Search results for "Chlorin"

COMPOSITION OF REFUSE DERIVED FUELS IN LATVIA AND ESTONIA IN COMPARISION WITH WORLDWIDE AVERAGE VALUES

2019

Information about composition of RDF worldwide was collected using literature analysis. RDF samples produced in Latvia and Estonia were collected, those fractional and elemental composition analyzed using standard methods. Comparing obtained results with worldwide data we have found that the quality of local RDFs in general is higher than typical values, while elevated content of chlorine must be mentioned as a problem. Results also show that majority of chlorine in studied samples exists in organic form. Recommendations to overcome this problem have been developed. 

Near-infrared emissive bacteriochlorin-diketopyrrolopyrrole triads: Synthesis and photophysical properties

2019

International audience; The synthesis of unprecedented energy transfer triads containing a near-infrared (NIR) emissive bacteriochlorin subunit and two diketopyrrolopyrrole (DPP) moieties linked to each other via ethynyl or zero-carbon spacers is presented. Their optical and fluorescence properties were determined in CHCl3 and toluene. These photophysical measurements highlight the ability of DPP scaffold to act as an effective energy donor, which once excited in the range 450-550 nm resulting nearly exclusively NIR emission of hydroporphyrin (ETE > 96%). Since DPP dyes are valuable structurally tunable fluorophores that may be used in the construction of high-performance multicomponent pho…

Quasi-digital conversion for resistive devices: application in GMR-based IC current sensors

2013

Resistive devices, including sensors, are used in a huge range of applications within different scenarios. When a complete system is considered, a quasi-digital output is often recommendable. If the conversion is operated at device level, some problems such as noise disturbs, insertion losses and so on, can be reduced. In this work, we describe a resistance-tofrequency (R-f) converter with a suggested application in low current monitoring by means of GiantMagnetoResistance (GMR) sensors. Specific devices have been designed and microfabricated. The system has been tested by means of discrete components with a PCB. The complete microsystem monolithic integration in a standard CMOS technology …

Antiviral capacity of sanitizers against infectious viruses in process water from the produce industry under batch and continuous conditions

2023

The presence of human enteric viruses in produce has extensively been reported. However, the significance of the quality of process water (PW) used by the produce industry and the viral inactivation capacity of water disinfection agents used to maintain the microbiological quality of PW has received limited attention. This study evaluates the antiviral disinfection efficacy of chlorine, chlorine dioxide (ClO2) and peracetic acid (PAA) at recommended operational limits in PW using hepatitis A virus (HAV), the cultivable norovirus surrogate, murine norovirus (MNV-1), and MS2 coliphages. Defined commodity representative crops (baby leaves, bell peppers, and the vegetable mix of tomatoes, cucum…

The occurrence of Dechlorane Plus and related norbornene-based flame retardants in Baltic wild salmon (Salmo salar)

2015

Twenty five Baltic wild salmon (Salmo salar) specimens were analysed for the content of Dechlorane-related compounds (DRCs). Out of the ten analysed DRCs, seven compounds were detected in the muscle tissues of salmon, including Dechlorane (Dec) 602, Dec 603, syn- and anti-stereoisomers of Dechlorane Plus (DP), Dechlorane Plus monoadduct (1,3-DPMA), hexachlorocyclopentadienyl-dibromocyclooctane (DBHCTD), and Mirex. The concentrations of Dec 604 and two DP dechlorinated compounds - decachloropentacyclooctadecadiene (Cl10DP) and undecachloropentacyclooctadecadiene (Cl11DP) - were below the limit of detection in all samples. The aggregated concentrations of DRCs (ΣDRC) were in the range of 551-…

Use of Mussels (Anodonta piscinalis) in the Monitoring of Organic Chlorine Compounds

1988

Synthesis and structure verification of two previously uncharacterized pentachlorobiphenyls: PCB 108 and PCB 127

1992

Abstract The synthesis and structure verification of two previously uncharacterized polychlorinated biphenyl (PCB) congeners mono- ortho -substituted 2,3,3′,4,5′-pentachlorobiphenyl (PCB 108) and non- ortho -substituted 3,3′,4,5,5′-pentachlorobiphenyl (PCB 127) is described. The synthesis was done by the method of aromatic arylation in the presence of isopentyl nitrite. The purification and separation of the compounds was done by flash-chromatography on Al2O3- and charcoal columns. The structures were verified by 1H NMR, 13C NMR, IR and mass spectroscopy.

Organic chlorine compounds in lake sediments. IV. Dioxins, furans and related chloroaromatic compounds

1990

Abstract Polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), polychloronaphthalenes (PCNs) and coplanar PCBs were measured in surface sediments from 18 lake areas in Central Finland. Toxic 2, 3, 7, 8-substituted PCDD and PCDF congeners occurred at low levels (

Free and bound chlorophenols in kraft pulp bleaching effluents

1992

Abstract Free (F; hexane extractable) and chemically bound (B; alkali extractable) chlorophenols, catechols and guaiacols were measured from effluents of the C and E stages of chlorobleaching of kraft softwood pulp. Ratio B/F was in moste cases nearly one, but for tetrachloroguaiacol B/F was 20 in C and 2.70 in E stage. Organically bound chlorine (OCl) in chlorophenols was less than one percent of the total AOX (Adsorbable Organic Halogen) emitted.

The use of blue tit eggs as a biomonitoring tool for organohalogenated pollutants in the European environment

2010

In the present study, large scale geographical variation in the occurrence of organohalogenated pollutants (OHPs) was investigated throughout Europe using eggs of a terrestrial resident passerine species, the blue tit (Cyanistes caeruleus). Blue tit eggs from 10 sampling locations, involving suburban, rural and remote areas, in 7 European countries were collected and analysed. Sum polychlorinated biphenyl (PCB) levels ranged from 150 ng/g lipid weight (lw) to 2003 ng/g lw. Sum polybrominated diphenyl ethers (PBDEs) ranged from 3.95 ng/g lw to 114 ng/g lw. As expected, PCB and PBDE concentrations were significantly higher in the sampled suburban locations compared to the rural and remote loc…