Search results for "Calcite"
showing 10 items of 191 documents
Integrative analysis of the mineralogical and chemical composition of modern microbialites from ten Mexican lakes: What do we learn about their forma…
2021
International audience; Interpreting the environmental conditions under which ancient microbialites formed relies upon comparisons with modern analogues. This is why we need a detailed reference framework relating the chemical and mineralogical compositions of modern microbialites to the physical and chemical parameters prevailing in the environments where they form. Here, we measured the chemical, including major and trace elements, and mineralogical composition of microbialites from ten Mexican lakes as well as the chemical composition of the surrounding waters. Saturation states of lakes with different mineral phases were systematically determined and correlations between solution and so…
Simulated European stalagmite record and its relation to a quasi-decadal climate mode
2013
Abstract. A synthetic stalagmite record for the Bunker cave is constructed using a combined climate-stalagmite modeling approach. The power spectrum of the simulated speleothem calcite δ18O record has a pronounced peak at quasi-decadal time scale. Interestingly, mixing processes in the soil and karst above the cave represent a natural low-pass filter of the speleothem climate archive. We identify a quasi-decadal mode characterized by a "tripole pattern" of sea surface temperature affecting stalagmite δ18O values. This pattern, which is well-known in literature as the quasi-decadal mode in the North Atlantic, propagates eastwards and affects western European temperature surrounding the cave.…
Impact of basin burial and exhumation on Jurassic carbonates diagenesis on both sides of a thick clay barrier (Paris Basin, NE France).
2014
27 pages; International audience; Several diagenetic models have been proposed for Middle and Upper Jurassic carbonates of the eastern Paris Basin. The paragenetic sequences are compared in both aquifers to propose a diagenetic model for the Middle and Late Jurassic deposits as a whole. Petrographic (optical and cathodoluminescence microscopy), structural (fracture orientations) and geochemical (δ18O, δ13C, REE) studies were conducted to characterize diagenetic cements, with a focus on blocky calcite cements, and their connection with fracturation events. Four generations of blocky calcite (Cal1-Cal4) are identified. Cal1 and Cal2 are widespread in the dominantly grain-supported facies of t…
Abiotic and biotic controls on methane formation down to 2.5 km depth within the Precambrian Fennoscandian Shield
2017
Abstract Despite a geological history characterised by high temperature and pressure processes and organic carbon deprived crystalline bedrock, large amounts of hydrocarbons are found in deep groundwaters within Precambrian continental shields. In many sites, methane comprises more that 80% of the dissolved gas phase reaching concentrations of tens of mmol l −1 . In this study, we used isotopic methods to study the carbon isotope systematics and sources of crustal methane within the Fennoscandian Shield. The main study sites were the Outokumpu Deep Drill Hole and the Pyhasalmi mine in Finland, both of which allow groundwater sampling down to 2.5 km depth and have been previously studied for…
Intra-skeletal variability in trace elemental content of Precolumbian Chupicuaro human bones: the record of post-mortem alteration and a tool for pal…
2011
14 pages; International audience; This study applies an intra-skeletal sampling strategy to examine post-mortem alteration of archaeological human bone from west Mexico, and to reconstruct ancient diet. Human bone from the Chupicuaro culture (Mexico, Preclassic period) constitutes an ideal material with which to examine subsistence strategies because the specific hydrothermal environment in which the population lived would have provided certain food components (hydrothermal waters and carbonates) with distinct signature in Ca, Mg, F, Li, Sr, Mn, V and U values. Four to ten samples were taken from the long bones of six skeletons. Bone trace element content (Ca, P, F, Mn, Mg, Na, Li, V, Zn, R…
Modern sedimentary analogues and integrated monitoring to understand varve formation in the Mediterranean Lake Montcortès (Central Pyrenees, Spain)
2018
Este artículo contiene 13 páginas, 6 figuras, 1 tabla.
Revised phosphate-water fractionation equation reassessing paleotemperatures derived from biogenic apatite.
2010
8 pages; International audience; Oxygen isotopes of biogenic apatite have been widely used to reassess anomalous temperatures inferred from oxygen isotope ratios of ancient biogenic calcite, more prone to diagenetic alteration. However, recent studies have highlighted that oxygen isotope ratios of biogenic apatite differ dependent on used analytical techniques. This questions the applicability of the phosphate–water fractionation equations established over 25 years ago using earlier analytical techniques to more recently acquired data. In this work we present a new phosphate–water oxygen isotope fractionation equation based on oxygen isotopes determined on fish raised in aquariums at contro…
Effects of magnesium deprivation on development and biomineralization in the sea urchin Arbacia lixula
2019
Echinoderms have an extensive endoskeleton composed of magnesian calcite and occluded matrix proteins. As biomineralization in sea urchin larvae is sensitive to the Magnesium:Calcium ratio of seawater, we investigated the effects of magnesium deprivation on development and skeletogenesis in the sea urchin Arbacia lixula. We focused on the localization of the skeletogenic cells (primary mesenchyme cells) and the spatial expression of associated genes. Embryos reared in Mg-free seawater exhibited developmental delay from 6-h post-fertilization and at 24 h embryos showed complete lack of biomineral formation. Larvae (48–72 h) exhibited severe skeleton malformations. Fluorescent labelling revea…
Specifications for carbonate content quantification in recent marine sediments using Rock-Eval pyrolysis
2019
11 pages; International audience; The amount of CaCO3 in sediments and/or sedimentary rocks is usually measured by calcimetry while the nature of the carbonates is determined by X-ray diffraction. Recently, a carbonate recognition method based on the results of Rock-Eval pyrolysis was proposed in 2014 by Pillot et al. [1]. Rock-Eval pyrolysis is also widely used for the characterization of recent sediments. However, later in 2015 Baudin et al. [2] noticed that some of the characteristics of recent sediments tended to produce different results from those of more classical Rock-Eval analyses, causing bias in interpretations.In this study, the thermal stability of fossil and recent marine carb…
The open metastable structure of a collapsible sand: fabric and bonding
2015
This paper deals with the compositional and textural characteristics determining open metastable structures in the pleistocenic sand outcropping in the Agrigento district (Sicily). The aim of the study was to individuate the bonding types occurring between grains that could generate matric suction phenomena. The composition and microfabric were characterised by means of granulometry, porosimetry, permeability, optical and ESEM-EDS microscopy, thermogravimetry and XR diffractometry, electric conductivity, and ionic chromatography. The data thus acquired show that the skeleton of the sand is constituted mostly by bioclasts and microfossils, calcite and quartz monocrystalline grains. Moreover,…