Search results for "CORROSION"
showing 10 items of 456 documents
Degraded Gerber Saddles in RC Bridges
2023
Sudden failure of reinforced concrete (RC) or prestressed concrete (PC) Gerber saddles of bridges and viaducts has occurred all around in the word in the last few years due to corrosion of steel bars. The danger of sudden and brittle failure is often due to general and pitting corrosion of steel bars, concrete crushing, and loss of bond in steel bars. In this paper, the flexural response of reinforced concrete Gerber supports under their self-weight with or without service loads was investigated through determination of the load-deflection response of beams, with the focus on the consequences of pitting corrosion and loss of bond in steel bars. A simplified strut-and-tie model was developed…
Co-deposition and characterization of hydroxyapatite-chitosan and hydroxyapatite-polyvinylacetate coatings on 304 SS for biomedical devices
2019
During the last decades, biomaterials have been deeply studied to fabricate and improve coatings for biomedical devices. Metallic materials, especially in the orthopedic field, represent the most common materials used for different type of devices thanks to their good mechanical properties. Nevertheless, low/medium resistance to corrosion and low osteointegration ability characterizes these materials. To overcome these problems, the use of biocoatings on metals substrate is largely diffused. In fact, biocoatings have a key role to confer biocompatibility features, to inhibit corrosion and thus improve the lifetime of implanted devices. In this work, the attention was focused on Hydroxyapati…
Conditioning metallic aluminum in magnesium phosphate cements
2016
This work deals with the stabilization / solidification of radioactive waste using cement.More particularly, it aims at assessing the chemical compatibility between metallic aluminum and mortars based on magnesium phosphate cement. The physical and chemical processes leading to setting and hardening of the cement are first investigated. X-ray diffraction (XRD), thermogravimetry (TGA) and nuclear magnetic resonance spectroscopy (31P and11B MAS-NMR) arefirst used to characterize the solid phases formed during hydration, while inductively coupled plasma atomic emission spectroscopy analysis (ICP-AES), electrical conductimetry and pH measurementsprovide information on the pore solution composit…
Studio della resistenza alla corrosione di acciai impiegati nell’industria alimentare e delle bevande
2020
In the present study we performed the physico-chemical characterization of passive films grown on different stainless steel grades after long exposure time in hot purified water (HPW). In order to get more insight into dissolution phenomena that can induce rouging on equipment materials typically involved in food and beverage industries, 304L, 316L and a super duplex 2507 SS samples were passivated at the open circuit potential by different immersion times in HPW at 60°C. Photoelectrochemical and Electrochemical Impedance measurements were performed in the attempt to correlate the electronic properties of the passive films (band gap and conductivity type) to their corrosion resistance.
Flexural behavior of corroded RC beams
2018
Synopsis: A handily model to evaluate the bending resistance and the ductility of corroded beams critical in flexure and shear is proposed and debated. Effects of diffused and pitting corrosion on steel bars, compressive concrete strength reduction and concrete bond strength reduction due to rust creation are modelled. Practical method derived on limit state theory was here used to calculate the flexural and shear strength and the available ductility. The effectiveness of the model was also corroborated against numerous results collected in the literature pertaining to bending and shear resistance.
A mathematical description accounting for the superfluous hydrogen evolution and the inductive behaviour observed during electrochemical measurements…
2018
When electrochemical techniques are used to probe the surface of corroding magnesium with the aim of obtaining quantitative information on the corrosion process, two peculiarities are generally observed: i) with anodic polarization, the rate of hydrogen evolution increases instead of decreasing and ii) during electrochemical impedance spectroscopy measurements, an inductive contribution is often observed at the low-frequency end of the spectra. The presence of these two phenomena clearly has an impact on the methodology that should be applied to correctly estimate corrosion rates from electrochemical data. The aim of this work is to provide a general mathematical description of the corrodin…
Corrosion in amine units for acid gas treatment : a laboratory study
2009
International audience; Corrosion represents one of the most important operational issues in amine units used for acid gas treatment. Considerable experience is available in the literature both on laboratory and in the field. Based on this experience, proven mitigation strategies are available, using corrosion inhibitors or corrosion resistant alloys at selected locations in the plant. However, the technical causes of the corrosivity of amine solvents are still not well understood. Furthermore, recent field experience showing severe corrosion in sweet units pointed out the difficulty to transpose design solutions from sour to sweet gas. There is obviously a need for more precise data on the…
Analisi teorico-sperimentale del comportamento di elementi in cemento armato soggetti a corrosione
Moment-Axial Domain of Corroded R.C. Columns
2018
In the present paper, a simplified model to determine the moment-axial force domain of the cross-section of reinforced concrete columns subjected to corrosion process is presented. The model considers members with square and rectangular cross-sections and it accounts for cover spalling, buckling of longitudinal reinforcing bars, loss of bond of bar in tension, reduction of confinement pressures (due to the reduction of the area of stirrups and cracking of concrete induced by rust formation). The analytical expressions for prediction of the area reduction of steel, bond strength and critical load of longitudinal bars utilized were verified against experimental data available literature.
INFLUENCE OF THE ANODIZATION CONDITIONS ON THE ELECTRONIC PROPERTIES AND CRYSTALLOGRAPHIC STRUCTURES OF THE CORROSION LAYERS ON TUNGSTEN. A PHOTOELEC…
1983
ABSTRACT The influence of morphology, composition and crystallographic structure on the photoelectrochemical behaviour of anodic oxide films on tungsten obtained in various conditions of anodization has been investigated. Different photocurrent spectra and absorption edges were obtained for each type of film. Optical band gaps ranging between 2.55 eV and 3.15 eV were determined for crystalline and amorphous WO 3 films grown in different conditions. The low quantum efficiency of the anodic films must be attributed to the presence of an amorphous (a-W0 3 ) film which controls the transport of the injected photocarriers.