Search results for "CONSTANTS"
showing 10 items of 150 documents
Modeling of the role of conformational dynamics in kinetics of the antigen-antibody interaction in heterogeneous phase.
2012
[EN] A novel approach that may potentially be used to study biomolecular interactions including the simultaneous determination of structural and kinetic binding parameters is described in this Article for the first time. It allows a rigid distinction between the possible reaction mechanisms of biomolecular recognition, induced fit and conformational selection. The relative importance of the two pathways is determined not by comparing rate constants but the structural aspects of the interaction instead. So the exact location of antigen molecules with respect to the capture antibody is depicted experimentally, avoiding the use of X-ray crystallography. The proposed pattern is applied to study…
Thermodynamic studies of actinide complexes. 1. A reappraisal of the solution equilibria between plutonium(IV) and ethylenediaminetetraacetic acid (E…
2007
Abstract A detailed reevaluation of the complexation equilibria of plutonium(IV) with the polyaminocarboxylic sequestering agent EDTA4− has been performed in 1 M (H,K)NO3 media at 298 K by means of visible absorption spectrophotometry and glass-electrode potentiometry at millimolar concentration levels. The high binding affinity even under strongly acidic conditions supports the exclusive formation of the neutral Pu(EDTA) complex over the range 0.01 ≤ [H+] ≤ 0.9 M with an apparent formation constant of log β110 = 25.8(1) at 0.9 M HNO3. Extrapolation to zero ionic strength using the SIT approach provides the first ever-reported NEA–TDB compliant estimate of β 110 0 ( log β 110 0 = 32.2 ( 3 )…
Heats and Entropies of Reaction of Transition Metal Ions with Ethylenediamine
1960
THE heats of formation of complexes between ligands and metal ions are very important to further the ligand field-theory and check its implications. Until now, only the heats of hydration of the first transition group ions have been used for this purpose1 as the thermochemical data on the complexes formed by ligands other than water are very incomplete. The transition metal complexes of ethylenediamine, which have a very nearly octahedral configuration, could also be fruitfully studied in terms of ligand field-theory. Unfortunately only the thermal data on nickel (II), copper (II) and zinc (II) complexes are known2, and so the formation constants have been used instead of the values of enth…
Complex formation of Tb3+ with glycolate, D-gluconate and α-isosaccharinate in neutral aqueous perchlorate solutions
2003
Summary An electromigration technique was used for measurements of metal-ligand formation constants of non-carrier-free 160Tb3+ with glycolate, D-gluconate and α-isosaccharinate ligands. The overall ion mobilities of Tb at different concentrations of the ligands were measured in chemically inert perchlorate solutions (pH 7 and T= 298.1K) with an overall ionic strength μ = 0.1. The stepwise stoichiometric stability constants are: Tb3+/glycolate: log K 1=2.72(18), log K 2=1.73(19), log K 3= 1.12(17), Tb3+/D-gluconate: log K 1=2.96(11), log K 2=2.60(11), log K 3=1.13(9), Tb3+/α-ISA: log K 1=3.07(8), log K 2 = 2.69(11), log K 3 = 1.80(12).
Importance of torsion and invariant volumes in Palatini theories of gravity
2013
We study the field equations of extensions of general relativity formulated within a metric-affine formalism setting torsion to zero (Palatini approach). We find that different (second-order) dynamical equations arise depending on whether torsion is set to zero (i) a priori or (ii) a posteriori, i.e., before or after considering variations of the action. Considering a generic family of Ricci-squared theories, we show that in both cases the connection can be decomposed as the sum of a Levi-Civita connection and terms depending on a vector field. However, while in case (i) this vector field is related to the symmetric part of the connection, in (ii) it comes from the torsion part and, therefo…
Sum rules across the unpolarized Compton processes involving generalized polarizabilities and moments of nucleon structure functions
2018
We derive two new sum rules for the unpolarized doubly virtual Compton scattering process on a nucleon, which establish novel low-$Q^2$ relations involving the nucleon's generalized polarizabilities and moments of the nucleon's unpolarized structure functions $F_1(x,Q^2)$ and $F_2(x,Q^2)$. These relations facilitate the determination of some structure constants which can only be accessed in off-forward doubly virtual Compton scattering, not experimentally accessible at present. We perform an empirical determination for the proton and compare our results with a next-to-leading-order chiral perturbation theory prediction. We also show how these relations may be useful for a model-independent …
Dispersion theoretical analysis of the nucleon spin polarizabilities
1999
The spin polarizabilities of the nucleon have been calculated from pion photoproduction data using forward dispersion relations. The feasibility of an experimental determination of these structure constants is discussed by focusing on polarization observables of the reaction \( \vec{\gamma }\vec{p} \to \gamma p \)→ γ p.
Transparent Boundary Condition for Oseen-Frank Model. Application for NLC Cells With Patterned Electrodes
2015
In the present work a novel application of Transparent Boundary Conditions (TBC) to nematic liquid crystal cells (NLCC) with planar alignment and a patterned electrode is studied. This device is attracting great interest since it allows soliton steering by optically and externally induced waveguides. We employ the continuum Oseen-Frank theory to find the tilt and twist angle distributions in the cell under the one-constant approximation. The electric field distribution takes into account the whole 2D permittivity tensor for the transverse coordinates. Standard finite difference time domain methods together with an iterative method is applied to find an approximate solution to our coupled pr…
Light Quark Masses from Lattice Quark Propagators at Large Momenta
1999
We compute non-perturbatively the average up-down and strange quark masses from the large momentum (short-distance) behaviour of the quark propagator in the Landau gauge. This method, which has never been applied so far, does not require the explicit calculation of the quark mass renormalization constant. Calculations were performed in the quenched approximation, by using O(a)-improved Wilson fermions. The main results of this study are ml^RI(2GeV)=5.8(6)MeV and ms^RI(2GeV)=136(11)MeV. Using the relations between different schemes, obtained from the available four-loop anomalous dimensions, we also find ml^RGI=7.6(8)MeV and ms^RGI=177(14)MeV, and the MSbar-masses, ml^MS(2GeV)=4.8(5)MeV and …
Unravelling the modus operandi of phytosiderophores during zinc uptake in rice: the importance of geochemical gradients and accurate stability consta…
2020
Abstract Micronutrient deficiencies threaten global food production. Attempts to biofortify crops rely on a clear understanding of micronutrient uptake processes. Zinc deficiency in rice is a serious problem. One of the pathways proposed for the transfer of zinc from soils into rice plants involves deoxymugineic acid (DMA), a phytosiderophore. The idea that phytosiderophores play a wider role in nutrition of Poaceae beyond iron is well established. However, key mechanistic details of the DMA-assisted zinc uptake pathway in rice remain uncertain. In particular, questions surround the form in which zinc from DMA is taken up [i.e. as free aqueous Zn(II) or as Zn(II)–DMA complexes] and the role…