Search results for "Chemical Engineering"
showing 10 items of 5892 documents
Specifications for carbonate content quantification in recent marine sediments using Rock-Eval pyrolysis
2019
11 pages; International audience; The amount of CaCO3 in sediments and/or sedimentary rocks is usually measured by calcimetry while the nature of the carbonates is determined by X-ray diffraction. Recently, a carbonate recognition method based on the results of Rock-Eval pyrolysis was proposed in 2014 by Pillot et al. [1]. Rock-Eval pyrolysis is also widely used for the characterization of recent sediments. However, later in 2015 Baudin et al. [2] noticed that some of the characteristics of recent sediments tended to produce different results from those of more classical Rock-Eval analyses, causing bias in interpretations.In this study, the thermal stability of fossil and recent marine carb…
Modeling the natural gas supply chain for sustainable growth policy
2020
Abstract Natural gas has been used globally as a transitional fuel for supporting a green-energy-supply strategy, which has been questioned for the intermittence and lack of reliability of renewables. This paper proposes a System Dynamics model for assessing alternative security of supply policy along the natural gas value chain. The model incorporates demand, transport, production and reserves of natural gas variables according to a systemic perspective. It also includes a module for evaluating the effect of natural gas price on the demand and supply levels, respectively. Alternative supply policies are evaluated under different scenarios. The chosen case-study focuses on the Colombian nat…
Energy and economic analysis of air-to-air heat pumps as an alternative to domestic gas boiler heating systems in the South of Italy
2019
Abstract According to the electricity tariff recently issued by the Italian government for the domestic heating systems fed with heat pumps (HP), an energy and economic analysis was carried out with the aim of investigating the effectiveness of the air-to-air heat pump systems (HPS) as an alternative to the traditional heating using domestic gas boilers systems (GBS). For the purpose of this study, the apartments of three residential buildings were examined. The hourly heating loads were calculated with the ASHRAE radiant time series and the coefficient of performance (COP) of the HPs was evaluated for each operating condition. The costs for the heating system installation and electricity a…
Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries
2018
This study investigates the effect of high-temperature pyrolysis and post-treatment processes on spruce and oak charcoal yields and CO2 reactivity in a slow pyrolysis reactor. Post-treatment processes such as co-pyrolysis of biomass and recirculated tar mixture with that to the distillation of the charcoal-tar blend gave similar increase in charcoal yields. From a technological standpoint, co-pyrolysis of charcoal and tar mixture decreased the CO2 reactivity of the charcoal approaching that of fossil-based coke. This emphasize the importance of tar addition and high temperature treatment on charcoal properties. Moreover, the findings of this work show the potential use of the tar organic fr…
BIOCLEANING
2017
Cleaning is one of the first and most important steps in conservative restora- tion intervention, as it removes the unwanted layers of dirt and deposit from the surface of an artefact. It must be done selectively, however, by adapting the cleaning operation to the different zones and removing successive layers of deposit without acting directly on the original materials of the surface. Generally, cleaning protocols are based on chemical or physical procedures with potential negative effects for restorers’ health and/or for the materials constituting the artworks. As an alternative, solvent gels, rigid gels and resin soaps can be used for selective cleaning. In recent decades, biological cle…
Partial Stabilization of Input-Output Contact Systems on a Legendre Submanifold
2017
This technical note addresses the structure preserving stabilization by output feedback of conservative input-output contact systems, a class of input-output Hamiltonian systems defined on contact manifolds. In the first instance, achievable contact forms in closed-loop and the associated Legendre submanifolds are analysed. In the second instance the stability properties of a hyperbolic equilibrium point of a strict contact vector field are analysed and it is shown that the stable and unstable manifolds are Legendre submanifolds. In the third instance the consequences for the design of stable structure preserving output feedback are derived: in closed-loop one may achieve stability only rel…
Minimal-model for robust control design of large-scale hydraulic machines
2018
Hydraulic machines are in use where the large forces, at relatively low velocities, are required by varying loads and often hazardous and hard-to-reach environments, like e.g. offshore, mining, forestry, cargo logistics, and others industries. Cranes and excavators equipped with multiple hydraulic cylinders are typical examples for that. For design of the robust feedback controls of hydraulic cylinders, already installed into large-scale machines, there is a general lack of reliable dynamic models. Also the suitable and feasible identification techniques, especially in frequency domain, yield limited. This paper proposes a minimal-modeling approach for determining the most relevant open-lo…
Guidelines to Select Between Self-Contained Electro-Hydraulic and Electro-Mechanical Cylinder
2020
This research paper presents guidelines on how to select between self-contained electro-hydraulic and electromechanical cylinders. An example based on the motion control of a single-boom crane is studied. The sizing process of the different off-the-shelf components is analyzed in terms of design impact when replacing a traditional valve-controlled hydraulic cylinder. The self-contained electro-hydraulic solution is the best choice when a risk for high impact forces is present, when the required output power level lies continuously above 2 kW, or when installation space, weight, and cost are critical design objectives. However, the electro-mechanical solution is expected to show more control…
Identification and control design for path tracking of hydraulic loader crane
2017
The controlled operation of hydraulic machines with multiple degrees of freedom is challenging due to complex nonlinear dynamics of cylinder actuators, in addition to multibody dynamics like in the case of hydraulic manipulators. This paper addresses the system identification and control design for path tracking of a standard hydraulic loader crane. The kinematics of the crane is solved for operation in the vertical plane and generation of trajectories for the tool tip to be followed. A frequency response measurements and analysis have been done for dynamics modeling of both hydraulic cylinders actuating main boom and jib. The static dead-zone type input non-linearity has been identified an…
Influence of residual stress, surface roughness and crystallographic texture induced by machining on the corrosion behaviour of copper in salt-fog at…
2012
International audience; The influence of quadratic stress, crystallographic texture, lubrication and surface roughness generated by superfinish turning on the corrosion behaviour of pure copper was quantified in salt-fog atmosphere. This was done using statistical analysis (Pearson's correlation matrix). Three compounds were found after corrosion tests: atacamite/paratacamite and a black layer (mixture of the lubricant and the salt atmosphere). Surface characteristics were classified according to their decreasing influence on the formation of atacamite/paratacamite as follows: surface roughness and quadratic stress. Lubrication and the crystallographic texture have the lowest influence on c…