Search results for "Composites"

A 2,3-dialkoxynaphthalene-based naphthocage

2019

A 2,3-dialkoxynaphthalene-based naphthocage has been synthesized. This naphthocage prefers to bind small organic cations with its low-symmetry conformation, which is in contrast to 2,6-dialkoxynaphthalene-based naphthocages. Self-sorting of these two naphthocages with two structurally similar guests tetramethylammonium and tetraethylammonium was achieved as well. peerReviewed

Novel method for functionalising and patterning textile composites:Liquid resin print

2016

Abstract The paper reports a novel method of integrating resin into continuous textile reinforcement. The method presents a print of liquid reactive resin into textile preforms. A series of targeted injections forms a patch which upon consolidation and curing transforms into a stiff region continuously spanning through preform thickness. Enhancing the injected resin with conductive phase allows creating a pattern of patches with controlled dimensions and added functionalities. Patterned composites reveal features which are not typical for conventional composites such as fibre bridged interfaces, regular thickness variation, and gradient matrix properties. The presented study explores the ro…

Strength prediction of a triaxially braided composite

2011

The architecture of textile reinforcement affects the deformation and failure behavior of the textile reinforced composites. This paper presents an approximate method that incorporates the in-plane periodic meso structure of the textile composite in finite element models. In this approach, the representative unit cell (RUC) of a textile composite is divided into sub-cells. Instead of obtaining a homogeneous equivalent, these sub-cells are idealized and represented with laminates of different layups using shell elements. In this way, an RUC can be constructed with a small number of elements. This method holds the promise of creating a textile composite FE model with an improved accuracy with…

Rapid and eco-friendly synthesis of graphene oxide-silica nanohybrids

2014

Active colloidal suspensions: Clustering and phase behavior

2014

We review recent experimental, numerical, and analytical results on active suspensions of self-propelled colloidal beads moving in (quasi) two dimensions. Active colloids form part of the larger theme of active matter, which is noted for the emergence of collective dynamic phenomena away from thermal equilibrium. Both in experiments and computer simulations, a separation into dense aggregates, i.e., clusters, and a dilute gas phase has been reported even when attractive interactions and an alignment mechanism are absent. Here, we describe three experimental setups, discuss the different propelling mechanisms, and summarize the evidence for phase separation. We then compare experimental obse…

Aging effects in simple models for glassy relaxation

2006

Aging effects in the two-time correlation function and the response function after a quench from a high temperature to some low temperature are considered for a simple kinetic random energy model exhibiting stretched exponential relaxation. Because the system reaches thermal equilibrium for long times after the quench, all aging effect are of a transient nature. In particular, the violations of the fluctuation-dissipation theorem are considered and it is found that the relation between the response and the two-time correlation function depends on another function, the so-called asymmetry. This asymmetry vanishes in equilibrium but cannot be neglected in the aging regime. It is found that pl…

Rapid synthesis of tin (IV) oxide nanoparticles by microwave induced thermohydrolysis

2008

Abstract Tin oxide nanopowders, with an average size of 5 nm, were prepared by microwave flash synthesis. Flash synthesis was performed in aqueous solutions of tin tetrachloride and hydrochloric acid using a microwave autoclave (RAMO system) specially designed by the authors. Energy dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area analysis, nitrogen adsorption isotherm analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, and transmission electron microscopy (TEM), were used to characterize these nanoparticles. Compared with conventional synthesis, nanopow…

PMMA-titania nanocomposites: Properties and thermal degradation behavior

2012

Titania nanoparticles were prepared using a solegel method and calcination at 200 and 600 � C in order to obtain anatase and rutile phases, respectively. The obtained powders were used to prepare PMMAe titania nanocomposites by a melt compounding method. The effect of the crystalline phase and the amount of titania, in the range 1e5 wt.%, on the morphology, mechanical properties and thermal degradation kinetics of PMMA was investigated by means of X-ray diffractometry (XRD), transmission electron microscopy (TEM), 13 C cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy ( 13 C{ 1 H}CP-MAS NMR), including the measurement of proton spinelattice relaxation time in t…

Preparation and characterization of gels with garnet structure: A3B2C3O12, using ‘non-classical’ solvents

1992

Abstract Synthesis and characterization of some crystalline garnets by sol-gel techniques is described. The effects of emthanol, dimethyl sulfoxide (DMSO), CH2Cl2 and toluene solvents on gelation of TEOS are considered. Multicomponent gel formation in systems with stoichiometries 3CaO·Cr2O3·3SiO2 and 3CaO·Al2O2 was studied using DMSO, a polar solvent, and toluene, an apolar solvent. The dried gel was thermally treated and the powder was characterized by X-ray diffraction, differential thermal analysis/thermogravimetric analysis and scanning electron microscopy.

Structure and performance properties of environmentally-friendly biocomposites based on poly(ɛ-caprolactone) modified with copper slag and shale dril…

2018

The potential application of two types of industrial wastes, drill cuttings (DC) and copper slag (CS), as silica-rich modifiers of poly(ɛ-caprolactone) (PCL) was investigated. Chemical structure and physical properties of DC and CS fillers were characterized using X-ray diffractometer, X-ray fluorescence spectroscopy, particle size and density measurements. PCL/DC and PCL/CS composites with a variable content of filler (5 to 50 parts by weight) were prepared by melt compounding in an internal mixer. It was observed that lower particle size of DC filler enhanced processing of biocomposites comparing to CS filler. Smaller particles of DC filler and thus the higher specific surface area, enabl…