Search results for "Composite"

showing 10 items of 4584 documents

Dielectric nonlinearity of the PBB′B″O3 ferroelectric solid solutions

2001

Abstract Obtaining of novel thin film materials for electrically tuneable capacities is one of the current problems of ferroelectric material application. Suitable ferroelectric compounds exhibiting broad phase transitions and small dielectric loss in the paraelectric phase have been searched for the purpose. Lead-containing niobates PbMg1/3Nb2/3O3 (PMN), PbNi1/3Nb2/3O3 (PNN) and PbZn1/3Nb2/3O3 (PZN) and their solid solutions have been found as most appropriate. Materials have been synthesized by solid phase reactions from the relevant oxides; ceramic samples were obtained by conventional ceramic technology. Results of the studies of thermal dependence of dielectric permeability and loss fa…

Phase transitionMaterials scienceFerroelectric ceramicsDielectricCondensed Matter PhysicsFerroelectricityElectronic Optical and Magnetic MaterialsControl and Systems Engineeringvisual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumDielectric lossCeramicElectrical and Electronic EngineeringComposite materialTernary operationSolid solutionIntegrated Ferroelectrics
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Specifics of polarisation switching in PbNi1/3Nb2/3O3–PbTiO3–PbZrO3 ferroelectric ceramics

2004

Abstract The growing interest in disordered relaxor ferroelectrics is due to unusual properties mainly related to the existence of broad phase transitions characteristic to the systems. The effects of bias field on the dielectric response and polarisation switching are studied in the 0.5 PbNi 1/3 Nb 2/3 O 3 – x PbTiO 3 –(0.5− x ) PbZrO 3 system at different PbTiO 3 :PbZrO 3 ratio. Thermal behaviour of normalised remnant polarisation P r / P max of compositions with content of lead titanate x =0.33 and x =0.35 at frequency 0.1 Hz and different values of field E o are measured. Results of measured polarisation and depolarisation currents are compared with characteristics of polarisation switc…

Phase transitionMaterials scienceField (physics)Condensed matter physicsFerroelectric ceramicsDielectric permittivityMineralogyDielectric responsechemistry.chemical_compoundAmplitudechemistryMaterials ChemistryCeramics and CompositesLead titanateBias fieldJournal of the European Ceramic Society
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LEAD-FREE (Na0.5Bi0.5)1-xBaxTiO3 SINGLE CRYSTALS (0 ≤ x ≤ 0.05) AND THEIR DIELECTRIC AND PYROELECTRIC PROPERTIES

2009

ABSTRACT Lead-free single crystals of Na0.5Bi0.5TiO3-BaTiO3 (NBT-BT) system were prepared by Czochralski method and their dielectric and pyroelectric properties have been studied. The results were compared with these for pure NBT. The obtained samples show pure perovskite structure with rhombohedral symmetry at room temperature. Low frequency (100 Hz–100 kHz) investigations reveal the diffuse phase transitions. The obtained results are discussed in terms of local electric and strain fields caused by different ionic radius of (Na, Bi) and Ba ions. The NBT-BT system is expected to be a new promising candidate for lead-free electronic crystals.

Phase transitionMaterials scienceIonic radiusAnalytical chemistryDielectricLow frequencyCondensed Matter PhysicsFerroelectricityElectronic Optical and Magnetic MaterialsIonPyroelectricityCrystallographyControl and Systems EngineeringMaterials ChemistryCeramics and CompositesElectrical and Electronic EngineeringPyroelectric crystalIntegrated Ferroelectrics
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A thermotropic liquid crystal elastomer micro-actuator with integrated deformable micro-heater

2014

We present a liquid crystal elastomer (LCE) actuator with large stroke and fast reaction time. LCEs show a large macroscopic shape change when heated above the phase transition (≈120°C). Buried wafer-level fabricated micro-heaters offer optimal thermal reaction times and compact design of the actuators. A relative length change of λ = 1.28 was obtained with 320 mW power consumption. Heating the device from room temperature takes τrise = 19.7 s, cooling below the phase transition temperature from the fully contracted state needs τfall - 5.6s. We verify that the displacement may be accurately controlled by varying electrical input power.

Phase transitionMaterials scienceLiquid crystal elastomerStroke (engine)Composite materialActuatorElastomerThermotropic crystalDisplacement (fluid)Power (physics)2014 IEEE 27th International Conference on Micro Electro Mechanical Systems (MEMS)
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Bioinspired actuated adhesive patterns of liquid crystalline elastomers.

2012

Gecko-inspired arrays of micropillars made of a liquid crystalline elastomer display thermoswitchable adhesive behavior as a consequence of elongation changes caused by reorientation of the mesogens at the nematic-isotropic (N-I) phase transition.

Phase transitionMaterials scienceLiquid crystallineMechanical EngineeringElastomerBenzoatesLiquid CrystalsElastomersMechanics of MaterialsBiomimeticsAdhesivesGeneral Materials ScienceAdhesiveComposite materialElongationAdvanced materials (Deerfield Beach, Fla.)
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Phase transitions and upconversion luminescence in oxyfluoride glass ceramics containing Ba4Gd3F17 nanocrystals

2017

This is the peer reviewed version of the following article: G. Krieke, A. Sarakovskis, R. Ignatans, J. Gabrusenoks "Phase transitions and upconversion luminescence in oxyfluoride glass ceramics containing Ba4Gd3F17 nanocrystals", Journal of the European Ceramic Society, 2017, 37 (4), which has been published in final form at https://www.sciencedirect.com/science/article/abs/pii/S0955221916306768 This article may be used for non-commercial purposes in accordance with Elsevier Terms and Conditions for Sharing and Self-Archiving.

Phase transitionMaterials scienceLuminescenceScanning electron microscopeGlass ceramicsAnalytical chemistryNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesBa4Gd3F17symbols.namesakePhase (matter)Materials Chemistry:NATURAL SCIENCES:Physics [Research Subject Categories]OxyfluorideRietveld refinement021001 nanoscience & nanotechnologyPhoton upconversion0104 chemical sciencesTransmission electron microscopyCeramics and Compositessymbols0210 nano-technologyRaman spectroscopyLuminescenceUpconversion
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Synthesis and Characterization of Lead-Free (1-x)(K0.5Na0.5)Nb1-ySbyO3-xBaTiO3

2011

In this study lead-free ceramics with a formula (1-x)(K0.5Na0.5)Nb1-ySbyO3-xBaTiO3 have been synthesized and studied. XRD studies showed that all compositions have perovskite structure with monoclinic or tetragonal cell depending on substitution level. KNN ceramics with BaTiO3 have more homogeneous structure and increased density in comparison with pure KNN or antimony substituted KNN. Dielectric measurements revealed diffuse phase transition.

Phase transitionMaterials scienceMineralogychemistry.chemical_elementDielectricCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsCharacterization (materials science)CrystallographyTetragonal crystal systemchemistry.chemical_compoundAntimonychemistryControl and Systems Engineeringvisual_artBarium titanateMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCeramicElectrical and Electronic EngineeringMonoclinic crystal systemIntegrated Ferroelectrics
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Structural, magnetic, dielectric and mechanical properties of (Ba,Sr)MnO3 ceramics

2017

The authors acknowledge the CPU time allocation at Academic Computer Centre CYFRONET AGH in Cracow. This work was supported in part by PL-Grid Infrastructure and the European Regional Development Fund under the Infrastructure and Environment Programme [grant number UDA-POIS.13.01-023/09-00]. The research was partially carried out with the equipment purchased thanks to the financial support of the European Regional Development Fund in the framework of the Polish Innovation Economy Operational Program (contract no. POIG.02.01.00-12-023/08). L. Vasylechko acknowledges partial support of the Ukrainian Ministry of Education and Sciences under the Projects ?RZE?, ?KMON?, and ICDD Grant-in-Aid pro…

Phase transitionMaterials scienceMultiferroicsEnthalpyAnalytical chemistryAb initioFOS: Physical sciences02 engineering and technologyDielectricActivation energy01 natural sciences7. Clean energyThermal expansionDSCsymbols.namesakeNuclear magnetic resonanceManganites0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)Materials Chemistry:NATURAL SCIENCES:Physics [Research Subject Categories]Ceramic010306 general physicsArrhenius equationCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale PhysicsSIESTAMaterials Science (cond-mat.mtrl-sci)021001 nanoscience & nanotechnologyFTIRvisual_artCeramics and Compositessymbolsvisual_art.visual_art_medium0210 nano-technologyJournal of the European Ceramic Society
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Microfluidic Synthesis of Actuating Microparticles from a Thiol-Ene Based Main-Chain Liquid Crystalline Elastomer.

2016

In this article the microfluidic synthesis of strongly actuating particles on the basis of a liquid crystalline main-chain elastomer is presented. The synthesis is carried out in a capillary-based co-flow microreactor by photo-initiated thiol-ene click chemistry of a liquid crystalline monomer mixture. These microparticles exhibit a deformation from a spherical to a rod-like shape during the thermal-initiated phase transition of the liquid crystalline elastomer (LCE) at which the particles’ aspect ratio is almost doubled. Repeated contraction cycles confirm the complete reversibility of the particles’ actuation properties. The transition temperature of the LCE, the temperature range of the …

Phase transitionMaterials sciencePolymers and PlasticsCapillary actionMicrofluidicsmicrofluidicsoft actuator02 engineering and technologycontinuous flow synthesis010402 general chemistryElastomer01 natural sciencesArticlestimuli-responsivelcsh:QD241-441Physics::Fluid Dynamicschemistry.chemical_compoundphoto polymerizationlcsh:Organic chemistryLiquid crystalliquid crystalComposite materialmicrofluidic; microparticles; liquid crystal; stimuli-responsive; soft actuator; thiol-ene; liquid crystalline elastomer; photo polymerization; continuous flow synthesismicroparticlesthiol-eneGeneral ChemistryAtmospheric temperature range021001 nanoscience & nanotechnology0104 chemical sciencesCondensed Matter::Soft Condensed MatterMonomerchemistryliquid crystalline elastomerMicroreactor0210 nano-technologyPolymers
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Dielectric properties of 0.4Na0.5Bi0.5TiO3–(0.6-x)SrTiO3–xPbTiO3 solid solutions

2014

Abstract In this paper we present our measurements of the linear and nonlinear dielectric permittivity of 0.4 Na 0.5 Bi 0.5 TiO 3 – ( 0.6 - x ) SrTiO 3 – xPbTiO 3 solid solutions (x = 0, 0.05, 0.1, 0.15). The dielectric anomaly increases in the system with respect to the concentration of lead, showing that interactions between dipolar entities are modified. The system exhibits dipolar-glass-like behaviour at low values of x ( 0 ⩽ x 0.1 ). Relaxor behaviour emerges in the sample where x = 0.1 . Furthermore, a spontaneous first-order phase transition from relaxor to normal ferroelectric is observed at x ⩾ 0.15 . A few peculiar dispersion regions are observed in the ferroelectric phase, which …

Phase transitionMaterials sciencePolymers and PlasticsCondensed matter physicsMetals and AlloysDielectricFerroelectricityElectronic Optical and Magnetic MaterialsCondensed Matter::Materials SciencePhase (matter)Ceramics and CompositesRelaxation (physics)Phase diagramSolid solutionCole–Cole equationActa Materialia
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