abrupt and discontinuous decrease of the band gap at 24 GPa. The observed behavior is explained by means of density-functional calculations, which show that the behavior of the band gap is governed by the combined influence of Fe 4d and I 5p lone pair electrons. In addition, the abrupt decrease of the band-gap energy at 24 GPa is a consequence of a first-order s…