Search results for "Complex."
showing 10 items of 5824 documents
Severe effects of long-term drought on calcareous grassland seed banks
2018
Climate change models project shifts in precipitation patterns at regional and global scales. Increases in dry areas and the occurrence of drought predicted in future scenarios are likely to threaten grassland ecosystems. Calcareous grassland seed banks have proven to be resistant to short-term drought, but their responses to long-term drought are unknown. Here we show that 14 years of summer drought changed calcareous grassland seed bank composition, reducing its size and richness, and that these responses do not simply reflect patterns in the above-ground vegetation. Moreover, the effect of drought was larger on seed banks than on vegetation, and above-ground responses mediated by soil de…
Influence of plant traits, soil microbial properties, and abiotic parameters on nitrogen turnover of grassland ecosystems
2016
International audience; Although it is known that multiple interactions among plant functional traits, microbial properties , and abiotic soil parameters influence the nutrient turnover, the relative contribution of each of these groups of variables is poorly understood. We manipulated grassland plant functional composition and soil nitrogen (N) availability in a multisite mesocosm experiment to quantify their relative effects on soil N turnover. Overall, root traits, arbuscular mycorrhizal colonization, denitrification potential, as well as N availability and water availability, best explained the variation in measured ecosystem properties, especially the trade-off between nutrient sequest…
Lake browning impacts community structure and essential fatty acid content of littoral invertebrates in boreal lakes
2021
AbstractMany lakes in the northern hemisphere are browning due to increasing concentrations of terrestrial dissolved organic carbon (DOC). The consequences of lake browning to littoral invertebrates, however, are not fully understood. We analyzed community structure and fatty acid (FA) profiles of littoral invertebrates in humic (DOC-rich) and clear-water lakes in Eastern Finland. We found higher abundance of chironomids (Diptera: Chironomidae) in humic compared to clear-water lakes, whereas stoneflies (Plecoptera) and mayflies (Ephemeroptera: Baetidae) were more abundant in clear-water lakes. Taxon explained 65% of the differences in the FA composition of littoral invertebrates. However, t…
Effect of Seasonal Storage on Single-Stem Bark Extractives of Norway Spruce (Picea abies)
2021
Increasing the net value of forestry side-streams has both ecological as well as economic benefits for emerging biorefining industries. Spruce bark represents one of the nature’s abundant sources of valuable extractives. In this study, the impact of storage on the quality and quantity of Norway spruce (Picea abies) extractives was examined as a function of storage time, environmental conditions and season (i.e., winter or summer). The bark from stored spruce saw logs was extracted with an accelerated solvent extractor (ASE) at 120 °C with hexane and water. The produced extracts were analysed qualitatively and quantitatively by gas chromatography with a flame ionisation detector (GC-FID) and…
Evaluating the potential for evolutionary mismatch in Batesian mimics: A case study in the endangered smooth snake (Coronella austriaca)
2018
Many harmless organisms gain a survival advantage by mimicking venomous species. This is the case of the endangered smooth snake (Coronella austriaca), which mimics venomous vipers. Although this may protect the smooth snake against most of its natural predators, it may render them at greater risk of mortality from humans, who are more inclined to kill species, such as vipers, that they consider dangerous. This may cause an evolutionary mismatch, whereby humans may counteract the natural advantage of mimicry. We explore this possibility of evaluating the willingness of humans to kill smooth snakes versus the adder (Vipera berus), as well as their ability to discern them in the Åland Islands…
Loading and release of the complex [Pt(DTBTA)(DMSO)Cl]Cl·CHCl3 with the 2,2′-dithiobis(benzothiazole) ligand into mesoporous silica and studies of an…
2018
Abstract Synthetic delivery systems have great potential for overcoming problems associated with systemic toxicity that accompanies chemotherapy with the use of cisplatin and family of platinum anticancer drugs. Mesoporous silicates have been studied in context of drug delivery and drug targeting. In this paper we report the studies of loading and release of a platinum complex, [Pt(DTBTA)(DMSO)Cl]Cl∙CHCl3 (1) where DTBTA = 2,2′-dithiobis(benzothiazole), that was recently synthesized and structurally characterized. Evaluation in vitro of antitumor activity against a human breast cancer cell line (MCF-7) showed a very potent activity of complex(1). Therefore, we thought to incorporate this co…
NIR-absorbing transition metal complexes with redox-active ligands
2020
Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region. Peer reviewed
WarpDrive: Massively Parallel Hashing on Multi-GPU Nodes
2018
Hash maps are among the most versatile data structures in computer science because of their compact data layout and expected constant time complexity for insertion and querying. However, associated memory access patterns during the probing phase are highly irregular resulting in strongly memory-bound implementations. Massively parallel accelerators such as CUDA-enabled GPUs may overcome this limitation by virtue of their fast video memory featuring almost one TB/s bandwidth in comparison to main memory modules of state-of-the-art CPUs with less than 100 GB/s. Unfortunately, the size of hash maps supported by existing single-GPU hashing implementations is restricted by the limited amount of …
Torus Topology based Fault-Tolerant Network-on-Chip Design with Flexible Spare Core Placement
2018
The increase in the density of the IP cores being fabricated on a chip poses on-chip communication challenges and heat dissipation. To overcome these issues, Network-onChip (NoC) based communication architecture is introduced. In the nanoscale era NoCs are prone to faults which results in performance degradation and un-reliability. Hence efficient fault-tolerant methods are required to make the system reliable in contrast to diverse component failures. This paper presents a flexible spare core placement in torus topology based faulttolerant NoC design. The communications related to the failed core is taken care by selecting the best position for a spare core in the torus network. By conside…
A validity and reliability study of Conditional Entropy Measures of Pulse Rate Variability
2019
In this work, we present the feasibility to use a simpler methodological approach for the assessment of the short-term complexity of Heart Rate Variability (HRV). Specifically, we propose to exploit Pulse Rate Variability (PRV) recorded through photoplethysmography in place of HRV measured from the ECG, and to compute complexity via a linear Gaussian approximation in place of the standard model-free methods (e.g., nearest neighbor entropy estimates) usually applied to HRV. Linear PRV-based and model-free HRV-based complexity measures were compared via statistical tests, correlation analysis and Bland-Altman plots, demonstrating an overall good agreement. These results support the applicabil…