Search results for "Clay"
showing 10 items of 349 documents
An experimental and constitutive investigation on the chemo-mechanical behaviour of a clay. In Bio- and Chemo- Mechanical Processes in Geotechnical E…
2014
Engineering issues for which the understanding of the chemo-mechanical behaviour of soils is relevant include wellbore stability problems, the salinification of groundwater, and nuclear waste storage. However, despite the vast number of situations in which couplings between chemistry and mechanics occur, the available constitutive models rely on limited experimental evidence. This paper presents the results of an experimental programme on the chemo-mechanical behaviour of a non-swelling illite. The osmotic suction is controlled through the ion concentration of sodium chloride in the pore water. Stress paths include mechanical loading at a constant osmotic suction, and an increasing osmotic …
The void ratio dependency of the retention behaviour for a compacted scaly clay
2010
Resistenza a taglio di campioni rimaneggiati di Opalinus Clay
2021
La nota presenta una selezione dei risultati di un ampio programma sperimentale condotto con l’obiettivo di caratterizzare, dal punto di vista della resistenza a taglio, dei campioni rimaneggiati di Opalinus Clay, attraverso l’esecuzione di prove triassiali non convenzionali. I risultati mostrano chiaramente l’influenza del grado di preconsolidazione sul comportamento meccanico del geomateriale e in particolare sulla resistenza a taglio, che risulta caratterizzata da un picco di resistenza poco marcato e da un comportamento dilatante. La presenza di giunti all’interno del provino altera completamente il comportamento originario del materiale, che diventa duttile e contraente. Inoltre, in ta…
Microstructure and mechanical behaviour of a saturated compacted scaly clay
2011
The paper presents the results of a research on the influence of structure characteristics on the mechanical behaviour of a saturated compacted scaly clay. To this aim, mechanical properties of compacted scaly clay samples after saturation are compared with the corresponding properties measured on the clay reconstituted in the laboratory. For the stress range explored in the experimental programme, compacted scaly clay samples are stiffer and stronger than reconstituted clay samples owing to their greater density. Collected results are discussed taking in consideration microstructure characteristics of the compacted and reconstituted clay samples
Effects of Organoclay on Morphology and Properties of Nanocomposites Based on LDPE/PA6 Blends without and with SEBS-g-MA
2009
LDPE/PA-6 blends (75/25 wt/wt) were added with SEBS-g-MA (S) and/or an organoclay (20A) using different compounding sequences and the morphology and the properties of the blends or composites were investigated. An XRD study of the nanocomposites with pure polymers showed that 20A is intercalated by LDPE or PA-6 chains, whereas it is exfoliated by S if the clay concentration does not exceed 10 wt%. The SEM investigation showed that both S and 20A behave as efficient emulsifying agents for the LDPE/PA-6 blends. However, their effect on the mechanical properties was found to be opposite: S enhanced toughness but lowered the stiffness, whereas 20A improved the elastic modulus but impaired the i…
Clay nanocomposites based on compatibilized PA6/HDPE blends
2009
Physical and biological properties of electrospun poly(d,l‐lactide)/nanoclay and poly(d,l‐lactide)/nanosilica nanofibrous scaffold for bone tissue en…
2021
Abstract Electrospun scaffolds exhibiting high physical performances with the ability to support cell attachment and proliferation are attracting more and more scientific interest for tissue engineering applications. The inclusion of inorganic nanoparticles such as nanosilica and nanoclay into electrospun biopolymeric matrices can meet these challenging requirements. The silica and clay incorporation into polymeric nanofibers has been reported to enhance and improve the mechanical properties as well as the osteogenic properties of the scaffolds. In this work, for the first time, the physical and biological properties of polylactic acid (PLA) electrospun mats filled with different concentrat…
On the hydro-mechanical behaviour of remoulded and natural Opalinus Clay shale
2016
The geo-energy sector makes use of advanced technologies such as shale gas extraction, CO2 sequestration and nuclear waste geological disposal that rely on the exploitation of shale formations. Due to the great depths involved in these applications and the difficulties in retrieving intact samples, remoulded shale specimens are often adopted for hydro-mechanical testing. Remoulded and intact shales may substantially differ in their hydro-mechanical behaviour due to the particular structure of the natural material, which is the result of diagenesis and burial history. This paper presents an experimental campaign aimed at (i) characterizing the role of diagenesis and depth for Opalinus Clay s…
Thermodynamics and Structure of Plate-Like Particle Dispersions
2012
A considerable amount of mineral particles are found to have a plate-like shape. The work in this thesis concerns theoretical investigations, using a Monte Carlo method, of the properties of such particles in aqueous solutions. The objectives were first to create a model that could capture the essential physics of clay suspensions and also to understand the role of thermodynamics in certain chemical processes. For all investigations, the results are related to experimental studies. The acid-base behavior of clays have been studied, using the primitive model, and an excellent agreement between simulated and experimental results was found. The formation of gel phases as a function of the char…
Halloysite nanotubes as nanoreactors for heterogeneous micellar catalysis
2021
Abstract Hypothesis Electrostatic attractions between the anionic head group of sodium alkylsulphates and the positively charged inner surface of halloysite nanotubes (HNTs) drive to the formation of tubular inorganic micelles, which might be employed as nanoreactors for the confinement of non polar compounds in aqueous media. On this basis, sodium alkylsulphates/halloysite hybrids could be efficient nanocatalysts for organic reactions occurring in water. Experiments Sodium decylsulphate (NaDeS) and sodium dodecylsulphate (NaDS) were selected for the functionalization of the halloysite cavity. The composition, the structure and the surface charge properties of the hybrid nanotubes were dete…