Search results for "Cathode"

A Review of using spray pyrolysis through Sol-gel materials in the synthesis of cathode materials for lithium-ion batteries

2016

Over the years, new synthesis routes of the cathode electrochemical active material for lithium-ion batteries have improved remarkably to optimize their capacity and cycle life performance. This review study focused on the use of some techniques to synthesize the common cathode materials (LiCoO2, LiMn2O4, LiFePO4). The most common and simplest synthesis method was the mixing of powders in their solid-state form and heating them at relatively high temperatures over long periods. Other methods included the formation of sol-gel products that could be either heat-treated more or could be used directly by means of a spray pyrolysis method producing the desired active material. The spray pyrolysi…

BIO-ELECTROCHEMICAL SYSTEMS FOR ENERGY GATHERING FROM WASTEWATER

2017

It has been calculated that annually 1.5 × 108 MWh are wasted as municipal, industrial, and animal wastewater. The recovery of at least part of this energy it is of primary importance in order to approach circular economy. As AD, MFC is a biotechnology that uses microorganism into an anaerobic environment for energy conversion and recovery. Differently from AD, MFC belongs to the sub-division of Bio-Electrochemical Systems (BESs), having the advantage to achieve a direct electrical output. Exoelectrogens bacteria are employed, capable to close their respiratory electron chain on the surface of an electrode. Up to know, BESs were used to extract energy from a multitude of wastes, such as dis…

A single-chamber membraneless microbial fuel cell exposed to air using Shewanella putrefaciens

2016

Abstract Microbial Fuel Cells (MFCs) are bio-electrochemical devices which convert the chemical energy content of organic fuels into electricity, thanks to the ability of anode respiring bacteria to give electrons to the anode. This result is usually achieved under anaerobic conditions, obtained with a sealed anode chamber. Despite this, Shewanella oneidensis has been recognized by many authors to obtain the same results in presence of air. Furthermore, another member of the Pseudomonaceae family, Shewanella putrefaciens, has also shown the capability to catalyze the cathodic oxygen reduction. In this work the capability of S. putrefaciens to work under both anaerobic and micro-aerobic cond…

Optimization of the performance of an air-cathode MFC by changing solid retention time

2017

Structural, Spectroscopic and Electrical Features of Undoped and Mn Doped LiTi2(PO4)3

2010

The study of the ionic conducting material LiTi2(PO 4)3 and of its Mn-substituted derivate reveals that the Mn distribution is strictly related to the synthetic method. The results of the structural refinement of X-ray and neutron (ToF) powder diffraction data and of XPS analysis demonstrate that Mn2+ ions are located on the lithium octahedral site, while Mn3+ and Mn4+ ions occupy the titanium ones. The Mn2+ amount on the lithium site seems to be the main factor responsible for the conductivity decrease observed in doped samples. The EPR spectra evidence clustering effects of Mn on both Li and Ti sites and the presence of more insulated Mn2+ ions. The effect of the major Mn amount on Ti sit…

Electron beam induced growth of silver nanowhiskers

2015

Abstract In this paper we report an electron beam induced rapid (up to several tens of nm/s) growth of silver nanowhiskers from silver nanowire networks coated with TiO 2 by sol–gel method. Different growth conditions are tested and it is demonstrated that growth is optimal for samples with the film thickness in the range 50–200 nm and previously annealed at 400 °C for 5–10 min. Growth mechanism is attributed to cooperative effect of several factors including diffusion of Ag into TiO 2 matrix during annealing, electromigration of Ag atoms caused by strong electric field, and presence of mechanical stresses at interfaces enhanced by thermal expansions due to local heating under e-beam illumi…

The model of recombination process in TlBr

2002

The time-resolved luminescence was used as a tool in the study of recombination process in several undoped TlBr crystals. The spectra and decay kinetics observed under electron beam excitation were investigated. Observation of several luminescence bands with different decay rates shows that more than one recombination center is involved and the recombination process is quite complicated. The band at ∼2.5 eV is dominant under 10 ns excitation pulse (electron beam or nitrogen laser pulses). The results of short-lived absorption and luminescence are used for analysis of possible mechanisms of recombination processes in TlBr.

Application of atomic and nuclear techniques to the study of inhomogeneities in electrodeposited α-particle sources

2002

Three α-particle sources made by different methods of electrodeposition were analysed using α-particle spectrometry, Rutherford backscattering (RBS), and atomic force microscopy (AFM) on several surface zones. The thickness and homogeneity of these sources was studied using RBS, and the results were analysed jointly with those obtained with α-particle spectrometry and AFM techniques. The comparison of the electrodeposition methods showed that the most homogeneous electrodeposited zones corresponded to the source made with a stirring cathode.

First radioactive ions charge bred in REXEBIS at the REX-ISOLDE accelerator

2003

REXEBIS is the charge breeder of the REX-ISOLDE post accelerator. The radioactive 1$^{+}$ ions produced at ISOLDE are accumulated, phase-space cooled and bunched in the REXTRAP, and thereafter injected into the EBIS with an energy up to 60 keV. The REXEBIS produced the first charge bred ions in August 2001 and has been running nearly non-stop during September to December 2001. It has delivered stable $^{39}$K$^{10+}$ and $^{23}$Na$^{6+}$ beams generated in the ion source in front of REXTRAP with a Na$^{7+}$ current exceeding 70 pA (6x10$^{7}$ p/s). Stable $^{27}$Al$^{7+}$ and $^{23}$Na$^{6+}$ from ISOLDE and also the first radioactive $^{26}$Na$^{7+}$ and $^{24}$Na$^{7+}$ beams (just 5x10$^…

Application and development of ion-source technology for radiation-effects testing of electronics

2017

Abstract Studies of heavy-ion induced single event effect (SEE) on space electronics are necessary to verify the operation of the components in the harsh radiation environment. These studies are conducted by using high-energy heavy-ion beams to simulate the radiation effects in space. The ion beams are accelerated as so-called ion cocktails, containing several ion beam species with similar mass-to-charge ratio, covering a wide range of linear energy transfer (LET) values also present in space. The use of cocktails enables fast switching between beam species during testing. Production of these high-energy ion cocktails poses challenging requirements to the ion sources because in most laborat…