Search results for "CRA"
showing 10 items of 4890 documents
Aspects of the kinematic history and mechanisms of superposition of the proterozoic mobile belts of eastern Central Africa (northern Malawi and south…
1993
Abstract Commonly the Proterozoic tectonic evolution of the Central African basement is subdivided into three major events: (1) the Ubendian (∼2300−1800 Ma), (2) the Irumide (∼1350−950 Ma), and (3) the Pan-African (∼900−450 Ma) orogenic cycles. Relics of the Ubendian event are granite intrusions and, possibly, an amphibolite- to granulite-facies metamorphism. The Ubendian orogeny was followed by deposition of clastic sediments (Muva supergroup). In northern Malawi these sediments and the underlying basement were then thrust to the east-southeast/southeast during the Irumide orogeny. Horizontal shearing along subvertical zones (i.e. the Ubendian belt) was associated with subhorizontal crusta…
Generation of early Archaean grey gneisses through melting of older crust in the eastern Kaapvaal craton, southern Africa
2014
Abstract We report zircon ages, Hf-in-zircon isotopes as well as whole-rock geochemistry and Hf–Nd isotopic systematics for Palaeoarchaean grey gneisses of the Ancient Gneiss Complex of Swaziland, the oldest components of the Kaapvaal craton, southern Africa. The Hf-in-zircon isotopic compositions in these compositionally heterogeneous, multicomponent, migmatitic gneisses are highly variable, even in the oldest zircons dating back to 3.66 Ga, suggesting growth of zircon from melts representing a mix of juvenile and anatectic material derived from differentiated continental crust of Eoarchean to late Hadean age. In contrast, the initial Nd and Hf whole-rock isotopic compositions are frequent…
H2S fluxes from Mt. Etna, Stromboli, and Vulcano (Italy) and implications for the sulfur budget at volcanoes
2005
Abstract We present here new measurements of sulfur dioxide and hydrogen sulfide emissions from Vulcano, Etna, and Stromboli (Italy), made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes. Measurements at the F0 and FA fumaroles on Vulcano yielded SO 2 /H 2 S molar ratios of ≈0.38 and ≈1.4, respectively, from which we estimate an H 2 S flux of 6 to 9 t · d −1 for the summit crater. For Mt. Etna and Stromboli, we found SO 2 /H 2 S molar ratios of ≈20 and ≈15, respectively, which combined with SO 2 flux measurements, suggest H 2 S emission rates of 50 to 113 t · d −1 and 4 to 8 t · d −1 , respectively. We observe that “source” and plume SO 2 /H 2 …
Intercomparison of volcanic gas monitoring methodologies performed on Vulcano Island, Italy
2004
[1] Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2, SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTI…
Tunable diode laser measurements of hydrothermal/volcanic CO<sub>2</sub> and implications for the global CO<sub&am…
2014
Abstract. Quantifying the CO2 flux sustained by low-temperature fumarolic fields in hydrothermal/volcanic environments has remained a challenge, to date. Here, we explored the potential of a commercial infrared tunable laser unit for quantifying such fumarolic volcanic/hydrothermal CO2 fluxes. Our field tests were conducted between April 2013 and March 2014 at Nea Kameni (Santorini, Greece), Hekla and Krýsuvík (Iceland) and Vulcano (Aeolian Islands, Italy). At these sites, the tunable laser was used to measure the path-integrated CO2 mixing ratios along cross sections of the fumaroles' atmospheric plumes. By using a tomographic post-processing routine, we then obtained, for each manifestati…
Major-ion bulk deposition around an active volcano (Mt. Etna, Italy)
2005
Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition …
Magmatic signature in acid rain at Masaya volcano, Nicaragua: Inferences on element volatility during lava lake degassing
2021
Abstract Major, minor and trace element concentrations of single rainfall events were investigated at Masaya volcano (Nicaragua) in order to determine the relative contributions of volcanogenic elements. Most of the samples were collected in the summit area of the volcano around the Santiago crater, and two samples, representative of the local background, were collected at a 4.3 km upwind site. Samples from the summit are very acidic with pH down to 2.14 and contain large amounts of volcanogenic elements that can be clearly distinguished from the local background. These elements are released into the atmosphere from the continuously degassing lava lake of the Santiago crater, Masaya volcano…
SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namib…
2010
Abstract The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to per…
Archaean granulite-facies paragneisses from central Swaziland: inferences on Palaeoarchaean crustal reworking and a complex metamorphic history
2014
We present a petrographic, petrological, geochemical, and geochronological study (U–Pb/Lu–Hf) on granulite-facies paragneisses of the Mahamba Gneiss Complex in central Swaziland, eastern Kaapvaal Craton. Our data suggest that prograde metamorphism occurred at c . 3.07 Ga. Dating of detrital zircons of a metapelite in combination with geochronological and ambiguous structural relationships with granitoid gneisses suggests two possible scenarios: (1) the time of deposition of the sedimentary protoliths is prior to c . 3.58 Ga; (2) c . 3.58 Ga granitoid crust was the basement for the sedimentary protoliths. Furthermore, enrichment in Ni and Cr in the Mahamba metasediments may originate from er…
A Damara orogen perspective on the assembly of southwestern Gondwana
2008
The Pan-African Damara orogenic system records Gondwana amalgamation involving serial suturing of the Congo-Sao Francisco and Ro ´o de la Plata cratons (North Gondwana) from 580 to 550 Ma, before amalgamation with the Kalahari - Antarctic cratons (South Gondwana) as part of the 530 Ma Kuunga-Damara orogeny. Closure of the Adamastor Ocean was diachronous from the Aracuao ´ Belt southwards, with peak sinistral transpressional deformation followed by craton overthrusting and foreland basin development at 580- 550 Ma in the Kaoko Belt and at 545-530 Ma in the Gariep Belt. Peak deformation/metamorphism in the Damara Belt was at 530-500 Ma, with thrusting onto the Kalahari Craton from 495 Ma thro…