Search results for "Composites"
showing 10 items of 1905 documents
Reptation and constraint release
1991
Abstract The reptation and constraint release models are discussed by considering three recent experimental examples: (1) the diffusion of hydrogenated polybutadiene in matrices of molecular weights raning between 1 ⩽ Mw / Me ⩽ 253; (2) the diffusion of polystyrene (PS) chains in matrices of star branched PS; (3) the diffusion of very long PS chains in chemically cross-linked PS-networks. It is concluded that the reptation and constraint release models are applicable, but ‘constraint release’ should be understood in a wider sense allowing for non-reptative removal of barriers to lateral chain motion. The analysis of the third example proves that lateral modes of motion have a negligible inf…
Method of quantitative analysis of filler dispersion in composite systems with spherical inclusions
2011
In this work, a quantitative analysis method for the estimation of filler dispersion degree of filler particles in composite systems is presented and described. According to the procedure offered dispersion of filler particles of any form is associated with their area and the dispersion parameter D is defined as the probability to fall in a certain range of the particle area distribution. The method has been applied to both model and real systems characterized by different dispersion levels and various filler content. Final results highlight that for the case of better filler dispersion, the characteristic parameter, D, increases, since the quantity of filler particles having identical area…
Replica field theory for anharmonic sound attenuation in glasses
2011
Abstract A saddle-point treatment of interacting phonons in a disordered environment is developed. In contrast to crystalline solids, anharmonic attenuation of density fluctuations becomes important in the hydrodynamic regime, due to a broken momentum conservation. The variance of the shear modulus Δ2 turns out to be the strength of the disorder enhanced phonon–phonon interaction. In the low-frequency regime (below the boson peak frequency) we obtain an Akhiezer-like sound attenuation law Γ ∝ Τω2. Together with the usual Rayleigh scattering mechanism this yields a crossover of the Brillouin linewidth from a ω2 to a ω4 regime. The crossover frequency ωc is fully determined by the boson peak …
Relaxation dynamics in orientational glasses
1991
Abstract The multipolar relaxation dynamics observed in dipolar and quadrupolar glasses are reviewed. Special attention is given to the distribution of the relaxation times and to the temperature dependence of the mean relaxation rates. Experimental evidence is provided that orientational glasses can be described in terms of ‘strong glasses’ that are characterized by a low density of configurational states in the potential energy surface. It is suggested that this behavior results from the natural separation of timescales of reorientational and diffusive processes in these crystals.
Magnetic Exchange between Orbitally Degenerate Metal Ions: The Problem of Magnetic Anisotropy
2001
Abstract In this paper we show that a strong magnetic anisotropy appears in exchange mixed–valence clusters containing orbitally degenerate metal ions. Combining an effective Hamiltonian approach with the technique of the irreducible tensor operators (ITO) and pseudoangular momentum representation we have solved the problem of magnetic exchange in localized and delocalized (mixed–valence) systems with different overall symmetries ( D 2 h , D 3 h , D 4 h ). The energy pattern as well as the character of the magnetic anisotropy is closely related to the ground term of the ions, electron transfer pathways, and overall symmetry of the system being affected also by the local crystal fields, spin…
Nature of the non-exponential primary relaxation in structural glass-formers probed by dynamically selective experiments
1998
Several experimental methods feature the potential to distinguish between slow and fast contributions to the non-exponential, ensemble averaged primary response in glass-forming materials. Some of these techniques are based on the selection of subensembles using multi-dimensional nuclear magnetic resonance, optical bleaching, and non-resonant spectral hole burning. Others, such as the time-dependent solvation spectroscopy, measure microscopic responses induced by local perturbations. Using several of these methods it could be demonstrated for various glass-forming materials that the non-exponential relaxation results from a superposition of dynamically distinguishable entities. The experime…
Frustration of structural fluctuations upon equilibration of shear melts
2002
Abstract We report on the formation of amorphous solids from aquaeous suspensions of charged colloidal spheres. Comprehensive light scattering and microscopic studies show that in these systems the nucleation rate density continuously increases to very high values. At the highest particle densities of 47.5 μm −3 (packing fraction Φ =0.146) an amorphous state is observed of only short range order, finite static shear modulus and frozen long time dynamics. This state is composed of a piling of––as we propose pre-critical––nuclei. Differences from the Hard Sphere case are discussed in some detail. There the arrest of density fluctuations is observed and described by Mode Coupling scenarios. In…
Characterization of electrospun poly(lactide) composites containing multiwalled carbon nanotubes
2019
The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: The authors would like to thank the Ministry of Education, Science and Technological Development, Republic of Serbia, for funding projects III45022 and 172056 and European Cooperation in Science and Technology (COST) action CA15107.
Optical properties of biocompatible polyaniline nano-composites
2006
Abstract Polyaniline (PANI) is an electro-active polymer of great interest thanks to its outstanding physical and chemical properties which make it suitable for various applications in optics, bioelectronics, biosensors, diagnostics and therapeutic devices. Unfortunately, PANI is infusible and insoluble in most common solvents and, thus, very difficult to process. In the attempt of improving processability, yet preserving its interesting properties, PANI has been synthesized in the form of particles and dispersed into a hydrogel matrix. The synthesis of PANI–hydrogel composites proceeds via γ-irradiation of PANI dispersions as obtained by ‘in situ’ polymerization of aniline in the presence …
Assessment of Arundo donax Fibers for Oil Spill Recovery Applications
2019
In the last years, natural fibers are increasingly investigated as an oil recovery system in order to overcome the oil spillage phenomena, thus preserving environment and aquatic life. In particular, lignocellulose-based fibers have recently been employed with promising results. In such a context, the aim of this paper is to assess the oil sorption capability of natural fibers extracted from the stem of the giant reed Arundo donax L., a perennial rhizomatous grass belonging to the Poaceae family that grows naturally all around the world thanks to its ability to tolerate different climatic conditions. Sorption tests in several pollutants and water as a reference were carried out. The fibers …