Search results for "CONFINEMENT"
showing 10 items of 213 documents
From Behavior of Water on Hydrophobic Graphene Surfaces to Ultra-Confinement of Water in Carbon Nanotubes
2021
In recent years and with the achievement of nanotechnologies, the development of experiments based on carbon nanotubes has allowed to increase the ionic permeability and/or selectivity in nanodevices. However, this new technology opens the way to many questionable observations, to which theoretical work can answer using several approximations. One of them concerns the appearance of a negative charge on the carbon surface, when the latter is apparently neutral. Using first-principles density functional theory combined with molecular dynamics, we develop here several simulations on different systems in order to understand the reactivity of the carbon surface in low or ultra-high confinement. …
ECRIS plasma spectroscopy with a high resolution spectrometer
2020
Electron Cyclotron Resonance Ion Source (ECRIS) plasmas contain high-energy electrons and highly charged ions implying that only noninvasive methods such as optical emission spectroscopy are reliable in their characterization. A high-resolution spectrometer (10 pm FWHM at 632 nm) enabling the detection of weak emission lines has been developed at University of Jyväskylä, Department of Physics (JYFL) for this purpose. Diagnostics results probing the densities of ions, neutral atoms, and the temperature of the cold electron population in the JYFL 14 GHz ECRIS are described. For example, it has been observed that the cold electron temperature drops from 40 eV to 20 eV when the extraction volta…
Efficiency of Stress-Strain Models of Confined Concrete With and Without Steel Jacketing to Reproduce Experimental Results
2016
The improvement and the capacity assessment of existing buildings has become the main topic of the last years so that different studies can be found devoted to damaged structures or structures not having a capacity compatible with the safety levels of the actual codes. Reinforced concrete framed structure buildings represent a conspicuous rate of the existing constructions so many efforts are addressed to them. Referring to this type of buildings, a good prediction of strength and deformation capacity requests models able to interpret the constitutive law of concrete confined by internal reinforcement or by eventual external reinforcement applied to increase capacity of cross-sections. Cons…
Laser heating and ablation at high repetition rate in thermal confinement regime
2006
International audience; Laser heating and ablation of materials with low absorption and thermal conductivity (paint and cement) were under experimental and theoretical investigations. The experiments were made with a high repetition rate Q-switched Nd:YAG laser (10 kHz, 90 ns pulse duration and l = 532 nm). High repetition rate laser heating resulted in pulse per pulse heat accumulation. A theoretical model of laser heating was developed and demonstrated a good agreement between the experimental temperatures measured with the infrared pyrometer and the calculated ones. With the fixed wavelength and laser pulse duration, the ablation threshold fluence of paint was found to depend on the repe…
Synthesis of multi-color luminescent ZnO nanoparticles by ultra-short pulsed laser ablation
2020
Abstract Crystalline ZnO nanoparticles (NPs) are synthesized by ultra-short femtosecond (fs) pulsed laser ablation (PLA) of a zinc plate in deionized water, and are investigated by optical absorption and time resolved luminescence spectra in combination with the morphology and structure analysis. The comparison with previous experiments based on short nanosecond (ns) PLA highlights that pulse duration is a crucial parameter to determine the size and the optical properties of ZnO NPs. While short PLA generates NPs with average size S ‾ of ~ 30 nm, ultrashort PLA allows to achieve much smaller NPs, S ‾ ⩽ 10 nm, that evidence weak quantum confinement effects on both the absorption edge and th…
Simplified Model for Compressive Behavior of Concrete Columns Strengthened by Steel Angles and Strips
2010
This paper presents an analytical model to determine the compressive response of concrete members, having a square transverse cross section and reinforced with steel angles at the corners and steel strips connecting the steel angles. The model evaluates the effects of transverse strips and steel angles on confinement pressures, including strength and buckling phenomena. Compressive response was evaluated in cases of directly and indirectly loaded elements. The data produced correlate well with available experimental data.
Nanoconfined mixed Li and Mg borohydrides as materials for solid state hydrogen storage
2012
Abstract Several mixtures of LiBH4 and Mg(BH4)2 borohydrides in different stoichiometric ratios (1:0, 2:1, 1:1, 1:2, 0:1), prepared by high energy ball milling, have been investigated with X-ray powder diffraction and thermal programmed desorption (TPD) volumetric analysis to test the dehydrogenation kinetics in correlation with the physical mixture composition. Afterwards mixed and unmixed borohydrides were dispersed on high specific surface area ball milled graphite by means of the solvent infiltration technique. BET and statistical thickness methods were used to characterize the support surface properties, and SEM micrographs gave a better understanding of the preparation techniques. It …
Analysis-oriented stress–strain model of CRFP-confined circular concrete columns with applied preload
2018
The compressive behavior of FRP-confined concrete is a current issue in the field of structural retrofitting. The available models well predict the stress–strain behavior under monotonic and cyclic loads. However, in the practical applications, columns that need an increasing of bearing capacity are often strengthened under serviceability load conditions, with a stress and strain state that could change the response of the reinforced systems with respect to the case of the unloaded state. In this paper, the compressive behavior of circular FRP-confined concrete columns with preload is analyzed with the introduction of a modified analysis-oriented model. Differently from the classical formul…
Effect of corner over-reinforcing strips on the compressive behaviour of TRM confined masonry columns
2020
Several recent works studied the efficiency of inorganic matrix composites, namely Textile Reinforced Mortar (TRM) or Fabric Reinforced Cementitious Matrix, for enhancing the strength and shortening capacity of masonry columns subjected to axial load. Literature studies were addressed to study the great number of variables involved in the problem, such as the nature and the grade of mortar, the strength of the fabric, the number of reinforcing layers, the type, the arrangement and the strength of the masonry, and helped to draw the first technical guidelines for practitioners and designers. All the experimental works highlighted that the actual performance of TRM confinement in masonry memb…
Compressive behaviour of eccentrically loaded slender masonry columns confined by FRP
2018
Abstract Fibre Reinforced Polymer (FRP) confinement represents an effective tool for retrofitting masonry piers or columns enhancing their structural performance. This technique has been widely studied in the literature mainly with reference to short columns, while no extensive information is available on the influence of second order effects on its efficacy in case of slender members. Within this framework, the presented study concerns a simplified method able to assess the effects of FRP confinement on the compressive behaviour of slender masonry columns. A proper constitutive law of FRP confined masonry in compression is adopted for performing a sectional analysis, in which also consider…