Search results for "CORROSION"
showing 10 items of 456 documents
SVET, AFM and AES study of pitting corrosion initiated on MnS inclusions by microinjection
2003
As pitting is a random phenomenon, it is difficult to predict where a pit will appear on the surface and consequently the use of local probes is rendered difficult. In this work, a new method to study pitting corrosion on a MnS inclusion on 316L stainless steel is proposed. It consists in modifying locally the chemistry in its vicinity by injecting with a microcapillary an aggressive solution of NaCl, H2SO4 or HCl. Once a pit appears, scanning vibrating electrode technique (SVET) is used to follow the current fluctuations over and around the pit when the metal is polarized at a passive potential. In another series of experiments the effect of local activation of MnS inclusion was studied ex…
Technical Note:Study of the Cl−-Induced Breakdown of the Passive Layer on Steel
1991
Abstract The Cl−-induced breakdown of the passive layer on a standard steel has an induction time that increases in a nearly linear fashion with the previous holding time (at the passivation potent...
Influence of the passive film properties and residual stresses on the micro-electrochemical behavior of duplex stainless steels
2010
In the present paper, the chemical composition of passive films formed on both phases of two types of duplex stainless steels (UNS S31803 and UNS S32304) is determined at the micro-scale using Auger electron spectroscopy (AES). Samples were either mechanically polished (down to diamond pastes) or electrochemically etched in acidic solutions. The micro-electrochemical behavior of samples was then determined in sodium chloride media by means of the electrochemical micro-cell technique (capillary diameters of 30 μm). The results obtained were analyzed considering the passive film chemical composition. Quantitative relationships between electrochemical parameters and the distribution of chromiu…
Corrosion Phenomena of Eurofeer Steel in Pb-17Li Stationary Flow at Magnetic Field
2006
Search of new energy sources draws the increasing attention to use for this purpose of reactors. In the Europe some years the program EUROATOM uniting scientific of the many countries for the decision of constructive problems at designing of fusion reactors operates. One of the main things in this program is the problem of liquid metals breeder blanket behaviour. Structural material of blanket should meet high requirements because of extreme operating conditions. Therefore the knowledge of the effect of metals flow velocity, temperatures and also a neutron irradiation and a magnetic field on the corrosion processes are necessary. At the moment the eutectic lead -lithium (Pb-17Li) is conside…
Influence of the grain orientation spread on the pitting corrosion resistance of duplex stainless steels using electron backscatter diffraction and c…
2013
Abstract The corrosion behavior of UNS S32202 duplex stainless steel was studied by combining electron backscatter diffraction (EBSD) measurements and critical pitting temperature tests at the microscale. The grain orientation spread (GOS) value was determined in grains of both phases from EBSD data. It was shown that austenitic sites containing extremely small ferrite grains having a GOS value greater than 1.3° were precursor sites for pitting in 4 M NaCl. The critical pitting temperature range was 45–90 °C. All the other sites of both phases remained passive up to 100 °C.
Passive properties of lean duplex stainless steels after long-term ageing in air studied using EBSD, AES, XPS and local electrochemical impedance spe…
2013
Abstract Passivity of duplex stainless steel was studied after long-term ageing in air using local electrochemical impedance spectroscopy, AES, XPS and EBSD. After mechanical polishing, the passive film was homogeneous and had a capacitive behaviour described by the CPE. After long-term ageing, a small thickening was detected and O2−/OH− was significantly higher in the austenite than in the ferrite. Austenite behaved as a blocking electrode whereas two capacitive loops were observed in the ferrite (low value of O2−/OH). The loop at high frequencies was related with the oxygen reduction and the loop at low frequencies was connected with the passive film.
Localized hydrogen cracking in the austenitic phase of a duplex stainless steel
1996
The aim of this study is to investigate the role of hydrogen on the mechanical behavior of an austenitic phase, in the particular situation of duplex stainless steels. In these duplex alloys, in presence of hydrogen, the ferritic phase is embrittled by hydrogen and the resistance to cracking is mainly related to the behavior of the austenitic phase. Thus, a discussion of the role of hydrogen at the crack tip of a duplex alloy (as function of the microstructure) has been proposed by T. Perng and C.J. Altester after experiments conducted in gaseous environment. A similar experimental approach has been followed in this study; slow strain rate tests (SSRT) have been performed on duplex stainles…
Relationships between the Impedance of Oxide Scales on Martensitic and Austenitic Steels and Corrosion Rate in Liquid Lead-Bismuth Eutectic
2004
Abstract The impedance properties (resistance and capacitance) of oxide scales on the martensitic/ferritic steel HT-9 and austenitic stainless steel Type 316L (UNS S31603) were examined during immersion in lead-bismuth eutectic (LBE) using a technique similar to electrochemical impedance spectroscopy. These scales were created by preoxidizing the samples in an air/water vapor environment at 800°C for various times prior to immersion in LBE. Calculation of oxide conductivity for samples immersed in LBE at 200°C for 200 h yielded σHT9 ≈ 4 × 10−7 (Ω × cm)−1 while σ316 ≈ 3 × 10−8 (Ω × cm)−1. The influence of temperature alone gave the anticipated Arrhenius behavior with Ea equal to 0.12 eV, whi…
Influence of preoxidation on the corrosion of steels in liquid lead-bismuth eutectic
2004
Abstract Oxidation studies of martensitic/ferritic and austenitic steels have been conducted in static lead bismuth eutectic (LBE). Samples were preoxidized in an air/H2O gas mixture prior to immersion in LBE. Preoxidation films grown on HT-9 at 800°C for 48 h had a bilayer structure, an outer Fe-rich layer, and an inner Cr-rich layer. Glancing angle x-ray diffraction data found that two distinct structures were present in this oxide: Fe1+xCr2−xO4 spinel (cubic, face-centered cubic [fcc]) and (Cr,Fe)2O3 (rhombohedral, corundum). Magnetite formation (Fe3O4) was ruled out. Immersion in LBE resulted in the growth of an Fe-rich film on top of the preoxidation layer. It was concluded that the gr…
Corrosion Resistance of Alloys in IGCC Environment
2001
IGCC recovery boiler materials are subject to severe corrosion in environments composed of a gas mixture (CO-H 2 -H 2 O-CO 2 -H 2 S) and vanadium-containing fly-ash resulting from the combustion of oil residues. This paper presents a study of the corrosion behaviour of two Fe-Ni-Cr austenitic alloys in a typical IGCC environment at 400°C. The alloy composition influences the vanadium incorporated in the corrosion scales during the test, which affects the scale growth process. The valence state (determined by micro-XANES) and the amount of the incorporated vanadium is modified by a subsequent air flow at 400°C.