Search results for "Calcar"
showing 10 items of 131 documents
Unexplored alternative use of calcareous sludge from the paper-pulp industry in green geopolymer construction materials
2020
Abstract Calcareous sludge is an alkaline waste produced by the paper pulp industry that is commonly disposed of in land-fill. However, recent studies and the European regulations discourage such practice. This work investigates an alternative and innovative way to recycle and reuse this waste, as filler, in the production of green geopolymeric mortars intended for applications in construction. This is the first time that this calcareous sludge is used to produce novel waste-based materials, in both construction and geopolymer technology. The novel alkali-activated mortar also uses biomass fly ash – another slightly investigated waste stream – to substitute the metakaolin (70 wt% substituti…
A risk assessment proposal for underground cavities in Hard Soils-Soft Rocks
2018
Abstract Underground calcarenite quarries in Marsala (Sicily) have been involved in a number of collapses that have, seriously damaged numerous buildings. The stability conditions were therefore examined in order to assess risk conditions within the historical centre of the town and the surrounding areas, which are subject to urban expansion. Starting with an extensive collection of historical information, the research was carried out through surveys of the cavities, systematic sampling of material, petrographic analysis and geotechnical testing. The results of laboratory tests and in situ investigations provided a geotechnical characterization of both the intact material and the rock mass.…
Biocalcite and Carbonic Acid Activators
2017
Based on evolution of biomineralizing systems and energetic considerations, there is now compelling evidence that enzymes play a driving role in the formation of the inorganic skeletons from the simplest animals, the sponges, up to humans. Focusing on skeletons based on calcium minerals, the principle enzymes involved are the carbonic anhydrase (formation of the calcium carbonate-based skeletons of many invertebrates like the calcareous sponges, as well as deposition of the calcium carbonate bioseeds during human bone formation) and the alkaline phosphatase (providing the phosphate for bone calcium phosphate-hydroxyapatite formation). These two enzymes, both being involved in human bone for…
Single nanogranules preserve intracrystalline amorphicity in biominerals.
2015
We revisit the ultrastructural features of different calcareous biominerals and identify remarkable similarities: taxonomically very distant species show a common nanogranular structure, even if different extracellular secretion patterns are employed or calcium carbonate polymorphs formed. By these analyses, we elucidate the locus of the small fraction of intracrystalline organic matrix revealing its intergranular character and localize the intracrystalline amorphous calcium carbonate moiety commonly found in mesocrystalline biominerals and provide a first explanation for the pathway by which it is preserved.
Field and microcosm experiments to evaluate the effects of agricultural Cu treatment on the density and genetic structure of microbial communities in…
2006
The effects of Cu amendment on indigenous soil microorganisms were investigated in two soils, a calcareous silty clay (Ep) and a sandy soil (Au), by means of a 1-year field experiment and a two-month microcosm incubation. Cu was added as 'Bordeaux mixture' [CuSO(4), Ca(OH)(2)] at the standard rate used in viticulture (B1=16 kg Cu kg(-1) soil) and at a higher level of contamination (B3=48 kg Cu ha(-1) soil). More extractable Cu was observed in sandy soil (Au) than in silty soil (Ep). Furthermore, total Cu and Cu-EDTA declined with time in Au soil, whereas they remained stable in Ep soil. Quantitative modifications of the microflora were assessed by C-biomass measurements and qualitative modi…
The internal calcar septum and its contact with the virtual stem in THR: a computer tomographic evaluation.
2003
The internal calcar septum is a ridge of cortical bone protruding from the inner cortical wall of the proximal femur into the medullary canal. It extends from the lesser trochanter into the femoral neck and narrows the femoral cavity in its dorsal third. This region is essential for THR stability, but the degree of contact between the septum and standard THR implants has never been studied. We obtained CT scans of 50 arthrotic hip joints from patients requiring THR. Virtual stems (50 straight/wedge-shaped and 50 anatomic stems) were placed in CT images of the femora using a PC-based preoperative planning unit. The dimensions of the septum, degree and location of contact between the septum a…
Common genetic denominators for Ca++-based skeleton in Metazoa: role of osteoclast-stimulating factor and of carbonic anhydrase in a calcareous spong…
2012
Calcium-based matrices serve predominantly as inorganic, hard skeletal systems in Metazoa from calcareous sponges [phylum Porifera; class Calcarea] to proto- and deuterostomian multicellular animals. The calcareous sponges form their skeletal elements, the spicules, from amorphous calcium carbonate (ACC). Treatment of spicules from Sycon raphanus with sodium hypochlorite (NaOCl) results in the disintegration of the ACC in those skeletal elements. Until now a distinct protein/enzyme involved in ACC metabolism could not been identified in those animals. We applied the technique of phage display combinatorial libraries to identify oligopeptides that bind to NaOCl-treated spicules: those oligop…
Entella. Manufatti in pietra tenera di epoca medievale. Primi risultati da un approccio multidisciplinare
2016
Da oltre trent’anni anni la Scuola Normale Superiore conduce indagini archeologiche nel sito di Rocca d’Entella (Contessa Entellina, PA) e ricognizioni nel territorio comunale di Contessa Entellina. Le ricerche hanno permesso di delineare la storia del popolamento umano dall’antichità all’epoca moderna in un’ampia area della Sicilia occidentale interna, comprendente un centro d’altura naturalmente forti$cato (Entella) che per secoli ha mantenuto una $sionomia urbana e un’ampia porzione di territorio da esso dipendente, almeno in alcune epoche storiche. Per il Medioevo, in particolare, le ricerche hanno mostrato una ripresa dell’insediamento aperto già in epoca tardobizantina e ancor più nel…
Differenziazione e quantificazione dei carbonati litogenici e pedogenici di Gypsisuoli forestali attraverso l'analisi isotopica
2004
Gli autori riferiscono sui tipi e sui modelli di genesi dei carbonati dei suoli, attraverso l’uso degli isotopi del 13C. Lo studio è stato condotto in un’area dell’interno collinare argilloso siciliano, su suoli che evolvono sui depositi evaporitici della Serie Gessoso-Solfifera. Sono stati scelti cinque pedon su litotipi calcarei e non. I pedon sono stati descritti in campo e campionati secondo la sequenza degli orizzonti genetici; sui campioni di suolo sono state eseguite le seguenti analisi: tessitura, reazione, conducibilità elettrica, gesso, carbonio organico ed inorganico. Inoltre, parallelamente sono state eseguite le analisi isotopiche del carbonio organico ed inorganico. I risultat…
The Calabrian Stage redefined
2008
The name Calabrian was introduced in the geological literature by the French stratigrapher Maurice Gignoux in 1910, and later described in his important monograph (633 pages) "Les formations marines pliocènes et quaternaires de l'Italie du sud et de la Sicile" published in 1913. Detailed data were provided on several sections (Santa Maria di Catanzaro, Caraffa, Monasterace, Palermo) and on their fossil content. The Calabrian Stage has commonly been used for over fifty years as the oldest subdivision of the Quaternary, notably in the time scales of Berggren & van Couvering (1974) and Haq & Eysinga (1987). However, after the GSSP for the Pliocene/Pleistocene boundary (P/P) was approved by INQ…