Search results for "Charge Density"
showing 10 items of 206 documents
The nanoscale structure of the Pt-water double layer under bias revealed
2019
The nanoscopic mass and charge distribution within the double layer at electrified interfaces plays a key role in electrochemical phenomena of huge technological relevance for energy production and conversion. However, in spite of its importance, the nanoscopic structure of the double layer and its response to an applied potential is still almost entirely unknown, even for Pt-water, the most fundamental electrochemical interface. Using a general ab initio methodology which advances previous models towards a dynamic and more realistic description of an electrode/electrolyte interface, we simulate for the first time the nanoscopic structure of the Pt-water double layer and its response to an …
Calculation of the electrostatic field in a dielectric-loaded waveguide due to an arbitrary charge distribution on the dielectric layer
2016
The goal of this paper is to study the electrostatic field due to an arbitrary charge distribution on a dielectric layer in a dielectric-loaded rectangular waveguide. In order to obtain this electrostatic field, the potential due to a point charge on the dielectric layer is solved in advance. The high computational complexity of this problem requires the use of different numerical integration techniques (e.g., Filon, Gauss-Kronrod, Lobatto, …) and interpolation methods. Using the principle of superposition, the potential due to an arbitrary charge distribution on a dielectric layer is obtained by adding the individual contribution of each point charge. Finally, a numerical differentiation o…
Measuring the surface thickness of the weak charge density of nuclei
2020
The present PREX-II and CREX experiments are measuring the rms radius of the weak charge density of $^{208}$Pb and $^{48}$Ca. We discuss the feasibility of a new parity violating electron scattering experiment to measure the surface thickness of the weak charge density of a heavy nucleus. Once PREX-II and CREX have constrained weak radii, an additional parity violating measurement at a momentum transfer near 0.76 fm$^{-1}$ for $^{208}$Pb or 1.28 fm$^{-1}$ for $^{48}$Ca can determine the surface thickness.
ChemInform Abstract: Methylium Ions with OPV Chains - New NIR Dyes.
2010
Carbinols, which contain three OPV chains, were generated in convergent syntheses. The extension of the conjugation leads to a bathochromic effect that shifts the absorption from the UV into the visible region. The carbinol series has a convergence limit of the absorption at λmax = 415 nm. The corresponding carbenium ions exhibit a stronger bathochromic shift with the increasing number of repeating units in each chain. Thus, NIR dyes were obtained which show a convergence limit at λmax = 879 nm. The charge distribution in the ground state of the carbocations is discussed on the basis of 13C NMR spectroscopic data.
Triboelectrification of nanocomposites using identical polymer matrixes with different concentrations of nanoparticle fillers
2021
In this study, we investigate triboelectrification in polymer-based nanocomposites using identical polymer matrixes containing different concentrations of nanoparticles (NPs). The triboelectric surface charge density on polymer layers increased as the difference in nanoparticle filler concentration between the two triboelectric layers escalated, despite the fact that the polymer matrix was the same in both layers. This effect was observed in tests of various polymer types and filler NPs. Our mechanical experiments and finite element analysis simulations confirmed that polymeric triboelectrification is related to the surface viscoelastic deformation that occurs during mechanical contact and …
Electrophoresis of colloidal dispersions in the low-salt regime
2007
We study the electrophoretic mobility of spherical charged colloids in a low-salt suspension as a function of the colloidal concentration. Using an effective particle charge and a reduced screening parameter, we map the data for systems with different particle charges and sizes, including numerical simulation data with full electrostatics and hydrodynamics and experimental data for latex dispersions, on a single master curve. We observe two different volume fraction-dependent regimes for the electrophoretic mobility that can be explained in terms of the static properties of the ionic double layer.
Calcium binding and ionic conduction in single conical nanopores with polyacid chains: model and experiments.
2012
Calcium binding to fixed charge groups confined over nanoscale regions is relevant to ion equilibrium and transport in the ionic channels of the cell membranes and artificial nanopores. We present an experimental and theoretical description of the dissociation equilibrium and transport in a single conical nanopore functionalized with pH-sensitive carboxylic acid groups and phosphonic acid chains. Different phenomena are simultaneously present in this basic problem of physical and biophysical chemistry: (i) the divalent nature of the phosphonic acid groups fixed to the pore walls and the influence of the pH and calcium on the reversible dissociation equilibrium of these groups; (ii) the asym…
Correction to “Self-Consistent Charge Density-Functional Tight-Binding Parameterization for Pt–Ru Alloys”
2018
Spin, moments, and mean square nuclear charge radius ofSr77
1992
The neutron deficient $^{77}\mathrm{Sr}$ nucleus was studied by fast ion beam collinear laser spectroscopy with a detection scheme based on optical pumping, state selective neutralization, and atom counting. From the measured hyperfine splitting and isotope shift of the Sr II transition 5s $^{2}$${\mathit{S}}_{1/2}$\ensuremath{\rightarrow}5p $^{2}$${\mathit{P}}_{3/2}$ the nuclear spin I=5/2, the nuclear moments \ensuremath{\mu}=-0.348(4)${\mathrm{\ensuremath{\mu}}}_{\mathit{N}}$, ${\mathit{Q}}_{\mathit{s}}$=1.40(11) b, and the change in mean square charge radius \ensuremath{\delta}〈${\mathit{r}}^{2}$${\mathrm{〉}}^{88,77}$=0.248(12) ${\mathrm{fm}}^{2}$ were deduced. These ground-state proper…
Electrostatic interaction of a solute with a continuum. Improved description of the cavity and of the surface cavity bound charge distribution.
1987
Algorithms for a finer description of cavities in continuous media and for a more efficient selection of sampling points on the cavity surface are described. Applications to the evaluation of solute surface and volume and to the calculation of the solute-solvent electrostatic interaction energy, as well as of the cavitation energy are shown as examples.