Search results for "Chemical engineering"
showing 10 items of 5892 documents
Analytical strategies to determine quinolone residues in food and the environment
2007
23 páginas, 5 figuras, 5 tablas.
Observation of interaction forces by investigation of the influence of eluent additives on the retention behavior of aqueous nanoparticle dispersions…
2020
The investigation and subsequent understanding of the interactions of nanomaterials with components of their surrounding media is important to be able to evaluate both potential use cases as well as potential risks for human health and for the environment. To investigate such interactions, asymmetrical flow field-flow fractionation (AF4) is an interesting analytical tool. This statement grounds on the fact that interactions of the analyte with the membrane and with components of the eluent are crucial for the retention behavior of the analyte within the field-flow fractionation (FFF) channel. Therefore, the investigation of the retention behavior provides an insight in the nature of the int…
Determination of biochemical parameters in human serum by near-infrared spectroscopy
2014
NIR offers multiple advantages for serum analysis, permitting a fast and direct determination of several parameters simultaneously, with low sample handling and without the need for reagents during the measurement step. The aim of this paper was to provide an evaluation of this technique in a real world scale, for the simultaneous determination of several parameters and based on a considerable number of samples. Direct near infrared (NIR) absorbance measurements were used to determine the concentration of clinical parameters in human serum that are required in routine biochemical tests. Total protein, albumin, total cholesterol, high-density lipoprotein (HDL cholesterol), low-density lipopr…
New insights in the formation of silanol defects in silicalite-1 by water intrusion under high pressure.
2010
International audience; The "water-silicalite-1" system is known to act as a molecular spring. The successive intrusion-extrusion cycles of liquid water in small crystallites (6 × 3 × 0.5 μm(3)) of hydrophobic silicalite-1 were studied by volumetric and calorimetric techniques. The experiments displayed a decrease of the intrusion pressure between the first intrusion-extrusion cycle and the consecutive ones, whereas the extrusion pressures remained unchanged. However, neither XRD studies nor SEM observations revealed any structural and morphological modifications of silicalite-1 at the long-range order. Such a shift in the value of the intrusion pressure after the first water intrusion-extr…
Graphene and ionic liquids new gel paste electrodes for caffeic acid quantification
2015
Abstract Graphene/ionic liquids nanocomposite gels were synthesized by an electrochemical etching approach and fully characterized under a morphological and structural point of view. For this purpose, several analytical techniques were applied, as HR-TEM/EDX (High Resolution-Transmission Electron Microscopy/Energy Dispersive X-Ray Analysis); FE-SEM/EDX (Field Emission-Scanning Electron Microscopy/Energy Dispersive X-Ray Analysis); XPS (X-Ray Photoelectron Spectroscopy); FT-IR (Fourier Transform-Infrared Spectroscopy) and electrochemical techniques. After the characterization study, nanocomposite-gel paste electrodes were assembled, exhibiting a selective and specific detection toward the ca…
Understanding the role of Ti-rich domains in the stabilization of gold nanoparticles on mesoporous silica-based catalysts
2018
3 Tablae, 14 Figures.-- Supplementary material.-- © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Determination of the crystallinity of TiO2 photocatalysts
2018
Abstract This study reports a new simple method to determine the crystallinity of anatase and rutile TiO2 photocatalysts. The crystallinity degree of various anatase and rutile samples was estimated by XRD analysis from the ratio among the full width at half maximum intensities of the main diffraction peaks of anatase or rutile and the (111) peak of CaF2 as internal standard. The photocatalytic activity of selected powders was tested employing the photodegradation of 4-nitrophenol in aqueous solution as probe reaction. The results showed that the photoactivity of the investigated samples increased with increasing crystallinity and crystallite size.
Photocatalytic activity of nanocrystalline TiO2 (brookite, rutile and brookite-based) powders prepared by thermohydrolysis of TiCl4 in aqueous chlori…
2008
Abstract Nanocrystalline TiO2 powders were synthesized by thermohydrolysis of TiCl4 in HCl or NaCl aqueous solutions. Rutile, mixtures of brookite and rutile or mixtures of anatase, brookite and rutile were obtained depending on the acidity of the medium. Crystalline phases and composition of the mixtures were identified by using XRD analysis. Pure brookite nanoparticles, separated from the mixtures of brookite and rutile by simple peptization with water, were stable against transformation to rutile up to 750 °C. The prepared TiO2 powders were characterized by thermal analysis, diffuse reflectance spectroscopy and BET surface area determinations. The band gap of bulky brookite was estimated…
Photoactivity of Nanostructured TiO2 Catalysts in Aqueous System and their Surface Acid-Base, Bulk and Textural Properties
2007
This work reports on the characterisation and determintion of the photocatalytic activity of some TiO2 catalysts prepared using TiCl4 as precursor. The samples, consisting of suspensions, dispersions or powders of nanonstructured anatase or rutile phases, were obtained in very mild conditions, i.e., by boiling the solution obtained after hydrolysis of TiCl4 at atmospheric pressure: it is worth noting that no calcination was necessary to obtain photoactive phases. The samples were characterised by X-ray diffraction (XRD), determination of the BET specific surface area (SSA), scanning electron microscopy (SEM) observations and diffuse reflectance spectroscopy (DRS). FT-IR spectroscopy was use…
Visible light photocatalytic activity of macro-mesoporous TiO2-CeO2inverse opals
2018
Macro-mesoporous TiO2 inverse opal materials were synthesized and they were tested as photocatalysts under visible light irradiation. The influence of cerium oxide addition towards the Rhodamine B (RhB) photodegradation activity was evaluated. Structural, textural, spectral and surface properties of the TiO2-CeO2 inverse opal nanocomposites were studied by XRD, XPS, SEM, TEM, N2 adsorption-desorption, Diffuse Reflectance UV–vis and Photoluminescence spectroscopies. Compared to commercial TiO2 anatase, the macro-mesoporous TiO2 inverse opal exhibited six times higher kinetic rate constant in the RhB degradation under visible light irradiation. The good photocatalytic activity was related to …