Search results for "CORROSION"

An Overview on the Performance of 1,2,3-Triazole Derivatives as Corrosion Inhibitors for Metal Surfaces

2021

This review accounts for the most recent and significant research results from the literature on the design and synthesis of 1,2,3-triazole compounds and their usefulness as molecular well-defined corrosion inhibitors for steels, copper, iron, aluminum, and their alloys in several aggressive media. Of particular interest are the 1,4-disubstituted 1,2,3-triazole derivatives prepared in a regioselective manner under copper-catalyzed azide-alkyne cycloaddition (CuAAC) click reactions. They are easily and straightforwardly prepared compounds, non-toxic, environmentally friendly, and stable products to the hydrolysis under acidic conditions. Moreover, they have shown a good efficiency as corrosi…

Assessment and strengthening of reinforced concrete bridges with half-joint deterioration

2022

Existing Niagara-type concrete cantilever bridges, which in Italy are called Gerber bridges, suffer from degradation due to reinforcement corrosion and a consequent reduced load-bearing capacity. The assessment of these structures is therefore an important part of the procedures for analyzing the state of existing bridges and any interventions required for their retrofitting. In particular, safety against failure of the half-joint must be evaluated with respect to the behavior of the entire bridge and its state of conservation, determining what the conditions are that lead to failure, in terms of loads, state of stress, and possibly cracking state. This evaluation has to be carried out cons…

La torre del Tempo: il punto di vista del chimico

2013

L’obiettivo del presente lavoro è stato quello di valutare la tipologia di lega metallica, il suo degrado e la tipologia di vernice dell’opera in ferro policroma “La Torre del Tempo” di E. Tadini. A tale scopo sono state effettuate delle misure di Microscopia Ottica, Diffrattometria a raggi X, Spettroscopia micro-Raman e Spettroscopia NMR. The goal of this study was to evaluate the type and the of conservation state of the metal alloy and the type of varnish of samples coming from “La Torre del Tempo” E. Tadini. The samples were characterized by Optical Microscopy, X-ray Diffractometry, micro-Raman Spectroscopy and NMR spectroscopy.

Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition

2020

Abstract Cristobalite is a low-pressure, high-temperature SiO2 polymorph that occurs as a metastable phase in many geologic settings, including as crystals deposited from vapor within the pores of volcanic rocks. Such vapor-phase cristobalite (VPC) has been inferred to result from silica redistribution by acidic volcanic gases but a precise mechanism for its formation has not been established. We address this by investigating the composition and structure of VPC deposited on plagioclase substrates within a rhyolite lava flow, at the micrometer to nanometer scale. The VPC contains impurities of the form [AlO4/Na+]0—coupled substitution of Al3+ charge-balanced by interstitial Na+—which are ty…

The effect of Ag, Pb and Bi impurities on grain boundary sliding and intergranular decohesion in Copper

2016

We investigate the changes in grain boundary sliding (GBS) and intergranular decohesion in copper (Cu), due to the inclusion of bismuth (Bi), lead (Pb) and silver (Ag) substitutional impurity atoms at a $\Sigma$5 (0 1 2) symmetric tilt grain boundary (GB), using a first-principles concurrent multiscale approach. We first study the segregation behavior of the impurities by determining the impurity segregation energy in the vicinity of the GB. We find that the energetically preferred sites are on the GB plane. We investigate the intergranular decohesion of Cu by Bi and Pb impurities and compare this to the effect of Ag impurities by considering the work of separation, $W_s$ and the tensile st…

Effects of hydrogen-charging on the properties of S235JR steel

2017

The paper presents the test results of the S235JR steel susceptibility to damage under the influence of hydrogen. The test of mechanical properties was performed on the basis of a static stretch test of non-hydrogenated samples and after cathodic polarization. Electrochemical measurements for the assessment of corrosion resistance of non-hydrogenated and hydrogenated steels were carried out using open circuit potential measurement and registering of potentiodynamic polarization curves in a three-electrode measuring system. Hydrogenation was carried out for between 3 and 24 hours in a solution of 0.1 N sulfuric acid (VI) with the addition of 2 mg/dm 3 of arsenic oxide (III) at an electric cu…

The consequences of the inappropriate use of ventilation systems operating in indoor swimming pool conditions - analysis

2018

Increasingly more leisure facilities, such as water parks or indoor swimming pools are being built in Poland nowadays. In order to ensure the air quality required by standards for such leisure facilities it is necessary to fit them with effectively functioning ventilation. For the removal of excess humidity, as well as chlorine ions occurring as a result of the disinfection of water as well as the carbon dioxide emitted by people using the facility, the ventilation system needs to be appropriately designed and efficient. For this reason, studies into the air quality in such facilities were undertaken. The paper presents the causes and consequences of the inappropriate operation and maintena…

Green approach to corrosion inhibition of stainless steel in phosphoric acid of Artemesia herba albamedium using plant extract

2019

Essential oil from aerial parts of Artemisia herba-alba from Morocco was hydrodistilled and its chemical composition oil was investigated by capillary GC and GC/MS. The major components were 1,8-cineole (35.6%) and camphor (24.1%). Artemisia herba-alba essential oil AHAO was tested as corrosion inhibitor of stainless steel (SS) in 1M H3PO4 using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy measurements (EIS) and scanning electronically microscopy (SEM) studies. The results obtained showed that the essential oil of Artemisia reduces the corrosion rate. Tafel polarization method indicates that the plant extract behaves as a mixed type inhibitor. The inhibition…

Liner Poliolefinici nella produzione di canalizzazioni e manufatti in calcestruzzo

2009

Dating of Archaeological Gold by Means of Solid State Electrochemistry

2018

[EN] In archaeology and history of art, age determination is a fundamental analytical problem. While several techniques for age determination of various materials, like radiocarbon dating, are established, these methods cannot be applied for metals, for which new techniques have to be developed. For the first time a dating method for archaeological gold objects is described which is based on a corrosion clock and electrochemical measurements, using the voltammetry of immobilized particles. Samples are prepared by one touch' with a graphite pencil, only transferring a few nanograms of the archaeological gold. The method has been calibrated with the help of a series of well-documented gold sp…