Search results for "CaMoO4"

showing 2 items of 2 documents

Experimental and theoretical study to explain the morphology of CaMoO4 crystals

2018

Abstract CaMoO 4 crystals were prepared by a controlled co-precipitation method and processed in a domestic microwave-assisted hydrothermal system with two different surfactants (ethyl 4-dimethylaminobenzoate and 1,2,4,5-benzenetetracarboxylic dianhydride). The corresponding structures were characterized by X-ray diffraction and Rietveld refinement techniques, Fourier transform infrared spectroscopy, ultraviolet–visible absorption spectroscopy, and photoluminescence measurements. Field emission scanning electron microscopy was used to investigate the morphology of the as-synthesized aggregates. The structure, the surface stability of the (001), (112), (100), (110), (101), and (111) surfaces…

DiffractionPhotoluminescenceWulff constructionAbsorption spectroscopyRietveld refinementmicrowave-assisted hydrothermal methodAnalytical chemistryCaMoO402 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesSurface energy0104 chemical sciencesmorphologyGeneral Materials ScienceDensity functional theoryFourier transform infrared spectroscopyWulff construction0210 nano-technology
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Understanding the White-Emitting CaMoO4 Co-Doped Eu3+, Tb3+, and Tm3+ Phosphor through Experiment and Computation

2019

In this article, the synthesis by means of the spray pyrolysis method, of the CaMoO4 and rare-earth cation (RE3+)-doped CaMoO4:xRE3+ (RE3+ = Eu3+, Tb3+, and Tm3+; and x = 1, 2, and 4% mol) compounds, is presented. The as-synthesized samples were characterized using X-ray diffraction, Rietveld refinement, field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) spectroscopy. To complement and rationalize the experimental results, first-principles calculations, at the density functional theory level, have been performed to analyze the band structure and density of states. In addition, a theoretical method based on the calculations of surface energie…

terbium compoundsMaterials scienceTm3+lightingAnalytical chemistryfield emission microscopes02 engineering and technology010402 general chemistry01 natural sciencesSpray pyrolysiseuropium compoundsTb3+White-Emitting CaMoO4Physical and Theoretical Chemistrydensity functional theorycalcium compoundscomputation theoryenamelsPhosphor021001 nanoscience & nanotechnologyred phosphorselectronic structureCo-Doped Eu3+0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsESTRUTURA ELETRÔNICAGeneral Energyphotoluminescence spectroscopylight emissionphosphors0210 nano-technologyspray pyrolysisCo dopedscanning electron microscopy
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