Search results for "Ce4+"

showing 2 items of 2 documents

Mechanistic Investigations of the BZ Reaction with Oxalic Acid Substrate. I. The Oscillatory Parameter Region and Rate Constants Measured for the Rea…

2004

This paper is the first part of a study reinvestigating the mechanism of the Belousov-Zhabotinsky (BZ) reaction of oxalic acid, which is the simplest organic substrate for a BZ oscillator. New experiments are performed to find the oscillatory region in 1 M sulfuric acid at 20 °C. The removal rate of the end product bromine by an inert gas stream is a critical parameter here: oscillations can be observed only in a window of that parameter. The “rate constant” for the physical removal of bromine is measured as a function of the gas flow rate and reactor volume; furthermore, the rate constants of three component reactions important in this system are also determined. These are oxygen atom tran…

BELOUSOV-ZHABOTINSKII REACTIONBromineCE4+-MALONIC ACIDInorganic chemistryOxalic acidchemistry.chemical_elementSulfuric acidMALONIC-ACIDMODEL-CALCULATIONSCHEMICAL-REACTIONBROMINE REMOVALchemistry.chemical_compoundBelousov–Zhabotinsky reactionReaction rate constantchemistryINFINITE PERIOD BIFURCATIONHypobromous acidFEEDBACK LOOPORGANIC SUBSETNUMERICAL-SIMULATIONPhysical and Theoretical ChemistryInert gasSettore CHIM/02 - Chimica FisicaBromous acidThe Journal of Physical Chemistry A
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Exciton interaction with Ce3+ and Ce4+ ions in (LuGd)3(Ga,Al)5O12 ceramics

2021

The authors acknowledge the expert help of the staff of MAX IV Laboratory. The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. I.V. acknowledges the support of Russian Foundation for Basic Research # 20-52-S52001.

Materials scienceAbsorption spectroscopyExcitonBiophysicsAnalytical chemistry02 engineering and technology010402 general chemistry01 natural sciences7. Clean energyBiochemistryCeSynchrotronTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYSpectroscopy:NATURAL SCIENCES::Physics [Research Subject Categories]General Chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and OpticsXANESXANES0104 chemical sciencesAbsorption edgeCe4+Absorption bandEnergy transferGarnet scintillatorsExcited stateExcitons0210 nano-technologyLuminescence
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