Search results for "Cathode"
showing 10 items of 296 documents
Glucose oxidase as a biocatalytic enzyme-based bio-fuel cell using Nafion membrane limiting crossover
2013
A novel combination for an Enzyme-based Biofuel cell included a Nafion membrane as an ion transporter that maintained a working cell charge and inhibited membrane degradation. The prototype cell chamber used oxygen (O2) in the cathode cell and glucose in the anode. The Nafion membrane stability studied here was evidently in the region of 0% loss of conductivity as the charge was constant and increased after the addition of glucose. The prototype cell chamber used NaCl in the cathode cell and glucose oxidase (GOx) in the anodic chamber was successfully studied for membrane stability showed in this study no evidence of poisoning from membrane leakage in a controlled pH environment. There was …
Pulsed gas injection for X-ray spectroscopy of highly charged ions stored in the magnetic trapping mode of an electron beam ion trap
1998
Abstract Highly charged atoms produced in an electron beam ion trap were stored after the electron beam was turned off by operating the trap in the magnetic trapping mode. Such storage allowed monitoring charge exchange reactions between the stored ions and residual neutral gas present in the trap by X-ray detection. The charge exchange reactions were enhanced by the application of a pulse of neutral gas. The method was exemplified for the case of H-like uranium interacting with neutral neon, where the K-shell X-rays and the series limit for the electron capture of U91+ were observed.
Charge transport in electrically responsive polymer layers
2007
The processes of charge transport in the conducting polymer electrochromic films have been studied by means of spectral-electrochemical method, impedance spectroscopy and cyclic voltametry measurements. It has been shown that charge transport during the coloration-bleaching processes is not symmetric phenomenon. By means of impedance spectroscopy the effective diffusion coefficients for anode and cathode charge transport have been measured. The higher rate of charge transport in the bleaching process as compared to coloration is considered in the frame of conformation rebuilding of conducting polymer chains.
The Membrane-Less Microbial Fuel Cell (ML-MFC) with Ni-Co and Cu-B Cathode Powered by the Process Wastewater from Yeast Production
2020
Research related to measurements of electricity production was combined with parallel wastewater parameter reduction in a membrane-less microbial fuel cell (ML-MFC) fed with industry process wastewater (from a yeast factory). Electrodes with Ni–Co and Cu–B catalysts were used as cathodes. A carbon electrode (carbon cloth) was used as a reference due to its widespread use. It was demonstrated that all analyzed electrodes could be employed as cathodes in ML-MFC fed with process wastewater from yeast production. Electricity measurements during ML-MFC operations indicated that power (6.19 mW) and current density (0.38 mA·cm−2) were the highest for Ni–Co electrodes. In addition, during the explo…
Peculiarities of imaging one- and two-dimensional structures in an emission electron microscope. 1. theory
2000
Local changes in work function cause deviations of the electrical microfield near a sample surface as a result of the uniform accelerating field distribution between the sample (cathode) and the extractor electrode (anode). This results in a change in the electron trajectories. As a consequence, the microscope image shows remarkable changes in position, size, intensity and lateral resolution of distinct details, which can be quantitatively described by the calculations presented here. Analysing these effects in the image gives an opportunity to determine the real lateral size of the observed structures and the distribution of local contact potentials.
Formation of luminescence centres under excitation with electron beams in PbWO 4 and ZnWO 4 crystals
2005
The leading edge of intrinsic luminescence pulse in PbWO 4 and ZnWO 4 single crystals is studied. The rise of luminescence intensity is observed after excitation with electron beam pulse. The luminescence rise is shown tobe a result of luminescence center formation via electron-hole recombination within spatially correlated pairs. An electron of a geminate electron-hole pair of PbWO 4 crystal self-traps and stimulates self-trapping of a hole at a close distance. In the ZnWO 4 crystal a hole of a geminate electron-hole pair self-traps and stimulates self-trapping of the electron producing a W 5 + center at a short distance. The rise-time of luminescence depends on spatial separation of recom…
Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4, solved by manual electron-diffraction tomography.
2012
The new mineral sarrabusite Pb5CuCl4(SeO3)4 has been discovered in the Sardinian mine of Baccu Locci, near Villaputzu. It occurs as small lemon–yellow spherical aggregates of tabular crystals (< 10 µm) of less than 100 µm in diameter. The crystal structure has been solved from and refined against electron diffraction of a microcrystal. Data sets have been measured by both a manual and an automated version of the new electron-diffraction tomography technique combined with the precession of the electron beam. The sarrabusite structure is monoclinic and consists of (010) layers of straight chains formed by alternating edge-sharing CuO4Cl2 and PbO8 polyhedra parallel to the c axis, which sha…
High-frequency electrodeless discharge lamps for atomic absorption analysis
2003
Abstract In this paper we present the results of an investigation of high-frequency electrodeless discharge lamps (HFEDLs), containing Cd, Zn, Hg, As, Te, Se, Pb, Sn, Tl and Bi, developed in our laboratories as light sources for atomic absorption spectrometry (AAS). Important physical processes in the lamps are discussed. Essential characteristics of HFEDLs for AAS, such as intensity, stability and operating life are considered. The intensities and detection limits are compared with the corresponding characteristics of hollow cathode lamps. The temporal behavior of an As HFEDL is compared with that of a commercially available electrodeless discharge lamp. Detection limits in graphite furnac…
Boron-Doped Diamond Electrodes for Electroorganic Chemistry
2011
Boron-doped diamond (BDD) electrodes provide an unusually wide electrochemical window in protic media, since there exist large offset potentials for the evolution of molecular hydrogen and oxygen, respectively. At the anode, alcohols are specifically converted to alkoxyl radicals. These can be used for chemical synthesis. When the enormous reactivity of such intermediate spin centers is not controlled, mineralization or electrochemical incineration dominates. Efficient strategies include either high substrate concentrations or fluorinated alcohols which seem to stabilize the spin centers in the course of reaction.
Structure solution with automated electron diffraction tomography data: different instrumental approaches
2011
Summary Over the past few years automated electron diffraction tomography has become an established technique for structure solution of nano-crystalline material. The intentional choice of an arbitrary tilt axis and thus, the use of nonoriented diffraction patterns (off-zone acquisition) together with fine equidistant sampling of the reciprocal space result in high quality intensity data sets. Coupling automated electron diffraction tomography with electron beam precession (Vincent & Midgley, 1994) enables sampling of intensities between the static slices of reciprocal space and therefore enhances the quality of intensity data further; relatively complex structures have been solved using 3D…