Search results for "CONI"
showing 10 items of 984 documents
High‐Zirconium‐Content Nano‐Sized Bimodal Mesoporous Silicas
2006
Silica-based nanoparticulated bimodal mesoporous materials with high Zr content (43 ≥ Si/Zr ≥ 4) have been synthesized by a one-pot surfactant-assisted procedure from a hydroalcoholic medium using a cationic surfactant (CTMABr = cetyltrimethylammonium bromide) as structure-directing agent, and starting from molecular atrane complexes of Zr and Si as hydrolytic inorganic precursors. This preparative technique allows optimization of the dispersion of the Zr guest species in the silica walls. The bimodal mesoporous nature of the final high surface area nano-sized materials is confirmed by XRD, TEM, and N2 adsorption–desorption isotherms. The small intraparticle mesopore system (with pore sizes…
Evaluation of shear bond strength of zirconia to composite resin using different adhesive systems
2019
Background To evaluate shear bond strength of zirconia to composite resin using different universal and conventional adhesives and a zirconia primer. Material and methods Forty zirconia blocks were fabricated of zirconium ingots (10×10×5 mm) and sintered at 1530°C for 2 hours. They were then air-abraded with Al2O3 particles. The specimens were divided into 4 groups and subjected to one of the following bonding agents: Futurabond U (group 1), Clearfil Universal Bond, universal adhesives (group 2), Z-Prime Plus, zirconia primer (group 3) and Adper Single Bond 2, conventional adhesive (group 4). Composite resin was then applied in a diameter of 5 mm and in a thickness of 2 mm. All the specimen…
ChemInform Abstract: Enantioselective Synthesis of Tertiary Alcohols Through a Zirconium-Catalyzed Friedel-Crafts Alkylation of Pyrroles with α-Ketoe…
2011
Chiral complexes of 1,1′-bi-2-naphthol-based ligands with zirconium tert-butoxide catalyze the Friedel–Crafts alkylation of pyrroles with α-ketoesters to afford tertiary alcohols in good yields and ee up to 98%. The reaction is also of application to 4,7-dihydroindole to give C2-alkylated indoles after oxidation with p-benzoquinone.
Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalized Friedel-Crafts Alkylation of Pyrroles with alpha-Ketoesters
2011
Chiral complexes of 1,10-bi-2-naphthol-based ligands with zirconium tert-butoxide catalyze the Friedel Crafts alkylation of pyrroles with R-ketoesters to afford tertiary alcohols in good yields and ee up to 98%. The reaction is also of application to 4,7-dihydroindole to give C2-alkylated indoles after oxidation with p-benzoquinone.
ChemInform Abstract: Synthesis of Functionalized Indoles with a Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Atom Through an Enantioselect…
2010
Chiral complexes of BINOL-based ligands with zirconium tert-butoxide catalyze the Friedel-Crafts alkylation reaction of indoles with beta-trifluoromethyl-alpha,beta-unsaturated ketones to give functionalized indoles with an asymmetric tertiary carbon center attached to a trifluoromethyl group. The reaction can be applied to a large number of substituted alpha-trifluoromethyl enones and substituted indoles. The expected products were obtained with good yields and ees of up to 99%.
The non-degenerate Dupin cyclides in the space of spheres using Geometric Algebra
2012
International audience; Dupin cyclides are algebraic surfaces of degree 4 discovered by the French mathematician Pierre-Charles Dupin early in the 19th century and \textcolor{black}{were} introduced in CAD by R. Martin in 1982. A Dupin cyclide can be defined, in two different ways, as the envelope of a one-parameter family of oriented spheres. So, it is very interesting to model the Dupin cyclides in the space of spheres, space wherein each family of spheres can be seen as a conic curve. In this paper, we model the non-degenerate Dupin cyclides and the space of spheres using Conformal Geometric Algebra. This new approach permits us to benefit from the advantages of the use of Geometric Alge…
Diachronie, analogie et iconicité : vers un principe d'adaptation sémiologique
2014
ACL Nat Axe 3; National audience; L’on constate, en linguistique diachronique, une tendance croissante à lier les évolutions linguistiques à la notion d’iconicité. Plus précisément, plusieurs des processus du changement linguistique, comme bon nombre de ses étapes, semblent orientés en vertu d’une tendance à l’accroissement de l’iconicité dans la langue. Or, parmi ces processus, l’analogie tient un rôle particulier dans la mesure où elle est associée à une simplification du système, à une harmonisation de ses formes. Mais si l’iconicité demeure un principe usuellement situé sur le plan cognitif, ses effets se mesurent aussi sur le plan de la sémiologie, autrement dit des signes qui constitu…
Sémantique et phonologie du système des personnes en italien. Un cas d'iconicité diagrammatique?
2012
Cet article présente une méthode d'analyse du lexique qui met en valeur l'isomorphisme entre le système des différences phonologiques et le système des différences sémantiques, en l'illustrant à partir des monosyllabes italiens qui distinguent la personne grammaticale. Premièrement, on esquisse le cadre théorique de la question, en commentant un extrait du grammairien latin Nigidius Figulus sur la base de la notion d'iconicité diagrammatique chez Peirce et Jakobson. Deuxièmement, on illustre les principales innovations méthodologiques que l'on vise à introduire. Troisièmement, on analyse le système des 89 monosyllabes italiens distinguant la personne. Quatrièmement, on étudie le rapport ent…
Coupled Modelling of ZrO 2 /α-Zr(O) Layers Growth under Thermal and Mechanical Gradients
2019
The oxidation process of a nuclear reactor fuel rod clad made of zirconium is simulated. It is assumed that the oxygen is transported by anionic diffusion in the zirconia layer (ZrO2). Part of this oxygen reacts at the interface between the zirconia layer and the metal, while the rest diffuses in the oxygen-enriched metal volume (α-Zr(O)) to the core of the metal by an interstitial mechanism. The model is based on the thermodynamics of irreversible processes and takes into account the influence of driving forces on the oxygen migration in the metal such as the oxygen concentration gradient, the temperature gradient [1] and the mechanical stress gradient [2]. The growth of both ZrO2 and α-Zr…
Physical, chemical and mechanical evolution of the fuel-cladding interface in irradiated PWR fuel rods
2022
During the fuel irradiation in nuclear reactor, the fuel-cladding assembly is exposed to several irradiation-induced modifications. The fuel swelling coupled with cladding creep leads to a contact between the fuel and the cladding. The oxygen transport from the UO2 fuel to the zirconium layer induces progressively the Zr-cladding oxidation. This oxidation is initially local with the formation of islets. Then, with the increasing burnup of the fuel, it conducts to a continuous layer of about 8-µm thickness, localized at the fuel-cladding interface. At high burnup, zirconia growths anchor themselves in the periphery of the fuel (which is restructured) leading to pellet/cladding interlocking. …