Search results for "Chalcogen"
showing 10 items of 189 documents
Hybrid chalcogenide nanoparticles: 2D-WS2 nanocrystals inside nested WS2 fullerenes.
2013
The MOCVD assisted formation of nested WS2 inorganic fullerenes (IF-WS2) was performed by enhancing surface diffusion with iodine, and fullerene growth was monitored by taking TEM snapshots of intermediate products. The internal structure of the core–shell nanoparticles was studied using scanning electron microscopy (SEM) after cross-cutting with a focused ion beam (FIB). Lamellar reaction intermediates were found occluded in the fullerene particles. In contrast to carbon fullerenes, layered metal chalcogenides prefer the formation of planar, plate-like structures where the dangling bonds at the edges are stabilized by excess S atoms. The effects of the reaction and annealing temperatures o…
ChemInform Abstract: The Valence States of Nickel, Tin, and Sulfur in the Ternary Chalcogenide Ni3Sn2S2 - XPS, 61Ni and 119Sn Moessbauer Investigatio…
2010
Effect of Isovalent Substitution on the Thermoelectric Properties of the Cu2ZnGeSe4–xSx Series of Solid Solutions
2013
Knowledge of structure–property relationships is a key feature of materials design. The control of thermal transport has proven to be crucial for the optimization of thermoelectric materials. We report the synthesis, chemical characterization, thermoelectric transport properties, and thermal transport calculations of the complete solid solution series Cu_2ZnGeSe_(4–x)S_x (x = 0–4). Throughout the substitution series a continuous Vegard-like behavior of the lattice parameters, bond distances, optical band gap energies, and sound velocities are found, which enables the tuning of these properties adjusting the initial composition. Refinements of the special chalcogen positions revealed a chang…
Photoluminescence Enhancement by Band Alignment Engineering in MoS 2 /FePS 3 van der Waals Heterostructures
2022
Single-layer semiconducting transition metal dichalcogenides (2H-TMDs) display robust excitonic photoluminescence emission, which can be improved by controlled changes to the environment and the chemical potential of the material. However, a drastic emission quench has been generally observed when TMDs are stacked in van der Waals heterostructures, which often favor the nonradiative recombination of photocarriers. Herein, we achieve an enhancement of the photoluminescence of single-layer MoS2 on top of van der Waals FePS3. The optimal energy band alignment of this heterostructure preserves light emission of MoS2 against nonradiative interlayer recombination processes and favors the charge t…
Structural-relaxation phenomena in As–S glasses as probed by combined PAL/DBAR technique
2015
Abstract Experimental techniques exploring phenomena of positron–electron interaction, namely the positron annihilation lifetime spectroscopy and Doppler broadening of annihilation radiation, are shown to be very informative tools to study radiation- and thermally-induced phenomena in chalcogenide glasses of binary As–S system. Time-dependent processes of free-volume voids agglomeration (expansion), fragmentation (refining) and disappearing (contraction) are identified as main stages of physical aging in S-rich glasses, while a competitive channel of coordination topological defects formation associated with void charging becomes significant in a vicinity of near-stoichiometric glass compos…
<title>Photoinduced AsSeS thin film phase plates as adaptive optics mirrors for eye aberration correction</title>
2008
Amorphous chalcogenide thin films are excellent materials for holographic recordings. AsSeS thin film coating is a useful optical material for it's thickness to be easily corrected with the use of exposure to light and consecutive chemical etching. Following properties allow to treat the surface of AsSeS chalcogenide films and to use them in adaptive optics systems for correction of the optical wavefront. Hereby, we characterize AsSeS film properties to be used for correction of optical aberrations of the human eye. The thickness of the film is characterized with the method of spectrodensitometry and the surface profile depth with a Hartman- Shack waveform analyzator.
Mid-infrared strong spectral broadening in microstructured tapered chalcogenide AsSe fiber
2012
We report on the generation of a supercontinuum in a chalcogenide microstructured tapered fiber. The suspended core diameter of the fiber is reduced from 5.5 μm to 0.8 μm in the waist of the tapered region. The zero dispersion wavelength is below 2 μm in the tapered region. To pump the fiber, we use a modelocked laser of 4 ps, with a central wavelength of 1960 nm. With only 150 W peak power in the fiber a supercontinuum is generated from 1300 to 2600 nm taking the supercontinuum wavelength edge at -30 dB from the continuum.
High third and second order non linearities of chalcogenide glasses and fibers for compact infrared non linear devices.
2008
Due to their intrinsic nature, chalcogenide glasses present attractive nonlinearities from third and second order, with values reaching between 10 and 1000 times those of silica. We present a study of their properties and their shaping with the purpose to reach efficient devices in the near-mid infrared.
Mid-infrared supercontinuum generation in suspended-core chalcogenide and tellurite optical fibers
2013
Summary form only given. The generation of optical supercontinua in the mid-infrared region and especially their expansion beyond the intrinsic limit dictated by fused silica is currently a subject of high interest. Tellurite and chalcogenide glasses have serious advantages because of their wide transmittance window which can reach more than 10 μm while the Kerr nonlinearity can be 500 times stronger than fused silica. These different features make them serious candidates for broad mid-infrared supercontinuum generation. For example, supercontinuum as broad as 4000-nm bandwidth has been generated in a sub-cm long Tellurite microstructured fiber by Domachuk et al. in ref. [1] by means of a f…
Demonstration of a reef knot microfiber resonator.
2009
We propose a new way to realize a microfiber optical resonator by implementing the topology of a reef knot using two microfibers. We describe how this structure, which includes 4 ports and can serve as an add-drop filter, can be fabricated. Resonances in an all-silica reef knot are measured and good fits are obtained from a simple resonator model. We also show the feasibility of assembling a hybrid silica-chalcogenide reef knot structure.