Search results for "Clay"
showing 10 items of 349 documents
The role of organoclay and matrix type in photo-oxidation of polyolefin/clay nanocomposite films
2009
Abstract In this paper the photo-oxidation behaviour of polyolefin/clay nanocomposite films was studied; in particular, the effect of the amount of organo-modifier and the matrix polarity on the photo-oxidation was investigated. Two different organo-modified clays and compositions of LDPE/EVA blend films were used and the photo-oxidation was followed by mechanical and spectroscopic analyses. The organoclay and matrix type strongly influence the photo-oxidative behaviour of nanocomposite films. The films filled with CL15A show a faster loss of mechanical performance and higher carbonyl formation with respect to the films filled with the CL20A. Additionally, the LDPE based nanocomposite under…
Preparation and characterization of polyamide 6/polyethylene blend-clay nanocomposites in the presence of compatibilisers and stabilizing system
2010
Abstract Several compatibilising systems were added to high-density polyethylene (HDPE) and polyamide 6 (PA6) blends in the presence of an organically modified montmorillonite (OMM). All the blends were prepared by using a co-rotating twin-screw extruder and characterized by SEM, TEM and XRD analyses. In addition, the rheological behaviour and the mechanical properties – tensile and impact – were evaluated. The presence of OMM affects the dimensions of the polymeric phases in the blend but not their mutual adhesion, granted only by the compatibilisers. TEM, SEM and XRD analyses indicated that there is a strict correlation between the compatibilisation level and the final interlayer distance…
Hematite as an Electrocatalytic Marker for the Study of Archaeological Ceramic Clay bodies: A VIMP and SECM Study**
2022
[EN] The electrocatalytic effect exerted by hematite, a ubiquitous component of clay bodies, on the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) can be used to acquire information on archaeological ceramics. The solid-state voltammetric response of different hematite and ochre specimens, accompanied by SECM analysis in contact with 0.10 M HCl aqueous solution, is described. In air-saturated solutions, catalytic effects on the ORR and OER are accompanied by Fe(III)/Fe(II) and Fe(IV)/Fe(III) redox reactions. Such processes are conditioned by a variety of factors, the hydroxylation degree of the mineral surfaces being particularly influential, and exhibit significant var…
Processing – morphology – property relationships of polyamide 6/polyethylene blend–clay nanocomposites
2013
In this work, we studied the effect of the method of preparation and of reprocessing on the morphology and, con- sequently, on the physical properties of polyamide 6 (PA6)/ high density polyethylene (HDPE)-clay nanocomposite blends in the presence of different compatibilizers. In particular, the nanocomposites were obtained by melt mixing using a co- rotating twin screw extruder (E1). The blends thus obtained were re-extruded (E2) under the same operating conditions. Moreover, blends with the same final composition were produced using a masterbatch of the compatibilizer with the clay prepared in a separated stage in a batch mixer (MB). All the materials were characterized by scanning electr…
Polysaccharides/Halloysite nanotubes for smart bionanocomposite materials.
2020
Biopolymers as alternative to fossils-derived polymers are attracting the interest of researcher in material science. Besides the economic advantages, the sustainability makes polysaccharides ideal candidates to prepare films and formulations. The addition of Halloysite nanotubes as green inorganic fillers was exploited to improve the physico-chemical properties and to introduce smart response abilities to the material. Halloysite is a natural tubular nanomaterial with hollow cavity and large aspect ratio. The effect of polymer charge on the morphology and mesoscopic properties of polysaccharides/halloysite nanocomposites has been highlighted. Different strategies (solvent casting, lyophili…
The Suitability of Chemically and Thermally Activated Quaternary Clays of Latvia as Raw Material for Geopolymer Binders
2013
It is now accepted that new binders are needed to replace Portland cement (PC) for enhanced environmental and durability performance. The urge to reduce emissions of carbon and the fact that PC structures having built a few decades ago are already facing disintegration problems points out the handicaps of PC binders. Research works carried out in developing of alkali-activated binders show that this new type of binder could have a huge potential to become as alternative building material. Latvian Quaternary clays were studied from the point of view of the national economy, analysing the physical properties and chemical composition of those sediments in connection with the possibilities of …
Effect of different matrices and nanofillers on the rheological behavior of polymer-clay nanocomposites
2009
In this work, a comprehensive study of the rheological behavior under shear and isothermal and nonisothermal elongational flow of low density polyethylene (LDPE) and ethylene-vinyl acetate copolymer (EVA) based nanocomposites was reported to evaluate their "filmability", that is, the ability of these material to be processed for film forming applications. The influence of two different kinds of organoclay - namely Cloisite 15A and Cloisite 30B - and their concentration was evaluated. The presence of filler clearly affects the rheological behavior in oscillatory state of polyolefin-based nanocomposites but the increase of complex viscosity and the shear thinning are not dramatic. A larger st…
Water retention behaviour of compacted and reconstituted scaly clays
2020
The paper presents the results of an experimental research devoted to investigate the response to suction variations of a scaly clay in compacted and reconstituted conditions. Different experimental techniques (axis translation, vapour equilibrium, dew point psychrometer suction measurements) were combined in order to explore the water retention properties in a wide suction range (0 ÷ 110 MPa). Experimental results allowed to define the water retention domains for a constant reference void ratio, highlighting the significant role of the microstructure on the response of the investigated clays. In particular, the collected results showed that in the low-medium suction range, the peculiar mic…
On the hydro-mechanical behaviour of a lime-treated embankment during wetting and drying cycles
2018
Abstract The paper presents some experimental results obtained on samples extracted from a full-scale embankment obtained by compacting a lime-treated clayey soil. A comprehensive test programme was carried out in order to highlight the improvement of mechanical behaviour induced by lime treatment as well as to assess the durability of the improved material, which may be affected by severe seasonal wetting and drying cycles. Direct shear tests, triaxial compression tests, swelling potential measurement and oedometric tests were performed on samples cured in controlled environmental conditions for at least 18 months. Wetting and drying cycles were applied in a very wide range of suction valu…
Experimental Investigation on the Compressive Behaviour of Clay Brick Masonry Columns Confined by BFRP or Steel Wires
2016
This paper presents the results of an experimental research aiming to investigate on the compressive behavior of full size clay brick masonry columns reinforced with Basalt Fiber Reinforced Cementitious Matrix (BFRCM) or with steel wires collaring. Uniaxial compressive tests were performed on eight retrofitted columns and four control specimens. Two masonry strength were considered by varying the mortar grade. Results are presented and discussed in terms of axial stress-strain relationships, failure modes and crack patterns of the specimens tested up to failure. For the limit of investigated variables, comparisons with unreinforced specimens show the ability of these alternative techniques …