Search results for "Clay"

Characterization and correlation of Upper Jurassic (Oxfordian) bentonite deposits in the Paris Basin and the Subalpine Basin, France

2003

Explosive volcanic activity is recorded in the Upper Jurassic of the Paris Basin and the Subalpine Basin of France by the identification of five bentonite horizons. These layers occur in Lower Oxfordian (cordatum ammonite zone) to Middle Oxfordian (plicatilis zone) clays and silty clays deposited in outer platform environments. In the Paris Basin, a thick bentonite (10–15 cm), identified in boreholes and in outcrop, is dominated by dioctahedral smectite (95%) with trace amounts of kaolinite, illite and chlorite. In contrast, five bentonites identified in the Subalpine Basin, where burial diagenesis and fluid circulation were more important, are composed of a mixture of kaolinite and regular…

Hybrid magnetic materials based on layered double hydroxides: from the chemistry towards the applications

2014

Layered double hydroxides (LDHs) are the leitmotiv of this dissertation. Contradicting the assertion that “any past was better”, LDHs have been continuously revisited from the middle of the twentieth century, and represent an excellent example of the never-ending beauty of Chemistry. New synthetic perspectives are giving a new impetus to LDH chemistry, which among hybrid materials, are finding their heyday. This is resulting in novel materials and also paving the way for new fundamental and practical insights. This dissertation is focused on magnetic LDHs, and for the sake of clarity it is organized in three main parts: we will move from basic synthetic and physical aspects of LDHs, through…

Photo-stabilization of biopolymers-based nanocomposites with UV-modified layered silicates

2020

Abstract Eco-friendly in-situ stabilised biopolymer nanocomposites based on polyamide 11 (PA11) and polylactic acid (PLA) were prepared by melt mixing in the presence of a modified organo-montmorillonite clay containing a chemically-bound hindered amine UV-stabilising function, [(UV)OM-MMt]. Characterisation of the newly synthesised organo-modifier containing the reactive hindered amine (HAS) UV-stabilising function [(UV)OM] has confirmed a successful synthesis. The (UV)OM was then introduced into NaMMt through ion exchange reaction to prepare the UV stabiliser-bound organo-modified-MMt, [(UV)OM-MMt]. The in-situ stabilised PA11- and PLA- nanocomposites (PA11-(UV)OM-MMt and PLA-(UV)OM-MMt) …

Polyolefin based nanocomposites: a method to achieve better dispersion of nanoclays in PE films and improve their physical properties

2009

Late Cretaceous palaeoenvironments expressed by the clay mineralogy of Cenomanian–Campanian chalks from the east of the Paris Basin

2005

Abstract The clay fraction of Cenomanian–Campanian chalks cored at Poigny and Sainte-Colombe, close to Provins (east-south-east of Paris), includes variable proportions of smectitic minerals, illite and kaolinite. The smectitic sediments (which constitute the background of low-terrigenous supply throughout the stratigraphic interval) resulted mainly from the warm, humid climate and high sea level that prevailed during Late Cretaceous in this area. During the Late Turonian, the smectitic sedimentation was interrupted by significant detrital inputs of illite and kaolinite. This reflected tectonic rejuvenation of landmasses coeval with an explosive volcanism expressed by the occurrence of bent…

From Maya Blue to “Maya Yellow”: A Connection between Ancient Nanostructured Materials from the Voltammetry of Microparticles

2011

The yellow hue of a series of samples from wall paintings in several Mayan archaeological sites can be attributed to the presence of indigoid compounds, including isatin and dehydroindigo, attached to palygorskite, a local phyllosilicate clay. SEM/EDX, TEM, UV/Vis spectroscopy, and voltammetry of microparticles show that the ancient Mayas could prepare indigo, Maya Blue, and "Maya Yellow" during successive stages. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effect of Morphology and Size of Halloysite Nanotubes on Functional Pectin Bionanocomposites for Food Packaging Applications

2017

Pectin bionanocomposite films filled with various concentrations of two different types of halloysite nanotubes were prepared and characterized in this study as potential films for food packaging applications. The two types of halloysite nanotubes were long and thin (patch) (200-30 000 nm length) and short and stubby (Matauri Bay) (50-3000 nm length) with different morphological, physical, and dispersibility properties. Both matrix (pectin) and reinforcer (halloysite nanotubes) used in this study are considered as biocompatible, natural, and low-cost materials. Various characterization tests including Fourier transform infrared spectroscopy, field emission scanning electron microscopy, rele…

Chemical weathering of volcanic rocks at the island of Pantelleria, Italy: Information from soil profile and soil solution investigations

2007

Abstract Concentrations of major, minor and trace elements were determined in soil profiles and soil solutions from the island of Pantelleria, Sicily Channel, to evaluate the weathering extent of soils evolved on trachytic and pantelleritic rocks and the aqueous transport of elements by their soil solutions. The chemical index of alteration (CIA) indicates a low-to-moderate degree of weathering; consistently, the mineralogical and geochemical imprints of the parent rocks are generally preserved. The chemical weathering appears to be incongruent, owing to primary minerals and glass dissolving to a variable degree while secondary minerals have formed. Based on the calculated saturation state …

Over-estimation of efficiency of weathering in tropical “Red Soils”: its importance for geoecological problems

2000

Abstract Weathering and soil formation rates are regarded as the main criteria of a tolerable soil loss. The efficiency of weathering in the seasonal semiarid tropics has often been greatly over-estimated especially in the geomorphologic literature in which weathering is assumed to be as fast or even faster than surface erosion. Six selected “Red Soils” in two intramontane basins of hyperthermic SW Nepal near the border with India, with 1500–1750 mm annual rainfall (5 humid months), and a “Black Soil” near Baroda, Gujarat, India (3–4 humid months) were studied mineralogically. Two of the “Red Soils” have TL ages between 10 and 30 ka, the “Black Soil” has one of about 10 ka. The yellowish si…

Clay minerals, oxyhydroxide formation, element leaching and humus development in volcanic soils

2008

Aweathering sequence with soils developing on volcanic, trachy-basaltic parent materials with ages ranging from 100–115,000 years in the Etna region served as the basis to analyse and calculate the accumulation and stabilisation mechanisms of soil organic matter (SOM), the transformation of pedogenic Fe and Al, the formation and transformation of clay minerals, the weathering indices and, by means of mass-balance calculations, net losses of the main elements. Although the soils were influenced by ash depositions during their development and the soil on the oldest lava flow developed to a great extent under a different climate, leaching of elements and mineral formation and transformation co…