Search results for "Chloromethane"

showing 10 items of 692 documents

CCDC 250842: Experimental Crystal Structure Determination

2005

Related Article: J.-C.Hierso, A.Fihri, V.V.Ivanov, B.Hanquet, N.Pirio, B.Donnadieu, B.Rebiere, R.Amardeil, P.Meunier|2004|J.Am.Chem.Soc.|126|11077|doi:10.1021/ja048907a

(mu~2~-11'-Di-t-butyl-33'44'-tetrakis(diphenylphosphino)ferrocene-PP'P''P''')-bis(dichloro-nickel) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 256921: Experimental Crystal Structure Determination

2005

Related Article: L.Bareille, P.Le Gendre, P.Richard, C.Moise|2005|Eur.J.Inorg.Chem.||2451|doi:10.1002/ejic.200401028

(mu~2~-eta^5^-(2-(Diphenylphosphino)ethyl)cyclopentadienyl-P)-bis(benzoato-O)-dichloro-(eta^5^-cyclopentadienyl)-(eta^6^-p-cymene)-ruthenium-titanium benzoic acid dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 248544: Experimental Crystal Structure Determination

2004

Related Article: C.Boskovic, A.Sieber, G.Chaboussant, H.U.Gudel, J.Ensling, W.Wernsdorfer, A.Neels, G.Labat, H.Stoeckli-Evans, S.Janssen|2004|Inorg.Chem.|43|5053|doi:10.1021/ic049600f

(mu~3~-Hydroxo)-(mu~3~-oxo)-(mu~3~-2-(alpha-phenylsalicylidenealdiminato)ethanolato-NOOO'O')-tris(mu~2~-2-(alpha-phenylsalicylidenealdiminato)ethanolato-NOOO')-tris(mu~2~-benzoato-OO')-(benzoato-O)-penta-iron(iii) dichloromethane methanol solvate sesquihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 955945: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-cyclohexylethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1825951: Experimental Crystal Structure Determination

2018

Related Article: Jacques Pliquett, Souheila Amor, Miguel Ponce-Vargas, Myriam Laly, Cindy Racoeur, Yoann Rousselin, Franck Denat, Ali Bettaïeb, Paul Fleurat-Lessard, Catherine Paul, Christine Goze, Ewen Bodio|2018|Dalton Trans.|47|11203|doi:10.1039/C8DT02364F

({2-[(5-chloro-1H-pyrrol-2-yl)(phenyl)methylidene]-N-[2-(diphenylphosphanyl)ethyl]-2H-pyrrol-5-aminato}(difluoro)boron)-chloro-gold(i) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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A novel two-dimensional organostannoxane coordination network promoted by phenazine: Synthesis, characterization and X-ray structure of

2009

Abstract Reaction of the dimeric hydroxo di-n-butylstannane trifluoromethanesulfonato complex [n-Bu2Sn(μ-OH)(H2O)0.5(η1-O3SCF3)]2 (1) with phenazine (C12H8N2, Phz) (2) in dichloromethane at room temperature in a 1:3 molar ratio yielded the novel two-dimensional organometallic coordination polymer 2 ∞ { [ n - Bu 2 ( μ -OH ) SnOSn ( μ - η 2 - O 3 SCF 3 ) n - Bu 2 ] 2 [ n - Bu 2 ( μ -OH ) SnOSn ( η 1 - O 3 SCF 3 ) n - Bu 2 ] 2 } (3), together with the phenazinium trifluoromethanesulfonate salt [C12H9N2]+ [CF3SO3]−, crystallographically isolated in two different structural arrangements, free 4 and in π–π aromatic stacking interaction with independent intercalated non-protonated phenazine molecu…

010405 organic chemistryCoordination polymerOrganic ChemistryIntermolecular forcePhenazineSupramolecular chemistryStacking010402 general chemistry01 natural sciencesBiochemistry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistryMoleculePhysical and Theoretical ChemistryTrifluoromethanesulfonateDichloromethaneJournal of Organometallic Chemistry
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E,Z-Stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition

2016

The stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama–Michael addition is reported. The reaction of silylketene acetals with N-tosylimines derived from β,γ-unsaturated α-keto esters in dichloromethane provided the corresponding (Z)-α,β-dehydroamino esters while the (E)-isomers were obtained when the reaction was carried out in the presence of 10 mol% copper(II) triflate.

010405 organic chemistryGeneral Chemical Engineeringchemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCopper0104 chemical scienceschemistry.chemical_compoundchemistryTosylCompostos orgànicsMichael reactionOrganic chemistryAminoàcidsTrifluoromethanesulfonateQuímica orgànicaDichloromethane
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Effect of Iodination on the Photophysics of the Laser Borane anti-B18H22: Generation of Efficient Photosensitizers of Oxygen

2019

Treatment of the laser borane anti-B18H22 (compound 1) with iodine in ethanol gives the monoiodinated derivative 7-I-anti-B18H21 (compound 2) in 67% yield, or, by reaction with iodine or ICl in the presence of AlCl3 in dichloromethane, the diiodinated derivative 4,4'-I2-anti-B18H20 (compound 3) in 85% yield. On excitation with 360 nm light, both compounds 2 and 3 give strong green phosphorescent emissions (λmax = 525 nm, ΦL = 0.41 and λmax = 545 nm, ΦL = 0.71 respectively) that are quenched by dioxygen to produce O2(1Δg) singlet oxygen with quantum yields of ΦΔ = 0.52 and 0.36 respectively. Similarly strong emissions can be stimulated via the nonlinear process of two-photon absorption when …

010405 organic chemistrySinglet oxygenNuclear magnetic resonance spectroscopyBorane010402 general chemistryPhotochemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryYield (chemistry)Physical and Theoretical ChemistrySpectroscopyPhosphorescenceDerivative (chemistry)DichloromethaneInorganic Chemistry
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CCDC 986491: Experimental Crystal Structure Determination

2014

Related Article: Albert Ferrer-Ugalde, Arántzazu González-Campo, Clara Viñas, Jesús Rodríguez-Romero, Rosa Santillan, Norberto Farfán, Reijo Sillanpää, Antonio Sousa-Pedrares, Rosario Núñez, Francesc Teixidor|2014|Chem.-Eur.J.|20|9940|doi:10.1002/chem.201402396

12-bis(Anthracen-9-ylmethyl)-12-dicarba-closo-dodecaborane dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2131009: Experimental Crystal Structure Determination

2022

Related Article: Braulio M. Puerta Lombardi, Ethan R. Pezoulas, Roope A. Suvinen, Alexander Harrison, Zachary S. Dubrawski, Benjamin S. Gelfand, Heikki M. Tuononen, Roland Roesler|2022|Chem.Commun.|58|6482|doi:10.1039/D2CC01476A

210-bis[26-bis(propan-2-yl)phenyl]-331111-tetramethyl-210-diazadispiro[4.2.48.25]tetradeca-19-diene-210-diium bis(tetrafluoroborate) dichloromethane unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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