Search results for "Calibration"
showing 10 items of 890 documents
Precision luminosity measurements at LHCb
2014
Measuring cross-sections at the LHC requires the luminosity to be determined accurately at each centre-of-mass energy $\sqrt{s}$. In this paper results are reported from the luminosity calibrations carried out at the LHC interaction point 8 with the LHCb detector for $\sqrt{s}$ = 2.76, 7 and 8 TeV (proton-proton collisions) and for $\sqrt{s_{NN}}$ = 5 TeV (proton-lead collisions). Both the "van der Meer scan" and "beam-gas imaging" luminosity calibration methods were employed. It is observed that the beam density profile cannot always be described by a function that is factorizable in the two transverse coordinates. The introduction of a two-dimensional description of the beams improves sig…
Uncertainty Assessment of a Water-Quality Model for Ephemeral Rivers Using GLUE Analysis
2011
Every model is, by definition, a simplification of the system under investigation. Although it would be desirable to reduce the gap between the simulated and the observed behaviors of the system to zero, this reduction is generally impossible owing to the unavoidable uncertainties inherent in any modeling procedure. Uncertainty analyses can provide useful insights into the best model approach to be used for obtaining results with a high level of significance and reliability. The evaluation of parameter uncertainties is necessary for calibration and for estimating the impact of these uncertainties on model performance. In this context, the uncertainty of a river water-quality model developed…
Assessment of data availability influence on integrated urban drainage modelling uncertainty
2009
In urban water quality management, several models are connected and integrated for analysing the fate of pollutants from the sources in the urban catchment to the final recipient; classical problems connected with the selection and calibration of parameters are amplified by the complexity of the modelling approach increasing their uncertainty. The present paper aims at studying the influence of reductions in available data on the modelling response uncertainty with respect to the different integrated modelling outputs (both considering quantity and quality variables). At this scope, a parsimonious integrated home-made model has been used allowing for analysing the combinative effect of data…
An intercalibration study of the use of 4-Methyumbelliferyl-ß-D-glucuronide for the specific enumeration of Escherichia coli in seawater and marine s…
1991
A fluorogenic assay for the specific detection of Escherichia coli on the basis of its β-glucuronidase activity (MUG method) was applied to seawater and marine sediments with different contamination levels. The study was carried out in three Mediterranean areas (Malaga-Spain, Nice-France and Palermo-Sicily), using strictly standardized methods (membrane filtration), media (mFC and Chapman-TTC agars) and reagents, to evaluate statistically its sensitivity and specificity according to the origin and contamination of samples, the workers performing the tests and the selected culture media. The results obtained indicate that the MUG method is highly specific (94.5%) and sensitive (90.8%) for th…
Application of an HPLC-MS/MS method for mycotoxin analysis in commercial baby foods
2012
Abstract This article describes the validation of an analytical method for the detection of 21 mycotoxins in baby food. The analytical method is based on the simultaneous extraction of selected mycotoxins by matrix solid-phase dispersion (MSPD) followed by liquid chromatography coupled with tandem mass spectrometry (LC–MS/MS) using a hybrid triple quadrupole-linear ion trap mass spectrometer (QTRAP®). Information Dependent Acquisition (IDA), an extra confirmation tool for samples that contain the selected mycotoxins, was used. The matrix effects were evaluated, and the corrections for the matrix effects were performed using two calibration approaches: external matrix-matched calibration and…
New method for remote and repeatable monitoring of intraocular pressure variations
2014
We present initial steps toward a new measurement device enabling high-precision, noncontact remote and repeatable monitoring of intraocular pressure (IOP)-based on an innovative measurement principle. Using only a camera and a laser source, the device measures IOP by tracking the secondary speckle pattern trajectories produced by the reflection of an illuminating laser beam from the iris or the sclera. The device was tested on rabbit eyes using two different methods to modify IOP: via an infusion bag and via mechanical pressure. In both cases, the eyes were stimulated with increasing and decreasing ramps of the IOP. As IOP variations changed the speckle distributions reflected back from th…
Measurement and storage of a network of jacobians as a method for the visual positioning of a robot arm
1996
The goal of this paper is to describe a method to position a robot arm at any visible point of a given workspace without an explicit on line use of the analytical form of the transformations between real space and camera coordinates (camera calibration) or between cartesian and joint coordinates (direct or inverse kinematics of the robot arm). The formulation uses a discrete network of points distributed all over the workspace in which a procedure is given to measure certain Jacobian matrices which represent a good local linear approximation to the unknown compound transformation between camera and joint coordinates. This approach is inspired by the biological observation of the vestibulo-o…
Numerical dating of the Eckfeld maar fossil site, Eifel, Germany: a calibration mark for the Eocene time scale.
2000
Sediments of the Eckfeld maar (Eifel, Germany) bear a well-preserved Eocene fauna and flora. Biostratigraphically, Eckfeld corresponds to the Middle Eocene mammal reference level MP (Mammals Paleogene) 13 of the ELMA (European Land Mammal Age) Geiseltalian. In the maar crater, basalt fragments were drilled, representing explosion crater eruption products. By 40Ar/39Ar dating of the basalt, for the first time a direct numerical calibration mark for an Eocene European mammal locality has been established. The Eckfeld basalt inverse isochron date of 44.3 +/- 0.4 Ma suggests an age for the Geiseltalian/Robiacian boundary at 44 Ma and, together with the 1995 time scale of Berggren et al., a time…
Direct chromatographic study of the enantioselective biodegradation of ibuprofen and ketoprofen by an activated sludge
2018
[EN] The quantification of the enantiomeric fraction (EF) during the biodegradation process is essential for environmental risk assessment. In this paper the enantioselective biodegradation of ibuprofen, IBU, and ketoprofen, KET, two of the drugs most consumed, was evaluated. Biodegradation experiments were performed in batch mode using a minimal salts medium inoculated with an activated sludge (collected from a Valencian Waste Water Treatment Plant) and supplemented with the racemate of each compound. The inoculum activity was verified using fluoxetine as reference compound. The experimental conditions used (analyte concentration and volume of inoculum) were chosen according to OECD guidel…
Comparison between sodium dodecylsulphate and cetyltrimethylammonium bromide as mobile phases in the micellar liquid chromatography determination of …
2004
The retention behaviour of non-steroidal anti-inflammatory drugs (NSAIDs) using micellar mobile phases of sodium dodecylsulphate (SDS) is studied and compared with that observed with micellar mobile phases of cetyltrimethylammonium bromide (CTAB). A liquid chromatographic procedure for the determination of acemetacin, diclofenac, indomethacin, ketoprofen, naproxen and tolmetin in pharmaceutical preparations is described. The proposed system uses a Kromasil C18 analytical column and a solution of 0.15 M SDS at pH 3 with 10% 1-propanol as mobile phase. Under these conditions, the studied NSAIDs elute between 6 and 10 min at a 1 mL min(-1) flow rate. Limits of detection (LOD) are lower than 0.…