Search results for "Ciencias Naturales"
showing 10 items of 287 documents
Mechanistic Understanding of Food Effects: Water Diffusivity in Gastrointestinal Tract Is an Important Parameter for the Prediction of Disintegration…
2013
Much interest has been expressed in this work on the role of water diffusivity in the release media as a new parameter for predicting drug release. NMR was used to measure water diffusivity in different media varying in their osmolality and viscosity. Water self-diffusion coefficients in sucrose, sodium chloride, and polymeric hydroxypropyl methylcellulose (HPMC) solutions were correlated with water uptake, disintegration, and drug release rates from trospium chloride immediate release tablets. The water diffusivity in sucrose solutions was significantly reduced compared to polymeric HPMC and molecular sodium chloride solutions. Water diffusivity was found to be a function of sucrose concen…
Semiflexible Polymers in Spherical Confinement: Bipolar Orientational Order Versus Tennis Ball States
2017
Densely packed semiflexible polymers with contour length L confined in spheres with radius R of the same order as L cannot exhibit uniform nematic order. Depending on the chain stiffness (which we vary over a wide range), highly distorted structures form with topological defects on the sphere surface. These structures are completely different from previously observed ones of very long chains winding around the inner surface of spheres and from nematic droplets. At high densities, a thin shell of polymers close to the sphere surface exhibits a tennis ball texture due to the confinement-induced gradual bending of polymer bonds. In contrast, when the contour length of the chains is significant…
Droplets pinned at chemically inhomogenous substrates: A simulation study of the two-dimensional Ising case
2016
As a simplified model of a liquid nanostripe adsorbed on a chemically structured substrate surface, a two-dimensional Ising system with two boundaries at which surface fields act is studied. At the upper boundary, the surface field is uniformly negative, while at the lower boundary (a distance L apart), the surface field is negative only outside a range of extension b, where a positive surface stabilizes a droplet of the phase with positive magnetization for temperatures T exceeding the critical temperature Tw of the wetting transition of this model. We investigate the local order parameter profiles across the droplet, both in the directions parallel and perpendicular to the substrate, vary…
Names for trace fossils: a uniform approach.
2006
The taxonomic treatment of trace fossils needs a uniform approach, independent of the ethologic groups concerned. To this aim, trace fossils are rigorously defined with regard to biological taxa and physical sedimentary structures. Potential ichnotaxobases are evaluated, with morphology resulting as the most important criterion. For trace fossils related to bioerosion and herbivory, substrate plays a key role, as well as composition for coprolites. Size, producer, age, facies and preservation are rejected as ichnotaxobases. Separate names for undertracks and other poorly preserved material should gradually be replaced by ichnotaxa based on well-preserved specimens. Recent traces may be iden…
Late Quaternary nearshore molluscan patterns from Patagonia: Windows to southern southwestern Atlantic-Southern Ocean palaeoclimate and biodiversity …
2019
Varied approaches (palaeobiodiversity, palaeobiogeography, bioerosion, geochemistry) to unique Patagonian late Quaternary molluscan assemblages in the southwestern Atlantic, with ages especially from interglacial Marine Isotope Stage (MIS) 5e and MIS 1, provide large-scale and long-temporal palaeoenvironmental data for the southern SWA. Together with new patterns of δ18O and δ13C variations in modern, mid-Holocene, and Late to Middle Pleistocene shells of Protothaca antiqua (Bivalvia) and the coeval Pleistocene Tegula atra (Gastropoda), the overall sources of evidence illustrate possible responses to recent palaeoclimate and sea-ice changes around the southernmost SWA-western Antarctica, le…
Late Cenozoic brittle deformation in the Southern Patagonian Andes: Record of plate coupling/decoupling during variable subduction?
2018
The Andes of southern Patagonia experienced a Miocene shift towards faster and higher angle subduction followed by the approach and collision of the Chile oceanic ridge. We present a kinematic study characterizing palaeostress fields computed from brittle tectonics to better constrain upper crustal deformation during this complex scenario. Although previous studies already suggested variable kinematics, it is striking that in a long-lasting subduction environment, the computed palaeostress tensors are mostly strike-slip (55%), while 35% are extensional, and only 10% compressive which are concentrated along a main frontal thrust. Cross-cutting relationships and synsedimentary deformation ind…
Cestodes from Hector's beaked whale ( Mesoplodon hectori ) and spectacled porpoise ( Phocoena dioptrica ) from Argentinean waters.
2010
Single individuals of 2 little-known cetacean species, Mesoplodon hectori and Phocoena dioptrica, stranded and died on the coast of Argentina (Buenos Aires and Chubut provinces, respectively) and were studied for the presence of helminths. The cestodes found were described and illustrated using light microscopy. The following cestode taxa were recovered: Tetrabothrius (Tetrabothrius) hobergi n. sp. (several fragmented specimens, at least 1 gravid) and Tetrabothrius (s.l.) sp. 1 (several fragmented immature specimens) from M. hectori, and Tetrabothrius (s.l.) sp. 2 (single fragmented immature specimen) and 2 morphotypes of tetraphyllidean larvae from P. dioptrica. Tetrabothrius (T.) hobergi …
Land surface temperature retrieval from LANDSAT TM 5
2004
In this paper, three methods to retrieve the land surface temperature (LST) from thermal infrared data supplied by band 6 of the Thematic Mapper (TM) sensor onboard the Landsat 5 satellite are compared. The first of them lies on the estimation of the land surface temperature from the radiative transfer equation using in situ radiosounding data. The others two are the mono-window algorithm developed by Qin et al. [International Journal of Remote Sensing 22 (2001) 3719] and the single-channel algorithm developed by Jime´nez-Mun˜oz and Sobrino [Journal of Geophysical Research 108 (2003)]. The land surface emissivity (LSE) values needed in order to apply these methods have been estimated from a…
DFT study on the cycloreversion of thietane radical cations.
2011
The molecular mechanism of the cycloreversion (CR) of thietane radical cations has been analyzed in detail at the UB3LYP/6-31G* level of theory. Results have shown that the process takes place via a stepwise mechanism leading to alkenes and thiobenzophenone; alternatively, formal [4 + 2] cycloadducts are obtained. Thus, the CR of radical cations 1a, b(center dot+) is initiated by C2-C3 bond breaking, giving common intermediates INa,b. At this stage, two reaction pathways are feasible involving ion molecule complexes IMCa,b (i) or radical cations 4a,b(center dot+) (ii). Calculations support that 1a(center dot+) follows reaction pathway (leading to the formal [4 + 2] cycloadducts 5a). By cont…
Pyrosequencing vs. culture-dependent approaches to analyze lactic acid bacteria associated to chicha, a traditional maize-based fermented beverage fr…
2015
The diversity of lactic acid bacteria (LAB) associated with chicha, a traditional maize-based fermented alcoholicbeverage from Northwestern Argentina, was analyzed using culture-dependent and culture-independent approaches.Samples corresponding to 10 production steps were obtained from two local producers at Maimará(chicha M) and Tumbaya (chicha T). Whereas by culture-dependent approach a few number of species(Lactobacillus plantarum and Weissella viridescens in chicha M, and Enterococcus faecium and Leuconostocmesenteroides in chicha T) were identified, a higher quantitative distribution of taxa was found in both beveragesby pyrosequencing. The relative abundance of OTUs was higher in chic…