Search results for "CORROSION"

Photocurrent spectroscopy of thin passive films

2002

Publisher Summary This chapter reviews theoretical background on the photoelectrochemistry of metal and semiconductor electrodes on which photocurrent spectroscopy (PCS) relies, by focusing particularly on new features that are typical of the photoelectrochemical behavior of thin passive films and usually absent in the behavior of bulk crystalline semiconductors. The chapter also highlights the advantages of PCS in getting in situ information on the structure of the metal-passive-film-electrolyte systems and shows a more recent quantitative use of this technique in characterizing the composition of passive films. The formation of a protective film on a metallic surface is a key step in esta…

ChemInform Abstract: Photoelectrochemical Characterization of Thin Anodic Oxide Films on Zirconium Metal.

2010

Abstract The effect of metal surface preparation on the properties of thin oxide films grown on zirconium in different electrolytes was investigated by photocurrent spectroscopy. Both passive layers grown by free corrosion of the samples in a solution and thin oxides grown anodically at a constant rate were investigated. The photoelectrochemical results give a complex picture of the interface, being influenced by the metal surface preparation, the solution pH and the electrode potential. A duplex structure of the films has been suggested on the basis of the photocurrent spectra, with an external hydrous layer (amorphous or strongly defective) having an optical gap ( E g 2 ~ 3 eV) lower resp…

Recent advances in photocurrent spectroscopy of passive films

2003

Abstract The quantitative application of photocurrent spectroscopy (PCS) for the in-situ determination of the composition of passive films and corrosion layers is reviewed in the light of recent theoretical advances, that have allowed to relate the measured optical gaps to the Pauling electronegativities of the film components. The correlations derived are tested versus recent experimental results regarding mixed oxides, anhydrous passive films on metallic alloys and hydroxide layers. The effect of the eventual long-range disorder into the passive film on the optical band gap values is also discussed. New experimental evidence reported for mixed d,d-metal oxides and passive films on sp,d-me…

Photoelectrochemical Techniques in Corrosion Studies

2005

Physico-chemical characterization and corrosion properties of friction stir welded Al2024-T4 alloys

2009

Research on the internal pressure behavior of metal gas distribution pipelines with different types of tubing defects

2017

The paper aims to approach an important subject related to natural gas distribution networks which, depending on the expansion of the localities, are composed of intercommunicating pipes, pressure reducing stations and branch connections fittings. The urban networks are the most complex ones and the rural areas networks are the simplest. However, irrespective of their installation, they must meet the safety operating requirements as much as possible. According to standards, all these components must be tight and pressure resistant. In this regard, we intend to approach a very important issue related to the behavior of the tubular steel material showing corrosion and/or material defects, and…

An assembly of organic-inorganic composites using halloysite clay nanotubes

2018

Halloysite is natural tubular clay suitable as a component of biocompatible nanosystems with specific functionalities. The selective modification of halloysite inner/outer surfaces can be achieved by exploiting supramolecular and covalent interactions resulting in controlled colloidal stability adjusted to the solvent polarity. The functionalized halloysite nanotubes can be employed as reinforcing filler for polymers as well as carriers for the sustained release of active molecules, such as antioxidants, flame-retardants, corrosion inhibitors, biocides and drugs. The tubular morphology makes halloysite a perspective template for core-shell metal supports for mesoporous catalysts. The cataly…

Effect of magnetic field on the corrosion of iron and St20 steel as studied by positron annihilation

2010

Lifetime spectra of positron annihilation in iron and St20 steel corroded in the water solution of HCl and in vapour above its surface have been investigated with emphasis on the effect of corrosion time and environment (solution or vapour) as well as of the presence and orientation of the magnetic field on the measured positron annihilation parameters. All the registered positron lifetime spectra consist of two components. For corroded samples the intensities of the two components as well as the corresponding values of the mean positron lifetime, differ from those for uncorroded material. The corrosion-induced changes in the positron annihilation parameters depend on the corrosion environm…

Chemical compatibility of bulk alumina in flowing PbLi alloy under magnetic field

2021

Abstract Electrically insulating flow channel inserts (FCI) may be needed in liquid-based breeding blanket concepts to electrically decouple the metal flow from the strong magnetic field in a future fusion reactor. Although the magnetohydrodynamic simulation demonstrates a reduction of the pressure drop when a sandwich-like steel-alumina-steel FCI is employed, the tritium production efficiency in the breeding zone of a breeding blanket is limited to 550 °C due to the steel corrosion. Previous theoretical thermomechanical analyses point out the possible occurrence of induced interfacial stresses between the steel and the ceramic part. Both factors motivate the actual FCI development towards …

Performance of a historical cantilever reinforced concrete bridge with half-joint degradation

2022

The lack of maintenance of roadway concrete bridges built from the Second World War until the 70 s of the 20th century has led in recent years to an ever-increasing request for safety assessments. When bridge performance in terms of Serviceability Limit State (SLS) and Ultimate Limit State (ULS) has to be evaluated, in-situ visual inspections and load tests for safety and maintenance assessment have to be coupled with structural analysis. In order to identify a sound bridge structural model and to assess the actual conservation state, more refined models than those usually considered for section and reinforcement design should be used to reproduce the results of load tests and perform globa…