Search results for "Chemical separation"

Rapid chemical separation procedures

1976

Fast, discontinuous separation procedures are described for zirconium, niobium, technetium and antimony from fission products. Other rapid separation methods from aqueous solutions are summarized. The combination of a gas jet recoil transport system with a continuous solvent extraction technique and with a thermochromatographic separation method is presented. The application of such procedures to the investigation of new and already known short-lived nuclides is illustrated by some examples.

The Use of the Macrocyclic Chelator DOTA in Radiochemical Separations

2019

Der Zerfall des94Sr

1973

The nuclide94Sr was isolated by chemical separation methods after thermal neutron induced fission of235U. Its decay properties were investigated employing semi-conductor spectrometers and coincidence techniques. A half-life of 74.1±0.3 sec was found. Besides the 1428.3 keV γ-ray we found 4 new γ-rays which could be placed in a decay scheme comprising three excited states of94Y. The 1+ states in theuu-nuclides90,92,94Y and88,90,92Rb are compared.

The decay of 31 sec98Zr, 2.9 sec98Nb and 51 min98Nb

1976

TheΒ- andγ-radiations of98Zr and98m, g Nb have been investigated employing scintillation and semiconductor spectrometers and coincidence techniques. Sources of98Nb were produced by the98Mo(n, p)98Nb reaction, sources of98Zr by fission of235U with thermal neutrons applying chemical separations. For98Zr, a half-life of 30.7±0.4 sec and aQ β-value of 2.3±0.2 MeV were obtained, for the98Nb isomers, half-lives of 2.86±0.06 sec and 51.3±0.4 min, andQ β-values of 4.8±0.2 MeV and 4.5±0.2 MeV, respectively. Noγ-rays were observed in the decay of98Zr. The decay of 2.9 sec98Nb was found to involve 11γ-ray transitions. In the decay of 51 min98Nb, 54γ-transitions were detected. Spin and parity of 1+ and…

Chemical separation and MC-ICPMS analysis of U, Th, Pa and Ra isotope ratios of carbonates

2018

Diagenetic alteration of fossil reef corals may have severe effects on the reliability of 230Th/U-ages. The widely applied criteria introduced to test for the reliability of coral 230Th/U-ages are often not sufficient to identify all altered ages. The combination of 230Th/U- with 231Pa/U-dating has been suggested as a promising method to identify altered ages. Furthermore, 226Ra/230Th ratios can provide information about the diagenetic history during the last 10 000 years. Here we present a method to chemically separate U, Th, Pa and Ra from the same aliquot of a carbonate sample. The isotope ratios of our mixed U–Th–Pa–Ra spike are calibrated using a secular equilibrium material treated in…