Search results for "Carbonates"
showing 10 items of 100 documents
Supported Polyhedral Oligomeric Silsesquioxane-Based (POSS) Materials as Highly Active Organocatalysts for the Conversion of CO2
2018
Very high turnover numbers (TON) and productivity values up to 7875 and 740 respectively have been obtained for the conversion of CO2 into cyclic carbonates by using hybrid materials based on imidazolium modified polyhedral oligomeric silsesquioxanes (POSS-Imi) grafted on amorphous silica (SiO2) and mesostructured SBA-15. The heterogeneous organocatalysts were easily prepared via a straightforward synthetic procedure allowing to generate high local concentration spots of imidazolium active sites surrounding the POSS core. This synthetic procedure is also a promising approach for the design of a wide library of hybrid functional materials. The materials do not possess other co-catalytic spec…
Changements environnementaux survenant à la limite Oligocène/Miocène du bassin des Limagnes (Massif central, France).
2018
16 pages; International audience; Continental environments are very sensitive to climatic variations. A unique opportunity to study the climate changes around the Oligocene/Miocene boundary is offered by the Limagne graben Basin (France) where this stage boundary is well constrained by fossils. Indeed, some localities of the Limagne Graben Basin are so rich in mammal remains that they have become a European reference for mammal biostratigraphy. The dominant sedimentary facies of the lacustrine deposits in the northern part of the Limagne Graben Basin are composed of poorly cemented marls and calcarenites containing various plants and animals remains (e.g. algae, fish bones and teeth, gastro…
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Oligo-Miocene lacustrine microbial and metazoan buildups from the Limagne Basin (French Massif Central)
2018
The Limagne Basin (French Massif Central) is an extensive continental lacustrine system accommodating microbial and metazoan buildups from Chattian to Aquitanian age. A description of these buildups and their associated biotic components in Grand Gandaillat and Crechy quarries provides insights into their spatio-temporal distribution patterns. Flats, cauliflowers, domes, cones and coalescent columnar morphologies have been identified with a main laminated mesofabric and laminated, columnar, filamentous and caddisfly-coated microfabrics. Two low-gradient margin models emerged based on the changes in the distribution, morphology and size of the microbial and metazoan-rich deposits through tim…
Reactive transport modelling of carbonate cementation in a deep saline aquifer, the Middle Jurassic Oolithe Blanche Formation, Paris Basin, France.
2016
10 pages; International audience; The Oolithe Blanche Formation (Bathonian, Middle Jurassic) is one of the deep saline aquifers of the Paris Basin in France. The spatial distribution of its reservoir properties (porosity, permeability, tortuosity, etc.) is now better known with relatively homogeneous properties, except for some levels in the central part of the basin, where permeability exhibits higher values. This spatial distribution has been correlated with diagenetic events (variability of cementation) and palaeo-fluid flow circulation phases leading to variable cementation. In this paper, numerical simulations of reactive transport are performed. They provide a preliminary quantitative…
Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.
2012
Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…
Fluid storage and migration properties of sheared Neptunian dykes
2019
Abstract Neptunian dykes are widely reported along the Tethyan carbonate platforms and are commonly considered as subsurface baffles or barriers to fluid flow. However, the fluid storage and migration properties of sheared Neptunian dykes are poorly known. For this reason, we investigate the inner structure and fluid flow properties of two Neptunian dykes, which can be characterized by different architectures if involved or not in brittle shearing processes. The dykes strike ca. WNW-ESE and crosscutting the tight Jurassic limestones exposed at Maranfusa Mt., NW Sicily, Italy. The unsheared and sheared Neptunian dykes are almost sub-vertical and at high-angle with respect to the horizontal p…
Geodynamic control on carbonate diagenesis: Petrographic and isotopic investigation of the Upper Jurassic formations of the Paris Basin (France).
2007
23 pages; International audience; The Oxfordian and Kimmeridgian carbonates of the eastern edge of the Paris Basin display poor reservoir properties (Φb15% and Kb0.1 md). The petrographic investigation and the resultant paragenetic sequence show that this is due to extensive precipitation of 2 types of almost synchronous blocky LMC (Low Magnesian Calcite) cements during mesogenesis (burial). Stable isotope investigation of these non-recrystallized cements, through both microdrilling sampling and in-situ SIMS (Secondary IonMass Spectrometry) analysis, shows that they originated from slightly buffered meteoric fluids (−3‰SMOW to −8‰SMOW) flowing through the Malm carbonate aquifers of the east…
In situ carbon and oxygen isotopes measurements in carbonates by fiber coupled laser diode-induced calcination: A step towards field isotopic charact…
2021
International audience; Natural stable isotopes ratios (δ13Ccarb and δ18Ocarb) of carbonates archived in the geological record are routinely used to reconstruct local and global paleo temperatures and the secular evolution of the biogeochemical carbon cycle. The state-of-the-art technique, employed since the mid 20th century, to measure these isotopic ratios starts with field sampling followed by several steps of physical and chemical laboratory preparation including: (i) microdrilling and/or sawing and crushing, (ii) CO2 release by wet acid digestion, (iii) gas equilibration, purification and transfer, before (iv) gas phase IRMS measurements. While these steps are time and resource consumi…
The relationships between soft-sediment deformation structures and synsedimentary extensional tectonics in Upper Triassic deep-water carbonate succes…
2016
Abstract We describe soft-sediment deformation structures into the Upper Triassic cherty limestone outcropping in the Pizzo Lupo section (Central Sicily, Italy), pertaining to the deep-water palaeodomain of the Southern Tethyan margin. In the study section, mainly consisting of thin-bedded mudstone/marl alternations with bedded chert intercalations, some lithofacies have been separated on the basis of the abundance of the calcium carbonate/clay content and the overall textural features. The deformational structures, displaying different deformational styles as folded and faulted beds, disturbed layers, clastic dikes, and slumps occur mainly in the deformed horizons that involve marl-dominat…