Search results for "Capacitor"
showing 10 items of 164 documents
Solution-processed transparent ferroelectric nylon thin films
2019
We have developed a method to solution process strongly hydrogen-bonded odd nylons into ferroelectric thin films.
Dielectric spectroscopy as a potential technique for prediction of kiwifruit quality indices during storage
2019
Dielectric spectroscopy has been employed as a simple, low cost and a non-destructive way for prediction of some physicochemical indices of kiwifruit during storage. A parallel-plate capacitor was developed and supplied with sinusoidal voltage waves within a frequency range of 40 kHz – 20 MHz. Dielectric properties of samples were measured by the dielectric sensor. Additionally, changes associated with fruit ripening properties, including firmness, total soluble solid (TSS) and pH were determined as a function of time at 2 °C. The results showed that storage time significantly affected the quality characteristics of kiwifruit. Artificial neural networks (ANNs) were employed to develop model…
Lumped parameter approach of nonlinear networks with transistors
1991
In this chapter we study the lumped parameter modelling of a large class of circuits composed of bipolar transistors, junction diodes and passive elements (resistors, capacitors, inductors). All these elements are nonlinear: the semiconductor components are modelled by “large signal” equivalent schemes, the capacitors and inductors have monotone characteristics while the resistors can be included in a multiport which also has a monotone description.
Boosting the supercapacitive behavior of CoAl-layered double hydroxides via tuning the metal composition and interlayer space
2020
Layered double hydroxides (LDHs) are promising supercapacitor materials due to their wide chemical versatility, earth abundant metals and high specific capacitances. Many parameters influencing the supercapacitive performance have been studied such as the chemical composition, the synthetic approaches, and the interlayer anion. However, no systematic studies about the effect of the basal space have been carried out. Here, two-dimensional (2D) CoAl-LDHs were synthesized through anion exchange reactions using surfactant molecules in order to increase the interlayer space (ranging from 7.5 to 32.0 Å). These compounds exhibit similar size and dimensions but different basal space to explore excl…
Ionic Liquid-Based Electrolytes for Supercapacitor and Supercapattery
2019
There is a strong desire to replace or complement aqueous and organic electrolytes by ionic liquids (ILs) in electrochemical energy storage (EES) devices to achieve high operating voltages and hence high energy capacity. ILs are regarded as the inherent and competitive electrolytes since they were introduced to the electrochemical research community because they can overcome many disadvantages of the conventional aqueous and organic electrolytes, such as narrow potential windows, volatility, and flammability. This paper reviews critically the recent literatures of IL-based electrolytes used in supercapacitor, supercapattery, and micro-supercapacitor. Supercapattery is a generic term for var…
MATERIALS AND PROCESSING ISSUES FOR THE MANUFACTURING OF INTEGRATED PASSIVE AND ACTIVE DEVICES ON FLEXIBLE SUBSTRATES
2008
Plast_ICs is a Public/Private Laboratory funded by Italian Government aimed to build a novel technological platform for the development of flexible electronics, mainly, but not solely, based on thin inorganic films. Integration of different functions, on single and/or multiple plastic foils, to generate a smart system is the final goal of the project. The building blocks of the platform will be presented, starting from the different plastic substrates characterization, going through the development of active devices, such as thin-film- transistors, and passive devices, like thin-film- resistors, capacitors, inductors. Fully inorganic elementary devices, based on optical patterning and in va…
Reduction of thermal damage in ultrathin gate oxides after intrinsic dielectric breakdown
2001
We have compared the thermal damage in ultrathin gate SiO2 layers of 5.6 and 3 nm thickness after intrinsic dielectric breakdown due to constant voltage Fowler-Nordheim stress. The power dissipated through the metal-oxide-semiconductor capacitor during the breakdown transient, measured with high time resolution, strongly decreases with oxide thickness. This is reflected in a noticeable reduction of the thermal damage found in the structure after breakdown. The effect can be explained as the consequence of the lower amount of defects present in the oxide at the breakdown instant and of the occurrence of a softer breakdown in the initial spot. The present data allow us to estimate the power t…
Optimization of anodizing process of tantalum for Ta2O5-based capacitors
2020
Anodic oxides were grown to 50 V on Ta in several organic ions containing anodizing baths. Their properties were compared with anodic Ta oxide film grown to the same formation voltage in 0.1 M NaOH. Anodizing process carried out in sodium citrate led to the growth of the anodic oxide with the best blocking properties whilst, when Ta is anodized in sodium adipate, a significant part of the circulated charge is wasted in side reactions, such as oxygen evolution. Photoelectrochemical measurements showed the presence of optical transitions at energy lower than the band gap for the anodic films grown in citrate and tartrate electrolytes, attributed to localized electronic states located close to…
Superior energy density through tailored dopant strategies in multilayer ceramic capacitors
2020
The Gerson–Marshall (1959) relationship predicts an increase in dielectric breakdown strength (BDS) and therefore, recoverable energy density (Wrec) with decreasing dielectric layer thickness. This relationship only operates however, if the total resistivity of the dielectric is sufficiently high and the electrical microstructure is homogeneous (no short circuit diffusion paths). BiFeO3–SrTiO3 (BF–ST) is a promising base for developing high energy density capacitors but Bi-rich compositions which have the highest polarisability per unit volume are ferroelectric rather than relaxor and are electrically too conductive. Here, we present a systematic strategy to optimise BDS and maximum polaris…
Dense ionic fluids confined in planar capacitors: in- and out-of-plane structure from classical density functional theory
2016
The ongoing scientific interest in the properties and structure of electric double layers (EDLs) stems from their pivotal role in (super)capacitive energy storage, energy harvesting, and water treatment technologies. Classical density functional theory (DFT) is a promising framework for the study of the in- and out-of-plane structural properties of double layers. Supported by molecular dynamics simulations, we demonstrate the adequate performance of DFT for analyzing charge layering in the EDL perpendicular to the electrodes. We discuss charge storage and capacitance of the EDL and the impact of screening due to dielectric solvents. We further calculate, for the first time, the in-plane str…