Search results for "Combustion"

showing 10 items of 232 documents

Rotational CARS thermometry at high temperature (1800 K) and high pressure (0.1-1.55 MPa)

2007

International audience; Dual-broadband rotational CARS (DB-RCARS) thermometry has been investigated at high temperature and high pressure. Single-shot measurements were performed at 1800 K, in air and nitrogen at pressures up to 1.55 MPa and in oxygen at pressures up to 0.5 MPa. For all conditions, the resonant signal contribution to the spectra clearly dominated over the non-resonant one, implying the high potential for DB-RCARS for temperature and concentration measurements also at the high temperatures and pressures used in the present investigation. The relative standard deviation was generally similar to 2% for single-shot data at pressures from 0.5 to 1.55 MPa. At the investigated tem…

Relative standard deviationAnalytical chemistrychemistry.chemical_element02 engineering and technology7. Clean energy01 natural sciencesOxygenSpectral lineStandard deviation010309 opticssymbols.namesakecombustion diagnostics0103 physical sciencesGeneral Materials Sciencerotational CARSSpectroscopy[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]Chemistry021001 nanoscience & nanotechnologyNitrogengas-phase thermometryHigh pressureExcited statesymbols0210 nano-technologyRaman spectroscopy
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Characterization and pilot scale fluidized bed gasification of herbaceous biomass: A case study on alfalfa pellets

2015

Abstract Pilot-scale bubbling fluidized bed gasification tests of alfalfa pellets were performed at two different operational periods ranged on the basis of the two given equivalence ratio (ER) (the ratio between actual air and the stoichiometric air) namely as 0.25 and 0.30. During the test, the solid feeding rate was kept constant at 4.7 kg/h while the air input was varied and thus the ER. Increasing air from 4.16 to 4.99 N m3/h contributed to the evolution pattern of several parameters such as the rise in gas lower heating value (LHV) and gas yield, the average maximum of which were 4.2 MJ/N m3 and 1.5 N m3/kg respectively. Gas composition was mainly boosted by the concentration of CO, a…

Renewable Energy Sustainability and the EnvironmentAirflowPelletsEnvironmental engineeringEnergy Engineering and Power TechnologyTarBiomassPulp and paper industryFuel TechnologyNuclear Energy and EngineeringFluidized bedEnvironmental scienceHeat of combustionCharGas compositionEnergy Conversion and Management
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Evaluation of the fuel potential of sewage sludge mixtures with beech sawdust and lignite

2018

Sewage sludge (SS) from municipal wastewater treatment has drawn serious attention of scientists around the world in the attempt to find feasible disposal methods. Therefore, in this work, a solution for valorisation of SS as solid fuel is proposed based on an advanced compositional investigation of SS versus conventional solid fuels, namely, lignite (L) and beech sawdust (BS). A characterisation in terms of proximate analysis and ultimate analysis was performed for the studied materials, both to SS, L, and BS as single fuel and to bi-component mixture formulas of SS and L/BS, in variable proportions of 30:70, 50:50, and 70:30. SS:BS based blends had higher hydrogen (from 4.43 wt. % to 5.14…

Renewable Energy Sustainability and the EnvironmentChemistry020209 energy02 engineering and technology010501 environmental sciencesPulp and paper industrySolid fuelCombustion01 natural sciencesWastewaterBiofuelvisual_art0202 electrical engineering electronic engineering information engineeringvisual_art.visual_art_mediumSewage sludge treatmentSawdustValorisationSludge0105 earth and related environmental sciencesJournal of Renewable and Sustainable Energy
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Structural and morphological properties of Co-La catalysts supported on alumina/lanthana for hydrocarbons oxidation

2004

Abstract Two Al 2 O 3 (24 wt%)–La 2 O 3 (76 wt%) supported Co–La oxides with Co loading 4 wt% and different La content (1 and 9 wt%) were prepared by co-impregnation of the support, the aluminum–lanthanum oxide, with cobalt and lanthanum nitrates in aqueous solution and successive calcination at 800 °C for 4 h. The alumina–lanthana was synthesized by the sol–gel method. The samples were characterized by X-ray diffraction (XRD) and Rietveld refinement in order to identify the crystalline phases and their relative weight. H 2 -TPR (Temperature Programmed Reduction) experiments were recorded with the aim to identify the different Co phases present. Co 3 O 4 and LaCoO 3 were formed for La loadi…

Rietveld refinementPEROVSKITEInorganic chemistryOxidechemistry.chemical_elementCondensed Matter PhysicsElectronic Optical and Magnetic Materialslaw.inventionCatalysischemistry.chemical_compoundCOMBUSTIONchemistrylawLACOO3Materials ChemistryCeramics and CompositesLanthanumCalcinationAtomic ratioTemperature-programmed reductionCobalt
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Solid Rocket Motor Combustion Instabilities: Analysis of the Transition to the First Limit Cycle

2009

A nonlinear multi time-scale analysis of the solid propellant rocket motor transition to the first limit cycle is presented and the motor behavior subsequent to some relevant transition scenarios is investigated. Important physical parameters characterizing the transition to limit cycle are then put in evidence and their cross-effects are studied. The analysis takes into account the effects of acoustic-vorticity-entropy wave coupling, waves steepening, rotational and viscous flow losses due to the steep-fronted waves, energy losses in the steepened state, nonlinear energy pathways and includes the study of the oscillatory energy losses in the nozzle, the unsteady combustion and the combusti…

Rocket Motor Combustion Instabilities Limit CycleSettore ING-IND/07 - Propulsione Aerospaziale
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New synthetic strategies for the enhancement of the ionic conductivity in Ce0.8Sm0.2O2-x

2013

Introduction Samarium-doped ceria has been widely investigat-ed for electrochemistry applications as full density elec-trolyte for intermediate temperature solid oxide fuel cells (IT-SOFC), between 500°C and 800°C [1]. One of the main challenges for the ceria-based electrolytes is to decrease the resistivity at the grain boundary zone, especially in this low temperature range. Microstructure and morphology of the powder play a fundamental role on the densification behaviour and grain boundary properties, thus affecting the overall conductivity of electrolytes [2]. In this light, solution combustion syn-thesis (SCS) represents a flexible method to produce ultra fine powders with suitable mic…

SDC electrolyteIT-SOFCcombustion synthesis ionic conductivitysamarium-doped ceria electrolytesolution combustion synthesis
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Models of SHS: An overview

2007

International audience; The theoretical models of SHS based on lamellar or cellular approximations of the heterogeneous reactive media are comparatively analyzed. It is shown that the ratio of the reaction time to the characteristic time of heat transfer between particles is a decisive parameter for the combustion wave propagation. When the time of reaction is shorter than the time of heat exchange, the combustion occurs in a discrete mode; in the opposite case, a quasi-homogeneous combustion mode occurs. Development of the discrete cellular model does not discard the quasi-homogeneous approach but markedly extends the scope of combustion theory. This extension enables explanation of many o…

SHS[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]quasi-homogeneous and discrete modes[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci][ PHYS.COND.CM-MS ] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]flame propagation[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Physics::Chemical Physicsstabilitycombustion synthesismathematical models[PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci][PHYS.PHYS.PHYS-CHEM-PH] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]
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Comparison of tritium measurement techniques for a laser cleaned JET tile

2014

Abstract Over the last 7–8 years, two quantitative analyzing methods—accelerator mass spectrometry (AMS) and full combustion (FC) followed by scintillation detection have been applied for determining the tritium activity concentrations in JET divertor tiles. These methods have two main differences – the range of detection and the spatial resolution – and are thus complementary. However, these differences can also complicate the comparison of the two techniques for typical JET divertor samples. Therefore a cross comparison exercise for tritium measurements was performed between the two methods using specially produced identical standard samples. The cross comparison measurements were perform…

ScintillationJet (fluid)Materials scienceLaser ablationTokamakMechanical EngineeringNuclear engineeringDivertorfull combustionLaserlaw.inventionNuclear physicsNuclear Energy and Engineeringlawtritium retentionvisual_artaccelerator mass spectometryvisual_art.visual_art_mediumGeneral Materials ScienceTiletokamaksCivil and Structural EngineeringAccelerator mass spectrometryFusion Engineering and Design
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Existence of a traveling wave solution in a free interface problem with fractional order kinetics

2021

Abstract In this paper we consider a system of two reaction-diffusion equations that models diffusional-thermal combustion with stepwise ignition-temperature kinetics and fractional reaction order 0 α 1 . We turn the free interface problem into a scalar free boundary problem coupled with an integral equation. The main intermediary step is to reduce the scalar problem to the study of a non-Lipschitz vector field in dimension 2. The latter is treated by qualitative topological methods based on the Poincare-Bendixson Theorem. The phase portrait is determined and the existence of a stable manifold at the origin is proved. A significant result is that the settling time to reach the origin is fin…

Settling timeScalar (mathematics)01 natural sciencesPoincare-Bendixson TheoremTraveling wave solutionsMathematics - Analysis of PDEsDimension (vector space)Free boundary problemFOS: Mathematics[MATH.MATH-AP]Mathematics [math]/Analysis of PDEs [math.AP]Trapping triangles0101 mathematicsMathematicsPhase portraitApplied Mathematics010102 general mathematicsMathematical analysisIntegral equationStable manifoldDiffusional-thermal combustionFree interface problems010101 applied mathematicsVector fieldFractional order kineticsAnalysisAnalysis of PDEs (math.AP)
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Exploring Solvent-free Citrate-Nitrate Auto-Combustion for the Synthesis of SOFC Electrocatalysts

2009

Settore CHIM/03 - Chimica Generale E InorganicaSOFC Electrocatalysts Citrate-Nitrate Auto-CombustionSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie
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