Search results for "CORROSION"
showing 10 items of 456 documents
Influence of Post-machining Thermal Treatment on the Corrosion Behaviour of Copper
2014
Abstract In this paper, the influence of a post-machining thermal treatment (PMTT) on the corrosion behaviour of copper was investigated in a salt fog atmosphere. The corrosion behaviour was affected by the presence of a high density of grain boundaries generated during machining or dislocations formed during PMTT under certain conditions. The obtained results showed that it is possible to find PMTT conditions to cancel changes induced by machining and that the critical factor leading to a sharp increase of the percentage of oxidized surface seems to be the density of dislocations near the machined surface.
Electrochemical Behaviour and Galvanic Effects of Titanium Implants Coupled to Metallic Suprastructures in Artificial Saliva
2018
The aim of the present study is to analyze the electrochemical behavior of five different dental alloys: two cobalt-chromium alloys (CoCr and CoCr-c), one nickel-chromium-titanium alloy (NiCrTi), one gold-palladium alloy (Au), and one titanium alloy (Ti6Al4V), and the galvanic effect when they are coupled to titanium implants (TiG2). It was carried out by electrochemical techniques (open circuit measurements, potentiodynamic curves and Zero-Resistance Ammetry) in artificial saliva (AS), with and without fluorides in different acidic conditions. The studied alloys are spontaneously passivated, but NiCrTi alloy has a very narrow passive domain and losses its passivity in presence of fluorides…
A comparison of three different micro-tomography systems for accurate determination of microvascular parameters
2008
The investigation of micro-vessel dimensions in 3D is currently problematic due to their complex structures and fine scale. Quantification of vascular parameters is important in several fields of biomedicine; including embryogenesis, wound healing, diseases characterized by uncontrolled angiogenesis (e.g. tumor growth and metastasis) and the development of implantable bio-materials where a functional vascular supply is critical to their successful integration into host tissue. However, techniques that can resolve the micron-scaled features of these capillary beds, such as scanning electron and confocal microscopy, do not allow for total image reconstitution in 3 D in thick tissue samples [1…
Microfocus X-ray computed tomography analysis of corroded glass objects
2009
Abstract Microfocus X-ray computed tomography (µCT) is a useful tool for non-destructive analysis of corroded archaeological glass objects and for monitoring restoration and conservation processes for these materials. This was demonstrated by µCT analysis of artificially corroded laboratory-produced glasses and corroded archaeological glasses retrieved from soil environments. Corrosion layers with a thickness of 20 µm or more can be detected as areas with lower X-ray attenuation values than the non-corroded glass. Features that are revealed by µCT analyses include the degree and patterns of corrosion and the presence of various internal structures in the corrosion layers. The study of resto…
Effect of Pulse Current Mode on Microstructure, Composition and Corrosion Performance of the Coatings Produced by Plasma Electrolytic Oxidation on AZ…
2019
Plasma electrolytic oxidation (PEO) coatings were grown on AZ31 Mg alloy in a silicate-based electrolyte containing KF using unipolar and bipolar (usual and soft-sparking) waveforms. The coatings were dual-layered consisting of MgO, MgF2 and Mg2SiO4 phases. Surface morphology of the coatings was a net-like (scaffold) containing a micro-pores network, micro-cracks and granules of oxide compounds. Deep pores were observed in the coating produced by unipolar and usual bipolar waveforms. The soft-sparking eliminated the deep pores and produced the lowest porosity in the coatings. It was found that the corrosion performance of the coatings evaluated using EIS in 3.5 wt. % NaCl solution is mostly…
Stabilizing organic photocathodes by low-temperature atomic layer deposition of TiO2
2017
Organic semiconductor light absorbers are receiving attention for their potential application in photoelectrochemical (PEC) cells for renewable fuels generation. Key to their advancement is precise control of the interfaces between charge-selective contacts, absorber layers, and electrocatalysts, while maintaining compatibility with an aqueous electrolyte environment. Here we demonstrate a new process for low-temperature atomic layer deposition (ALD) of TiO2 onto a P3HT:PCBM polymer blend surface for stable high-performance organic PEC photocathodes. This ALD TiO2 layer provides three key functions: (1) formation of an electron-selective contact to the polymer to enable photovoltage and pho…
Inhibitoren der Korrosion 28 (1). 2-Aminopyrimidin (2-AP) als an Inhibitor der the Korrosion des Kupfers in Salzlösungen unter Sauerstoff
1982
2-Aminopyrimidin ist der z. Z. beste Inhibitor der Korrosion von Kupfer unter Standardbedingungen. Mit den aus der Oberflache der Kupferprobe austretenden oder gebildeten Cu1+-Ionen baut sich eine Schutzschicht auf. Die Ausbildung dieser Deckschicht wird studiert als Funktion: (a) der Konzentration an 2-AP und der Cu2+-Ionen, (b) der Stromungsgeschwindigkeit und (c) in Abhangigkeit von der Art der Anionen im korrosiven Medium. Ruhepotential-Zeit-Messungen, Strom-Spannungskurven, Polarisationswiderstandskurven und Halteversuche, ohne und mit 2-AP sowie ohne und mit Cu2+-Ionen vermitteln einen Einblick in den Aufbau der Deckschicht. Inhibiors of corrosion 28 (1). 2-Aminopyrimidine (2-AP) as a…
The European contribution to the development and validation activities for the design of IFMIF lithium facility
2013
The International Fusion Materials Irradiation Facility (IFMIF) is an accelerator-driven intense neutron source where candidate materials for fusion reactors will be tested and validated. The high energy neutron flux is produced by means of two deuteron beams (total current of 250 mA, energy of 40 MeV) that strikes a liquid lithium target circulating in a lithium loop of IFMIF plant. The European (EU) contribution to the development of the lithium facility comprises five procurement packages, as follow: (1) participation to the experimental activities of the EVEDA lithium test loop in Oarai (Japan); (2) study aimed at evaluating the corrosion and erosion phenomena, promoted by lithium, for …
Microstructure and phase composition of bronze Montefortino helmets discovered Mediterranean seabed to explain an unusual corrosion
2021
AbstractTwo Monterfortino helmets, recovered in the Mediterranean seabed, show unusual features with respect to the more common helmets of the same period and found in underwater environments. Hence, they were investigated by a multi-analytical approach, which allowed us to identify the compounds constituting the helmets and to make some considerations about their metallurgy, although all the metal was converted to degradation products. The helmets, originally made in bronze, have maintained their original shape because of copper sulphides formation. The observed differences in composition between the two helmets were attributed to the position modification, of one of them, into the seabed …
Evidence for mechanical and chemical alteration of iron-nickel meteorites on Mars: Process insights for Meridiani Planum
2011
The weathering of meteorites found on Mars involves chemical and physical processes that can provide clues to climate conditions at the location of their discovery. Beginning on sol 1961, the Opportunity rover encountered three large iron meteorites within a few hundred meters of each other. In order of discovery, these rocks have been assigned the unofficial names Block Island, Shelter Island, and Mackinac Island. Each rock presents a unique but complimentary set of features that increase our understanding of weathering processes at Meridiani Planum. Significant morphologic characteristics interpretable as weathering features include (1) a large pit in Block Island, lined with delicate iro…