Search results for "Carbon isotope"

showing 10 items of 135 documents

Acidification processes in a peritidal carbonate succession across the Triassic/Jurassic boundary (Sicily)

2017

For the first time, a correlation between biostratigraphic events and δ13C curve was attempted along an UpperTriassic-Lower Jurassic peritidal limestone succession cropping out in westernmost Sicily. The peritidal carbonates are organized in shallowing upward cycles characterized by subtidal skeletal mudstone to grainstone, intertidal microbial mats and supratidal paleosoils. About 300 meters of this succession covering the Triassic-Jurassic interval were studied in details. On the base of the macro- and microfossil assemblages from the subtidal facies, four informal units have been recognized along the studied section. Unit R1 (at the base, 111 m thick) is dominated by large megalodonts, r…

Triassic-Jurassic boundary biotic crises carbon isotope excursion carbonate platform SicilySettore GEO/02 - Geologia Stratigrafica E Sedimentologica
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Suppression of intestinal microbiota-dependent production of pro-atherogenic trimethylamine N-oxide by shifting L-carnitine microbial degradation.

2014

Abstract Aims Trimethylamine-N-oxide (TMAO) is produced in host liver from trimethylamine (TMA). TMAO and TMA share common dietary quaternary amine precursors, carnitine and choline, which are metabolized by the intestinal microbiota. TMAO recently has been linked to the pathogenesis of atherosclerosis and severity of cardiovascular diseases. We examined the effects of anti-atherosclerotic compound meldonium, an aza-analogue of carnitine bioprecursor gamma-butyrobetaine (GBB), on the availability of TMA and TMAO. Main methods Wistar rats received L-carnitine, GBB or choline alone or in combination with meldonium. Plasma, urine and rat small intestine perfusate samples were assayed for L-car…

TrimethylamineTrimethylamine N-oxideBacterial growthBiologyGeneral Biochemistry Genetics and Molecular BiologyStatistics NonparametricCholinechemistry.chemical_compoundMethylaminesBetaineTandem Mass SpectrometryCarnitineBlood plasmamedicineCholineAnimalsCarnitineGeneral Pharmacology Toxicology and PharmaceuticsRats WistarChromatography High Pressure LiquidMeldoniumCarbon IsotopesMicrobiotaGeneral MedicineBiosynthetic PathwaysRatsBetaineGastrointestinal TractBiochemistrychemistrymedicine.drugMethylhydrazinesLife sciences
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Regional variations in the chemical and helium–carbon isotope composition of geothermal fluids across Tunisia

2011

Abstract Tunisia has numerous thermo-mineral springs. Previous studies have shown that their chemical composition and occurrence are strongly influenced by the regional geology. However little work has been done so far to study the isotopic composition of volatiles associated with these geothermal manifestations. Here, we report on the results of an extensive survey of both natural hot springs and production wells across Tunisia, aimed at investigating the spatial distribution of thermal fluids' geochemical characteristics and He–C isotopic composition. The chemistry of the analyzed samples highlights the heterogeneity of the water mineralization processes in Tunisia, as a consequence of th…

Tunisia010504 meteorology & atmospheric sciencesEarth scienceGeochemistryAquiferengineering.material010502 geochemistry & geophysics01 natural sciencesMantle (geology)Geochemistry and PetrologyTunisia; Helium isotopes; Carbon isotopes; Geothermal fluids; Groundwaters; Thermal springs[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces environmentGroundwaterChemical compositionGeothermal gradientComputingMilieux_MISCELLANEOUS0105 earth and related environmental sciences[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmospheregeographygeography.geographical_feature_categoryRiftCarbon isotopeThermal springsGeologyHelium isotopeSettore GEO/08 - Geochimica E Vulcanologia13. Climate actionIsotopes of carbonMagmatismengineeringHaliteGeothermal fluidGeologyChemical Geology
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Environmental and depositional controls on laminated freshwater carbonates: An example from the Roman aqueduct of Patara, Turkey

2013

Carbonate deposits in aqueducts are a new high-resolution data source for environmental changes during the time of the Roman Empire, notably in the fields of palaeoclimate and spring hydrology. In order to distinguish environmental effects from those related to depositional setting, laminated carbonate deposits were compared along the entire length of an ancient aqueduct channel at Patara, Turkey. The carbonate deposits, up to 80mm in thickness, are composed of lamina couplets up to 1mm thick of alternating porous microspar and dense, columnar sparite. The former formed in the dry, warm season and the latter in the wet, cool season. The presence of biofilms seems to play a role in the devel…

Turkeyaqueductcarbon isotopeRoman eraδ18ORoman aqueductmicrostructureGeochemistryAqueductMuglaArchaeoseismologyPalaeoclimateOceanographybiofilmIsotopes of oxygenSedimentary depositional environmentcarbonatechemistry.chemical_compoundPaleontologyCalcareous sinterwater temperaturepaleoclimatelaminationstable isotopeoxygen isotopeCarbonate depositssinterPataraEcology Evolution Behavior and SystematicsStable isotopesdepositional environmentEarth-Surface ProcessesCalcareous sinterPaleontologyarchaeologyLamination (geology)chemistryCarbonateLayeringenvironmental effectGeologyPalaeogeography, Palaeoclimatology, Palaeoecology
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Isotopically (δ13C and δ18O) heavy volcanic plumes from Central Andean volcanoes: a field study

2017

International audience; Stable isotopes of carbon and oxygen in volcanic gases are key tracers of volatile transfer between Earth's interior and atmosphere. Although important, these data are available for few volcanoes because they have traditionally been difficult to obtain and are usually measured on gas samples collected from fumaroles. We present new field measurements of bulk plume composition and stable isotopes (δ13CCO2 and δ18OH2O+CO2) carried out at three northern Chilean volcanoes using MultiGAS and isotope ratio infrared spectroscopy. Carbon and oxygen in magmatic gas plumes of Lastarria and Isluga volcanoes have δ13C in CO2 of +0.76‰ to +0.77‰ (VPDB), similar to slab carbonate;…

Volcanic gase010504 meteorology & atmospheric sciencesδ18Oδ13CEarth scienceGeochemistry010502 geochemistry & geophysics01 natural sciencesVolcanic GasesIsotopic signatureGeochemistry and Petrology[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyeventIsotope ratio infrared spectroscopy0105 earth and related environmental sciencesevent.disaster_typegeographygeography.geographical_feature_categoryStable isotope ratioCarbon isotopeδ18OFumaroleVolcanoIsotopes of carbon[SDU]Sciences of the Universe [physics]Kinetic fractionationGeology
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A Neandertal dietary conundrum: Insights provided by tooth enamel Zn isotopes from Gabasa, Spain

2022

The characterization of Neandertals’ diets has mostly relied on nitrogen isotope analyses of bone and tooth collagen. However, few nitrogen isotope data have been recovered from bones or teeth from Iberia due to poor collagen preservation at Paleolithic sites in the region. Zinc isotopes have been shown to be a reliable method for reconstructing trophic levels in the absence of organic matter preservation. Here, we present the results of zinc (Zn), strontium (Sr), carbon (C), and oxygen (O) isotope and trace element ratio analysis measured in dental enamel on a Pleistocene food web in Gabasa, Spain, to characterize the diet and ecology of a Middle Paleolithic Neandertal individual. Based on…

Zinc isotope ratiosCarbon IsotopesMultidisciplinaryMiddle PaleolithicNitrogen IsotopesIberian NeandertalsCarnivoraHomininHome de NeandertalPrehistòriaCarnivoryCarbonDietTrace ElementsOxygenZincSpainStrontiumAnimalsZinc IsotopesCollagenDental EnamelToothNeanderthals
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Trophic Transfer of Trace Elements in an Isotopically Constructed Food Chain From a Semi-enclosed Marine Coastal Area (Stagnone di Marsala, Sicily, M…

2012

Trace element accumulation is particularly important in coastal and transitional environments, which act as contaminant buffers between the continental and marine systems. We compared trace element transfer to the biota in two locations with different open-sea exposures in a semi-enclosed marine coastal area (Stagnone di Marsala, Sicily, Italy) using isotopically reconstructed food chains. Samples of sediment, macroalgae, seagrasses, invertebrates, fish, and bird feathers were sampled in July 2006 and analysed for stable carbon and nitrogen isotopes (δ(13)C, δ(15)N) and trace elements (arsenic [As], cadmium [Cd], total mercury [THg], and lead [Pb]). Trophic magnification factors were calcul…

biomagnification transitional systems Stagnone di MarsalaSettore BIO/07 - EcologiaGeologic SedimentsFood ChainHealth Toxicology and MutagenesisBiomagnificationToxicologyPoaceaeFood chainAnimalsSicilyTrophic levelBiodilutionCarbon IsotopesNitrogen IsotopesTrace elementFishesSedimentBiotaGeneral MedicineFeathersSeaweedPollutionInvertebratesIsotopes of nitrogenTrace ElementsEnvironmental chemistryEnvironmental scienceWater Pollutants ChemicalEnvironmental Monitoring
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Transport and partitioning of 13C-photoassimilate between peach fruiting shoots

2008

We used a non-intrusive method (13CO2 feeding) and a manipulative approach to see whether fruiting shoots in peach trees are autonomous or may import carbon from neighboring shoots under forced conditions, and whether the degree of autonomy is influenced by the source-sink relationship on the shoot. In three experiments, leaf to fruit ratio (L:F) of selected fruiting shoots was moderately (2005 and 2006) or strongly (extreme enforcing 2006) altered to either encourage or discourage movement of carbon from 13C-labeled sending shoots (SFS) to receiving fruiting shoots (RFS), both located on the same main scaffold of V-shaped peach trees. At stage I and III of fruit growth, fruit and shoot tip…

branch autonomy carbon isotopes fruiting shoot leaf area Prunus persica sink strength source-sink relations
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Climate-growth relationships of Quercus gussonei (Borzì) Brullo in the Mediterranean region: adaptive traits and water use efficiency.

2016

Due to their marginal distribution, peripheral tree populations are highly vulnerable and are more likely to be influenced by extreme climate conditions. This occurrence is known to cause dieback in many species at their Mediterranean margins. Quercus gussonei (Borzì) Brullo is a deciduous oak endemic of Sicily. It is a thermophilous, peripheral form of Quercus cerris L. which is showing an incipient but ongoing decline. A deeper ecophysiological knowledge is urgently needed on this species in order to plan proper conservation actions and reduce the risk of its extinction. In the aim to understand at what extent changes in environmental conditions could be responsible for Q. gussonei declin…

carbon isotope discrimination dendroecology forest dieback peripheral population in Sicily
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EFFECTS OF SENSITIZED AND UNSENSITIZED LONGWAVE U.V.-IRRADIATION ON THE SOLUTION PROPERTIES OF DNA

1971

— Two types of photoreactions occur in DNA irradiated in aqueous systems with longwave u.v.-light (Λ > 295 nm), namely, (a) thymine dimerization, and (b) single- and double-strand breakage of the sugar phosphate backbone; these two reactions are unrelated. The presence of acetophenone as a photosensitizer caused an increase in dimerization by a factor of 16, and an increase in single-strand breaks by a factor of 4. The number of thymine dimers per single-strand break is about 100 in the sensitized and 25 in the unsensitized reaction. The alteration of the radius of gyration of DNA molecules is that expected by the degradation observed. At the same time the change in hyperchromicity is very …

chemistry.chemical_classificationCarbon IsotopesAqueous solutionSugar phosphatesUltraviolet RaysHyperchromicityPyrimidine dimerDNAGeneral MedicinePhotochemistryBiochemistryThymineRadiation Effectschemistry.chemical_compoundchemistryEscherichia coliRadius of gyrationPhotosensitizerPhysical and Theoretical ChemistryThymineDNAPhotochemistry and Photobiology
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