Search results for "Chlorin"
showing 10 items of 374 documents
Luminescence properties of chlorine molecules in glassy SiO 2 and optical fibre waveguides
2017
The support from Latvian Research Program IMIS 2, project “Photonics and materials for photonics” is acknowledged. K.K. was partially supported by the Collaborative Research Project of Materials and Structures Laboratory, Tokyo Institute of Technology. The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.
Validation of a novel Multi-Gas sensor for volcanic HCl alongside H2S and SO2 at Mt. Etna
2017
Erratum to: Bull Volcanol (2017) 79: 36DOI 10.1007/s00445-017-1114-zDuring the steps of corrections, the publisher inadvertently changed the author affiliations so that they were no longer correct. The correct information is given below. The publisher regrets this mistake.; International audience; Volcanic gas emission measurements inform predictions of hazard and atmospheric impacts. For these measurements, Multi-Gas sensors provide low-cost in situ monitoring of gas composition but to date have lacked the ability to detect halogens. Here, two Multi-Gas instruments characterized passive outgassing emissions from Mt. Etna’s (Italy) three summit craters, Voragine (VOR), North-east Crater (NE…
Controlled treatment of a high velocity anisotropic aquifer model contaminated by hexachlorocyclohexanes
2020
International audience; Xanthan gels were assessed to control the reductive dechlorination of hexachlorocyclohexanes (HCHs) and trichlorobenzenes (TCBs) in a strong permeability contrast and high velocity sedimentary aquifer. An alkaline degradation was selected because of the low cost of NaOH and Ca(OH)2. The rheology of alkaline xanthan gels and their ability to deliver alkalinity homogeneously, while maintaining the latter, were studied. Whereas the xanthan gels behaved like non-Newtonian shear-thinning fluids, alkalinity and Ca(OH)2 microparticles had detrimental effects, yet, the latter decreased with the shear-rate. Breakthrough curves for the NaOH and Ca(OH)2 in xanthan solutions, ca…
Chlorine Partitioning Between a Basaltic Melt and H2O-CO2 Fluids at Mount Etna
2009
Partitioning experiments between a basaltic melt from Mt. Etna and a low-density hydrous fluid or vapor containing H(2)O or H(2)O-CO(2) were performed at 1200-1260 degrees C, at pressures between 1 and 200 MPa, either near the nickel-nickel oxide (NNO) buffer or at two log units above it (NNO + 2), and with different chloride concentrations. Most of the experiments were done at chloride-brine-undersaturated conditions, although at the highest Cl concentrations explored brine saturation might have been reached. The average partition coefficients (D(Cl)(fluid/melt)) over the range of Cl concentrations were derived on a weight basis by plotting the calculated concentrations of Cl in the fluid …
Review of the African genera Arantia Stål and Goetia Karsch (Orthoptera: Tettigoniidae: Phaneropterinae)
2017
The genus Arantia is reviewed, the distribution and distinguishing characters given. The three species of Goetia are assigned as subgenus to Arantia. Arantia gestri Griffini is transferred to this new subgenus and synonymized with G. dimidiata Bolívar. Other species synonymized are: A. accrana Karsch with A. rectifolia Brunner von Wattenwyl; A. gabunensis Brunner von Wattenwyl with A. regina Karsch; A. mammisignum Karsch and A. tigrina Bolívar with A. excelsior Karsch; A. ugandana Rehn is synonymized with A. fasciata (Walker). 6 species from Tropical Africa are newly described: A. (Arantia) quinquemaculata n. sp., A. (Arantia) ivoriana n. sp., A. (Euarantia) tanzanica n. sp., A. (Euarantia)…
Survey on the presence of non-dioxine-like PCBs (NDL-PCBs) in loggerhead turtles (Caretta caretta) stranded in south Mediterranean coasts (Sicily, So…
2017
A total of 71 loggerhead turtles (Caretta caretta) stranded along the coasts of Sicily (Southern Italy) were examined for non-dioxine like polychlorinated biphenyl (NDL-PCB) levels in muscle and adipose tissue by a gas chromatography-mass spectrometry/mass spectrometry (GC-MS/MS) method. The results revealed 6 high-indicator congener (∑6 PCBIND ) levels in 45% of the loggerhead turtles examined, with mean values of 980.39 ± 2508.39 ng/g wet weight in adipose tissue and 102.53 ± 238.58 ng/g wet weight in muscle tissue. The hexachloro and heptachloro PCB congeners were the most abundant in both the sample types. The highest NDL-PCB levels were reached in an adipose tissue sample of a loggerhe…
Enrichment, isolation and biodegradation potential of psychrotolerant polychlorinated-biphenyl degrading bacteria from the Kongsfjorden (Svalbard Isl…
2016
Persistent organic pollutants (POPs), such as polychlorinated biphenyls (PCBs), have been detected in abiotic Arctic matrices: surface sediments and seawater from coastal areas in the Kongsfjorden were collected and analyzed. Levels of PCBs varied depending on the sampling site. Total PCB concentrations were between 11.63 (site C2W) and 27.69 pg l-1 (site AW). These levels were comparable to those reported previously in lake sediments from the northern Svalbard. The occurrence and biodegradation potential of cold-adapted PCB-oxidizing bacteria in seawater and sediment along the fjord was also evaluated. After enrichment with biphenyl, 246 isolates were obtained with 45 of them that were abl…
Compendium of TCDD-mediated transcriptomic response datasets in mammalian model systems.
2017
Background 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) is the most potent congener of the dioxin class of environmental contaminants. Exposure to TCDD causes a wide range of toxic outcomes, ranging from chloracne to acute lethality. The severity of toxicity is highly dependent on the aryl hydrocarbon receptor (AHR). Binding of TCDD to the AHR leads to changes in transcription of numerous genes. Studies evaluating the transcriptional changes brought on by TCDD may provide valuable insight into the role of the AHR in human health and disease. We therefore compiled a collection of transcriptomic datasets that can be used to aid the scientific community in better understanding the transcriptiona…
Chlorinative stress in age-related diseases: A literature review
2017
Abstract Aging is an agglomerate of biological long-lasting processes that result being inevitable. Main actors in this scenario are both long-term inflammation and oxidative stress. It has been proved that oxidative stress induce alteration in proteins and this fact itself is critically important in the pathophysiological mechanisms leading to diseases typical of aging. Among reactive species, chlorine ones such as hypochlorous acid (HOCl) are cytotoxic oxidants produced by activated neutrophils during chronic inflammation processes. HOCl can also cause damages by reacting with biological molecules. HOCl is generated by myeloperoxidase (MPO) and augmented serum levels of MPO have been desc…
Formation of 2,4,6-trichlorophenol and 2,4,6-trichloroanisole during treatment and distribution of drinking water
1995
Biomethylation of 2,4,6-trichlorophenol to the potent off-flavour compound 2,4,6-trichloroanisole has previously been found to cause taste and odour problems in drinking water. In the present study, both compounds were detected in seemingly unpolluted surface waters. However, the highest concentrations of 2,4,6-trichloroanisole in tap water were caused by the formation of 2,4,6-trichlorophenol during chlorine disinfection of drinking water and subsequent methylation of this compound in the distribution system. Analysis of samples from several sites in the investigated distribution systems showed that there was a substantial spatial and temporal variation of the concentration of both 2,4,6-t…